Difference between revisions of "Metalloid" - New World Encyclopedia

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Together with the [[metal]]s and [[nonmetal]]s, the '''metalloids''' (in [[Greek language|Greek]] ''metallon'' = metal and ''eidos'' = sort - also called '''semimetals''') form one of the three categories of [[chemical element]]s as classified by [[ionization]] and [[bonding]] properties. They have properties intermediate between those of metals and nonmetals. There is no unique way of distinguishing a metalloid from a true [[metal]] but the most common is that metalloids are usually [[semiconductor]]s rather than [[Conductor (material)|conductor]]s.
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'''Metalloid''' is a term used in [[chemistry]] when classifying the [[chemical element]]s.  On the basis of their general physical and chemical properties, nearly every element in the [[periodic table]] can be termed either a [[metal]] or a [[nonmetal]].  A few elements with intermediate properties are, however, referred to as metalloids. (In [[Greek language|Greek]] ''metallon'' = metal and ''eidos'' = sort)
  
The known metalloids (and their [[List of elements by symbol|atomic symbols]]) are:
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There is no rigorous definition of the term, but the following properties are usually considered characteristic of metalloids:
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* metalloids often form [[amphoterism|amphoteric]] [[oxides]].
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* metalloids often behave as [[semiconductor]]s (B,Si,Ge) to [[semimetal]]s (eg. Sb).
 +
 
 +
The concepts of metalloid and semiconductor should not be confused.  Metalloid refers to the properties of certain ''elements'' in relation to the periodic table. Semiconductor refers to the physical properties of ''materials'' (including alloys, compounds) and there is only partial overlap between the two.
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The following elements are generally considered metalloids:<ref name="acs">ACS Periodic Table. [http://www.chemistry.org/portal/a/c/s/1/acsdisplay.html?DOC=sitetools\periodic_table.html#]</ref>
 
*[[Boron]] (B)
 
*[[Boron]] (B)
 
*[[Silicon]] (Si)
 
*[[Silicon]] (Si)
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*[[Antimony]] (Sb)
 
*[[Antimony]] (Sb)
 
*[[Tellurium]] (Te)
 
*[[Tellurium]] (Te)
*[[Polonium]] (Po)
 
  
<!--New elements that should be metalloids
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Some [[allotropes]] of elements exhibit more pronounced metal, metalloid or non-metal behavior than others. For example, for the element [[carbon]], its [[diamond]] allotrope is clearly non-metallic, but the [[graphite]] allotrope displays limited electric conductivity more characteristic of a metalloid. [[Phosphorus]], [[tin]], [[selenium]] and [[bismuth]] also have allotropes that display borderline behavior.  
*[[Ununhexium]] (Uuh)
 
*[[Ununseptium]] (Uus) (117; not yet synthesized)
 
-->
 
In the [[periodic table]], metalloids occur along the diagonal line from boron to polonium.  Elements to the upper right of this line are nonmetals; elements to the lower left are metals.
 
  
Semi-metallic behaviour is not confined to the elements, but is also found in [[alloys]] and [[compounds]].  
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In the standard layout of the [[periodic table]], metalloids occur along the diagonal line through the [[p block]] from boron to astatine.  Elements to the upper right of this line display increasing nonmetallic behaviour; elements to the lower left display increasing metallic behaviour. This line is called the "stair-step" or "staircase." The [[poor metal]]s are to the left and down and the [[nonmetal]]s are to the right and up.
  
