Cesium

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55 xenoncesiumbarium
Rb

Cs

Fr
Cs-TableImage.png
General
Name, Symbol, Number cesium, Cs, 55
Chemical series alkali metals
Group, Period, Block 1, 6, s
Appearance silvery gold
Cs,55.jpg
Atomic mass 132.9054519(2) g/mol
Electron configuration [Xe] 6s1
Electrons per shell 2, 8, 18, 18, 8, 1
Physical properties
Phase solid
Density (near r.t.) 1.93 g/cm³
Liquid density at m.p. 1.843 g/cm³
Melting point 301.59 K
(28.44 °C, 83.19 °F)
Boiling point 944 K
(671 °C, 1240 °F)
Critical point 1938 K, 9.4 MPa
Heat of fusion 2.09 kJ/mol
Heat of vaporization 63.9 kJ/mol
Heat capacity (25 °C) 32.210 J/(mol·K)
Vapor pressure
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 418 469 534 623 750 940
Atomic properties
Crystal structure cubic body centered
Oxidation states 1
(strongly basic oxide)
Electronegativity 0.79 (Pauling scale)
Ionization energies 1st: 375.7 kJ/mol
2nd: 2234.3 kJ/mol
3rd: 3400 kJ/mol
Atomic radius 260 pm
Atomic radius (calc.) 298 pm
Covalent radius 225 pm
Miscellaneous
Magnetic ordering no data
Electrical resistivity (20 °C) 205 nΩ·m
Thermal conductivity (300 K) 35.9 W/(m·K)
Thermal expansion (25 °C) 97 µm/(m·K)
Speed of sound (thin rod) (r.t.) 1.7 m/s
Bulk modulus 1.6 GPa
Mohs hardness 0.2
Brinell hardness 0.14 MPa
CAS registry number 7440-46-2
Notable isotopes
Main article: Isotopes of cesium
iso NA half-life DM DE (MeV) DP
133Cs 100% Cs is stable with 78 neutrons
134Cs syn 65.159 Ms
(2.0648y)
ε 1.229 134Xe
β- 2.059 134Ba
135Cs trace 73 Ts
(2,300,000y)
β- 0.269 135Ba
137Cs syn 948.9 Ms
(30.07y)
β- 1.176 137Ba

Cesium (also spelled caesium, chemical symbol Cs, atomic number 55) is a member of the group of chemical elements known as alkali metals. Soft and silvery gold in color, it is one of a handful of metals that liquefy near room temperature. It is the most alkaline of the stable elements, reacting explosively with water to produce the alkali cesium hydroxide, which can corrode glass. Its atoms readily lose electrons to produce ions, and this property makes cesium useful for photoelectric cells. Cesium is a catalyst for certain reactions in organic chemistry.

Contents

This element has many isotopes, of which the single stable isotope (cesium-133) has become the primary standard for measuring seconds of time and is therefore the basis of atomic clocks. Some of its radioactive isotopes are used to treat certain types of cancer, and cesium-134 helps measure cesium output by the nuclear power industry. Cesium-137 is commonly used in industry for such applications as moisture density gauges, leveling gauges, and thickness gauges. Cesium compounds are mildly toxic.

Discovery

Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860, when they analyzed the spectrum of mineral water obtained from Dürkheim, Germany. They held a drop of the water in a flame and observed the spectral lines of several elements. Among these lines they observed two blue lines that did not come from any of the known elements. They concluded that the blue lines were produced by a hitherto unknown element, which they named cesium (from the Latin word caesius, meaning "sky blue" or "heavenly blue"). Thus cesium became the first element discovered by spectral analysis. Bunsen isolated cesium salts from the spring water, and the metal itself was isolated in 1881 by Carl Setterberg, who worked in Bunsen's laboratory.

Occurrence

Pollucite, a cesium mineral.

Cesium occurs in several minerals, particularly lepidolite and pollucite (a hydrated silicate of aluminum and cesium). One of the world's most significant and rich sources of this metal is located at Bernic Lake in Manitoba. The deposits there are estimated to contain 300,000 metric tons of pollucite, at an average of 20 percent cesium.

Metallic cesium can be isolated by the electrolysis of fused (molten) cesium cyanide, as well as in several other ways. Exceptionally pure, gas-free cesium can be made by decomposing cesium azide with heat.

Notable characteristics

As an alkali metal, cesium is part of group one of the periodic table, between rubidium and francium. Also, it lies in period six, just before barium. This silvery gold metal is soft and ductile (it can be readily drawn into wires).

As noted above, the spectrum of cesium has two bright lines in the blue part of the electromagnetic spectrum. In addition, its spectrum has several other lines in the red, yellow, and green regions.

Cesium is the most electropositive and most alkaline of the stable chemical elements. Aside from francium, it has the lowest ionization potential of all the elements, which means that it readily loses its outermost electron to become an ion. (Ionization potential is the energy needed to remove an electron from the atom's outermost shell.)

Cesium is the least abundant of the five nonradioactive alkali metals. Technically, francium is the least common alkali metal, but because it is highly radioactive and its total worldwide quantity is estimated to be only 340 to 550 grams, its abundance can be considered zero in practical terms.[1]

Along with gallium, francium, and mercury, cesium is among the few metals that are liquid at or near room temperature. Its melting point is 28.44°C.

