Magnesium

12 sodium ← magnesium → aluminium Be ↑ Mg ↓ Ca periodic table
General
Name, Symbol, Number	magnesium, Mg, 12
Chemical series	alkaline earth metals
Group, Period, Block	2, 3, s
Appearance	silvery white
Atomic mass	24.3050(6) g/mol
Electron configuration	[Ne] 3s2
Electrons per shell	2, 8, 2
Physical properties
Phase	solid
Density (near r.t.)	1.738 g/cm³
Liquid density at m.p.	1.584 g/cm³
Melting point	923 K (650 °C, 1202 °F)
Boiling point	1363 K (1090 °C, 1994 °F)
Heat of fusion	8.48 kJ/mol
Heat of vaporization	128 kJ/mol
Heat capacity	(25 °C) 24.869 J/(mol·K)
Vapor pressure P/Pa 1 10 100 1 k 10 k 100 k at T/K 701 773 861 971 1132 1361
Atomic properties
Crystal structure	hexagonal
Oxidation states	2 (strongly basic oxide)
Electronegativity	1.31 (Pauling scale)
Ionization energies (more)	1st: 737.7 kJ/mol
	2nd: 1450.7 kJ/mol
	3rd: 7732.7 kJ/mol
Atomic radius	150 pm
Atomic radius (calc.)	145 pm
Covalent radius	130 pm
Van der Waals radius	173 pm
Miscellaneous
Magnetic ordering	paramagnetic
Electrical resistivity	(20 °C) 43.9 nΩ·m
Thermal conductivity	(300 K) 156 W/(m·K)
Thermal expansion	(25 °C) 24.8 µm/(m·K)
Speed of sound (thin rod)	(r.t.) (annealed) 4940 m/s
Speed of sound (thin rod)	(r.t.) 45 m/s
Shear modulus	17 GPa
Bulk modulus	45 GPa
Poisson ratio	0.29
Mohs hardness	2.5
Brinell hardness	260 MPa
CAS registry number	7439-95-4
Notable isotopes
Main article: Isotopes of magnesium iso NA half-life DM DE (MeV) DP 24Mg 78.99% Mg is stable with 12 neutrons 25Mg 10% Mg is stable with 13 neutrons 26Mg 11.01% Mg is stable with 14 neutrons

Magnesium (chemical symbol Mg, atomic number 12) is the eighth most abundant chemical element in the Earth's crust, constituting about 2% of the crust by weight. It is the third most plentiful element dissolved in seawater. It is classified as an alkaline earth metal and is not found in the form of the free metal in nature. Once produced from magnesium salts, it is primarily used as an alloying agent to make aluminium-magnesium alloys, sometimes called magnalium or magnelium.

Discovery and occurrence

The name magnesium originates from the Greek word for a district called Magnesia in Thessaly. The element, which is always combined with other elements in nature, is found in deposits of over 60 minerals. Of these, only dolomite, magnesite, brucite, carnallite, talc, and olivine are of commercial importance.

In 1755, Joseph Black in England recognized magnesium as being an element. Sir Humphry Davy electrolytically isolated pure magnesium metal in 1808, from a mix of magnesia (magnesium oxide, MgO) and mercuric oxide (HgO). French chemist Antoine Bussy described another method of preparing it in 1831.

In the United States, this metal is principally obtained by electrolysis of fused magnesium chloride from brines, wells, and seawater:

cathode: Mg²⁺ + 2 e^- → Mg

anode: 2 Cl^- → Cl_{2 (gas)} + 2 e^-

The United States has traditionally been the major world supplier of this metal, supplying 45% of world production even as recently as 1995. Today, the U.S. market share is at 7%. As of 2005, China has taken over as the dominant supplier, pegged at 60% world market share, which increased from 4% in 1995. To isolate the metal, China relies almost completely on what is called the Pidgeon process, in which magnesium oxide is reduced at high temperatures with silicon.

Notable characteristics of element and compounds

Elemental magnesium is a fairly strong, silvery-white, light-weight metal (two thirds the density of aluminium). It slightly tarnishes when exposed to air, although unlike the alkaline metals, storage in an oxygen free environment is unnecessary because magnesium is protected by a thin layer of oxide which is fairly impermeant and hard to remove. Like its lower periodic table group neighbor calcium, magnesium reacts with water at room temperature, though it reacts much more slowly than calcium. When it is submerged in water hydrogen bubbles will almost unnoticably begin to form on the surface of the metal, though if powdered it will react much more rapidly. The reaction will occur faster with higher temperatures (see precautions). Magnesium is a highly flammable metal, but while it is easy to ignite when powdered or shaved into thin strips, it is difficult to ignite in mass or bulk. Once ignited it is difficult to extinguish, being able to burn in both nitrogen (forming magnesium nitride), and carbon dioxide (forming magnesium oxide and carbon).