One definition of semi-metallic behavior would be if the [[conduction band]] and [[valence band]] overlap. This is also true of metals, so semi-metals must additionally have a relatively low carrier density.
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{| align="center" cellpadding="3"
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|-
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![[Boron group|13]]
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![[Carbon group|14]]
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![[Pnictogen|15]]
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![[Chalcogen|16]]
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![[Halogen|17]]
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|- style="background:#ffccff; color:#999999; text-align:center"
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| style="background:#ff0000; color:#000000" | <big>B</big><br><small>Boron</small>
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| <big>C</big><br><small>Carbon</small>
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| <big>N</big><br><small>Nitrogen</small>
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| <big>O</big><br><small>Oxygen</small>
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| <big>F</big><br><small>Fluorine</small>
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|- style="background:#ffccff; color:#999999; text-align:center"
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| <big>Al</big><br><small>Aluminium</small>
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| style="background:#ff0000; color:#000000" | <big>Si</big><br><small>Silicon</small>
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| <big>P</big><br><small>Phosphorus</small>
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| <big>S</big><br><small>Sulfur</small>
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| <big>Cl</big><br><small>Chlorine</small>
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|- style="background:#ffccff; color:#999999; text-align:center"
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| <big>Ga</big><br><small>Gallium</small>
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| style="background:#ff0000; color:#000000" | <big>Ge</big><br><small>Germanium</small>
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| style="background:#ff0000; color:#000000" | <big>As</big><br><small>Arsenic</small>
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| <big>Se</big><br><small>Selenium</small>
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| <big>Br</big><br><small>Bromine</small>
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|- style="background:#ffccff; color:#999999; text-align:center"
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| <big>In</big><br><small>Indium</small>
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| <big>Sn</big><br><small>Tin</small>
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| style="background:#ff0000; color:#000000" | <big>Sb</big><br><small>Antimony</small>
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| style="background:#ff0000; color:#000000" | <big>Te</big><br><small>Tellurium</small>
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| <big>I</big><br><small>Iodine</small>
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|- style="background:#ffccff; color:#999999; text-align:center"
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| <big>Tl</big><br><small>Thallium</small>
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| <big>Pb</big><br><small>Lead</small>
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| <big>Bi</big><br><small>Bismuth</small>
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| style="background:#ffccff; color:#999999" | <big>Po</big><br><small>Polonium</small>
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| style="background:#ffccff; color:#999999" | <big>At</big><br><small>Astatine</small>
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|}
  
<br/>
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==References==
{{PeriodicTablesFooter}} [[Category:Periodic table]] <br/>
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<references/>
  
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{{clear}}
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{{PeriodicTablesFooter}}
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{{compact periodic table}}
  
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{{chemistry-stub}}
 
<!--Category—>
 
<!--Category—>
[[Category:Physical sciences]]
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[[Category:Chemistry]]
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[[Category:Periodic table]]
 
[[Category:Metalloids|*]]
 
[[Category:Metalloids|*]]
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<!--Interlanguage links—>
 
<!--Interlanguage links—>
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{{Link FA|lmo}}
  
 
[[ar:شبه فلز]]
 
[[ar:شبه فلز]]
[[de:Halbmetall]]
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[[ast:Metaloide]]
[[et:Poolmetall]]
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[[bs:Polumetali]]
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[[bg:Металоид]]
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[[ca:Metal·loide]]
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[[cs:Polokov]]
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[[da:Halvmetal]]
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[[de:Halbmetalle]]
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[[et:Poolmetallid]]
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[[el:Μεταλλοειδή]]
 
[[es:Metaloide]]
 
[[es:Metaloide]]
 
[[eo:Metaloido]]
 
[[eo:Metaloido]]
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[[eu:Metaloide]]
 
[[fr:Métalloïde]]
 
[[fr:Métalloïde]]
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[[gl:Metaloide]]
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[[ko:준금속]]
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[[hr:Polumetali]]
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[[id:Metaloid]]
 
[[is:Málmungur]]
 
[[is:Málmungur]]
[[it:Metalloidi]]
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[[it:Semimetalli]]
[[he:מטלואידים]]
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[[he:מתכות למחצה]]
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[[jv:Metaloid]]
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[[lt:Pusmetaliai]]
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[[lmo:Mèzz-metàj]]
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[[hu:Félfémek]]
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[[ms:Metaloid]]
 
[[nl:Metalloïde]]
 
[[nl:Metalloïde]]
 
[[ja:半金属]]
 
[[ja:半金属]]
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[[no:Halvmetall]]
 
[[nn:Halvmetall]]
 
[[nn:Halvmetall]]
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[[nds:Halfmetall]]
 
[[pl:Półmetale]]
 
[[pl:Półmetale]]
[[pt:Metalóide]]
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[[pt:Semimetal]]
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[[ro:Metaloid]]
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[[qu:Yaqa q'illay]]
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[[ru:Полуметаллы]]
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[[simple:Metalloid]]
 
[[sl:Polkovina]]
 
[[sl:Polkovina]]
[[sv:Halvmetall]]
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[[sr:Металоиди]]
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[[sh:Metaloid]]
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[[fi:Puolimetalli]]
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[[sv:Metalloid]]
 