Cesium reacts explosively when it comes in contact with water (even cold water), and also reacts with ice at temperatures above −116°C. The reaction with water produces cesium hydroxide (CsOH), an extremely strong chemical base that will rapidly etch the surface of glass. In addition cesium reacts violently with chlorine gas to produce cesium chloride (CsCl).

Isotopes

Cesium has at least 39 known isotopes, which is more than any other element except francium. The atomic masses of these isotopes range from 112 to 151. Yet it has only one naturally occurring stable isotope: 133Cs. Most of the other isotopes (except for those noted in the table) have half-lives from a few days to fractions of a second.

Since 1967, the International System of Units (SI units) has defined the second based on oscillations between two energy levels of the cesium-133 atom. Thus the cesium oscillator has become the primary standard for time and frequency measurements.

The isotope 137Cs, with a half-life of 30.17 years, has been used in hydrologic studies, analogous to the use of tritium (3H). It decomposes to barium-137 (a short-lived product of decay), then to a form of nonradioactive barium.

Cesium-137 is produced during the detonation of nuclear weapons and in nuclear power plants. It was a notable product during the 1986 Chernobyl meltdown. Beginning in 1945, with the commencement of nuclear testing, 137Cs has been released into the atmosphere, where it is absorbed by moisture and returned to the Earth's surface as a component of radioactive fallout. Once 137Cs enters groundwater, it is deposited on soil surfaces and removed from the landscape primarily by particle transport.

Compounds of cesium

Cesium carbonate: Cesium carbonate is a white crystalline solid, with the chemical formula Cs2CO3. It is more soluble in organic solvents than most carbonates such as potassium carbonate. It is therefore used as a base in organic chemistry.

Cesium chloride: Cesium chloride (CsCl) is an ionic compound. It can be prepared by the reaction of cesium hydroxide or cesium carbonate with hydrochloric acid. The resulting cesium chloride salt is purified by recrystallization. The crystalline structure of this salt is composed of interlocking simple cubic lattices of anions and cations.

Cesium hydroxide: Cesium hydroxide (CsOH) is formed when cesium reacts with water. It is a powerful base, much like other alkali metal hydroxides such as sodium hydroxide and potassium hydroxide. It can corrode glass.

Cesium hydroxide is extremely hygroscopic, which means that it readily absorbs moisture from the environment. Laboratory cesium hydroxide is typically a hydrate.

This compound is not usually used in experiments, because the extraction of cesium is very expensive and it behaves very much like rubidium hydroxide and potassium hydroxide.

Applications

  • Cesium is most notably used in atomic clocks, which are accurate to seconds in many thousands of years.
  • Cesium-134 has been used as a measure of cesium output by the nuclear power industry. This isotope is used because, while it is less prevalent than either 133Cs or 137Cs, 134Cs is produced solely by nuclear reactions. 135Cs has also been used for this purpose.
  • Like other group one elements, cesium has great affinity for oxygen and is used as a "getter" in vacuum tubes.
  • This metal is also used in photoelectric cells because it readily emits electrons.
  • Cesium is used as a catalyst in the hydrogenation of certain organic compounds.
  • Cesium hydroxide is used to etch silicon, exposing octahedral planes. This technique can create pyramids and regularly shaped etch pits for uses such as MEMS (microelectromechanical systems).
  • Cesium chloride is used in the production of electrically conducting glasses.
  • Radioisotopes of cesium (in the form of cesium chloride) are used in nuclear medicine, including the treatment of cancer.
  • Cesium fluoride is widely used in organic chemistry as a base and as a source of anhydrous fluoride ion.
  • Cesium vapor is used in many common magnetometers.
  • Because of their high density, cesium chloride solutions are commonly used in molecular biology experiments for the isolation of nucleic acids by a technique known as "density gradient ultracentrifugation."
  • Recently, this metal has been used in ion propulsion systems.
  • Cesium-137 is an extremely common isotope in industrial applications such as:
    • moisture density gauges;
    • leveling gauges;
    • thickness gauges;
    • well-logging devices (used to measure the thickness of rock strata).

Precautions

All alkali metals are extremely reactive. As one of the heavier alkali metals, cesium is also one of the most reactive. As noted above, it is highly explosive when it comes in contact with water or ice. Cesium hydroxide is an extremely strong base and can attack glass.

All cesium compounds should be regarded as mildly toxic, because of its chemical similarity to potassium. Contact with large amounts can cause hyperirritability and spasms. On the other hand, such amounts would not ordinarily be encountered in nature, so cesium is not a major chemical environmental pollutant. Rats fed with cesium in place of potassium in their diet were found to die, so this element cannot replace potassium in function.

The isotopes 134Cs and 137Cs (present in the biosphere in small amounts as a result of radiation leaks) represent a radioactivity burden that varies depending on location. Radioactive cesium does not accumulate in the body as effectively as many other fission products, such as radioactive iodine or strontium.

See also

Notes

  1. Adloff, Jean-Pierre and George B. Kauffman. (September 23, 2005). Francium (Atomic Number 87), the Last Discovered Natural Element. The Chemical Educator 10 (5). Retrieved December 9, 2007.

References

External links

All links retrieved April 29, 2013.

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