Magnesium, when it burns in air, produces a brilliant white light. This was used in the early days of photography when magnesium powder was used as a source of illumination (flash powder). Later, magnesium ribbon was used in electrically ignited flash bulbs. Magnesium powder is still used in the manufacture of fireworks and marine flares where a brilliant white light is required.

Magnesium, when glowing white, has many chemical properties that it does not possess at lower temperatures. It also becomes more toxic, although this is irrelevant because the high temperature alone is extremely dangerous.

Magnesium compounds are typically white crystals. Most are soluble in water, providing the sour-tasting magnesion ion Mg²⁺. Small amounts of dissolved magnesium ion contributes to the tartness and taste of natural waters. Magnesium ion in large amounts is an ionic laxitive, and magnesium sulfate (Epsom salts) is sometimes used for this purpose. So-called "milk of magnesia" is a water suspension of one of the few insoluble magnesium compounds, magnesium hydroxide; the undissolved particles give rise to its appearance and name. Milk of magnesia is a mild base, and is commonly used as an antacid.

Isotopes

²⁶Mg is a stable isotope that has found application in isotopic geology, similar to that of aluminium. ²⁶Mg is a radiogenic daughter product of ²⁶Al, which has a half-life of 717,000 years. Large enrichments of stable ²⁶Mg have been observed in the Ca-Al-rich inclusions of some carbonaceous chondrite meteorites. The anomalous abundance of ²⁶Mg is attributed to the decay of its parent ²⁶Al in the inclusions. Therefore, the meteorite must have formed in the solar nebula before the ²⁶Al had decayed. Hence, these fragments are among the oldest objects in the solar system and have preserved information about its earliest history.

It is conventional to plot ²⁶Mg/²⁴Mg against an Al/Mg ratio. In an isochrone plot, the Al/Mg ratio plotted is ²⁷Al/²⁴Mg. The slope of the isochron has no age significance, but indicates the initial ²⁶Al/²⁷Al ratio in the sample at the time when the systems were separated from a common reservoir.

Compounds in living organisms

Magnesium ion is essential to the basic nucleic acid chemistry of life, and thus is essential to all cells of all known living organisms. Plants have an additional use for magnesium in that chlorophylls are magnesium-centered porphyrins. Many enzymes require the presence of magnesium ions for their catalytic action, especially enzymes utilizing ATP, or those which use other nucleotides to synthesize DNA and RNA.

Magnesium deficiency in humans was first described in the medical literature in 1934. The adult human daily nutritional requirement, which is affected by various factors including sex, weight and size, is 300-400 mg/day. Inadequate magnesium intake frequently causes muscle spasms, and has been associated with cardiovascular disease, diabetes, high blood pressure, anxiety disorders and osteoporosis. Acute deficiency (see hypomagnesemia) is rare, and is more common as a drug side effect (such as chronic alcohol or diuretic use) than from low food intake per se. The incidence of chronic deficiency resulting in less than optimal health, is debated.

The DRI upper tolerated limit for supplemental magnesium is 350 mg/day (calculated as mg of Mg elemental in the salt). The most common symptom of excess oral magnesium intake is diarrhea. Since the kidneys of adult humans excrete excess magnesium efficiently, oral magnesium poisoning in adults with normal renal function, is very rare. Infants, which have less ability to excrete excess magnesium even when healthy, should not be given magnesium supplements, except under a physician's care.

Magnesium salts (usually in the form of magnesium sulfate when given parenterally) are used therapeutically for a number of medical conditions, especially the hypertension of eclampsia. See Epsom salts for a list of conditions which have been treated with supplemental magnesium.

Food sources

Green vegetables such as spinach provide magnesium because the center of the chlorophyll molecule contains magnesium. Nuts (especially almonds), seeds, and some whole grains are also good sources of magnesium.

Although magnesium is present in many foods, it usually occurs in small amounts. As with most nutrients, daily needs for magnesium cannot be met from a single food. Eating a wide variety of foods, including five servings of fruits and vegetables daily and plenty of whole grains, helps to ensure an adequate intake of magnesium.