[[th:ธาตุกึ่งโลหะ]]
 
[[th:ธาตุกึ่งโลหะ]]
 
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[[vi:Á kim]]
{{credit|26025600}}
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[[tr:Yarı metal]]
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[[uk:Напівметали]]
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[[zh-yue:類金屬]]
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[[zh:类金属]]

Revision as of 16:58, 23 July 2008

Metalloid is a term used in chemistry when classifying the chemical elements. On the basis of their general physical and chemical properties, nearly every element in the periodic table can be termed either a metal or a nonmetal. A few elements with intermediate properties are, however, referred to as metalloids. (In Greek metallon = metal and eidos = sort)

There is no rigorous definition of the term, but the following properties are usually considered characteristic of metalloids:

The concepts of metalloid and semiconductor should not be confused. Metalloid refers to the properties of certain elements in relation to the periodic table. Semiconductor refers to the physical properties of materials (including alloys, compounds) and there is only partial overlap between the two.

The following elements are generally considered metalloids:[1]

Some allotropes of elements exhibit more pronounced metal, metalloid or non-metal behavior than others. For example, for the element carbon, its diamond allotrope is clearly non-metallic, but the graphite allotrope displays limited electric conductivity more characteristic of a metalloid. Phosphorus, tin, selenium and bismuth also have allotropes that display borderline behavior.

In the standard layout of the periodic table, metalloids occur along the diagonal line through the p block from boron to astatine. Elements to the upper right of this line display increasing nonmetallic behaviour; elements to the lower left display increasing metallic behaviour. This line is called the "stair-step" or "staircase." The poor metals are to the left and down and the nonmetals are to the right and up.

13 14 15 16 17
B
Boron
C
Carbon
N
Nitrogen
O
Oxygen
F
Fluorine
Al
Aluminium
Si
Silicon
P
Phosphorus
S
Sulfur
Cl
Chlorine
Ga
Gallium
Ge
Germanium
As
Arsenic
Se
Selenium
Br
Bromine
In
Indium
Sn
Tin
Sb
Antimony
Te
Tellurium
I
Iodine
Tl
Thallium
Pb
Lead
Bi
Bismuth
Po
Polonium
At
Astatine

References
ISBN links support NWE through referral fees

  1. ACS Periodic Table. [1]


Periodic tables

Standard table | Vertical table | Table with names | Names and atomic masses (large) | Names and atomic masses (small) | Names and atomic masses (text only) | Inline F-block | Elements to 218 | Electron configurations | Metals and non metals | Table by blocks | List of elements by name
Groups:   1 -  2 -  3 -  4 -  5 -  6 -  7 -  8 -  9 - 10 - 11 - 12 - 13 - 14 - 15 - 16 - 17 - 18
Periods:  1  -  2  -  3  -  4  -  5  -  6  -  7  -  8
Series:   Alkalis  -  Alkaline earths  -  Lanthanides  -  Actinides  -  Transition metals  -  Poor metals  -  Metalloids  -  Nonmetals  -  Halogens  -  Noble gases
Blocks:  s-block  -  p-block  -  d-block  -  f-block  -  g-block

Template:Chemistry-stub



ar:شبه فلز ast:Metaloide bs:Polumetali bg:Металоид ca:Metal·loide cs:Polokov da:Halvmetal de:Halbmetalle et:Poolmetallid el:Μεταλλοειδή es:Metaloide eo:Metaloido eu:Metaloide fr:Métalloïde gl:Metaloide ko:준금속 hr:Polumetali id:Metaloid is:Málmungur it:Semimetalli he:מתכות למחצה jv:Metaloid lt:Pusmetaliai lmo:Mèzz-metàj hu:Félfémek ms:Metaloid nl:Metalloïde ja:半金属 no:Halvmetall nn:Halvmetall nds:Halfmetall pl:Półmetale pt:Semimetal ro:Metaloid qu:Yaqa q'illay ru:Полуметаллы simple:Metalloid sl:Polkovina sr:Металоиди sh:Metaloid fi:Puolimetalli sv:Metalloid th:ธาตุกึ่งโลหะ vi:Á kim tr:Yarı metal uk:Напівметали zh-yue:類金屬 zh:类金属