The magnesium content of refined foods is usually low. Whole-wheat bread, for example, has twice as much magnesium as white bread because the magnesium-rich germ and bran are removed when white flour is processed. The table of food sources of magnesium suggests many dietary sources of magnesium.

Water can provide magnesium, but the amount varies according to the water supply. "Hard" water contains more magnesium than "soft" water. Dietary surveys do not estimate magnesium intake from water, which may lead to underestimating total magnesium intake and its variability.

Too much magnesium in the diet can make it difficult for your body to absorb calcium. On the other hand not enough magnesium can lead to irregular heartbeats, high blood pressure, insomnia and muscle spasms.

Following are some foods and the amount of magnesium in them:

• spinach (1/2 cup) = 80 milligrams (mg)
• peanut butter (2 tablespoons) = 50 mg
• black-eyed peas (1/2 cup) = 45 mg
• milk: low fat (1 cup) = 40 mg

The U.S. RDV/RDA is 400 mg of Magnesium.

Applications

As the metal

Magnesium is the third most commonly used structural metal, following steel and aluminum.

Magnesium compounds, primarily magnesium oxide, are used mainly as refractory material in furnace linings for producing iron, steel, nonferrous metals, glass and cement. Magnesium oxide and other compounds also are used in agricultural, chemical and construction industries. As a metal, this element's principal use is as an alloying additive to aluminium with these aluminium-magnesium alloys being used mainly for beverage cans.

Magnesium, in its purest form, can be compared to aluminium, and is strong and light, so it is used in several high volume part manufacturing applications, including automotive and truck components. Specialty, high-grade car wheels of magnesium alloy are called "mag wheels". In 1957, a Corvette SS, designed for racing, was constructed, with completely magnesium body panels. Volkswagen has used magnesium in its engine components for many years. For a long time, Porsche used magnesium alloy for its engine blocks due to the weight advantage. However, there is renewed interest in magnesium engine blocks, as featured in the 2006 BMW 325i and 330i models. The award-winning BMW engine uses an aluminium alloy insert for the cylinder walls and cooling jackets surrounded by a high temperature magnesium alloy AJ62A. The application of magnesium AE44 alloy in the 2006 Corvette Z06 engine cradle has advanced the technology of designing robust automotive parts in magnesium. Both of these alloys are recent developments in high temperature low creep magnesium alloys. New alloy development and lower costs, which are becoming competitive to aluminium, will further the number of automotive applications.

In December 2005, for the first time on record, the automotive grade magnesium alloy price per cm³ dropped below the A380 aluminum alloy price per cm³. ^{[citation needed]}

The second application field of magnesium is electronic devices. Due to low weight, good mechanical and electrical properties, magnesium is widely used for manufacturing of mobile phones, laptops, cameras, etc. housings and other electronic components.

Historically, magnesium was one of the main aerospace construction metals. However, due to low corrosion resistance, the application of magnesium in the aerospace industry was significantly reduced during the 1960s and 70s. At the present time, magnesium has a good chance of becoming an aerospace metal again. European Community runs three R&D magnesium projects in Aerospace priority of Six Framework Program.

Other uses include:

• Removal of sulfur from iron and steel.
• Photoengraved plates in the printing industry.
• Combined in alloys, this metal is essential for airplane and missile construction.
• When used as an alloying agent, this metal improves the mechanical, fabrication and welding characteristics of aluminium.
• Additive agent for conventional propellants and used in producing nodular graphite in cast iron.
• Reducing agent for the production of pure uranium and other metals from their salts.
• Magnesium is also flammable, burning at a temperature of approximately 2500K (2200 °C, 4000 °F).
• The autoignition temperature of magnesium is approximately 744K (473°C, 883°F).
• The extremely high temperature at which magnesium burns makes it a handy tool for starting emergency fires during outdoor recreation.
• Other uses include flashlight photography, flares, pyrotechnics, sparklers, and incendiary bombs.

In magnesium compounds

• Magnesium's hydroxide is used in milk of magnesia, its chloride and citrate used as oral magnesium supplements, and its sulfate (Epsom salts) for various purposes in medicine, and elsewhere.
• Dead-burned magnesite is used for refractory purposes such as brick and liners in furnaces and converters.
• Magnesium carbonate (MgCO₃) powder is also used by athletes, such as gymnasts and weightlifters, to improve the grip on objects – the apparatus or lifting bar.
• Magnesium stearate is a slightly flammable white powder with lubricative properties. In pharmaceutical technology it is used in the manufacturing of tablets, to prevent the tablets from sticking to the equipment during the tablet compression process (i.e., when the tablet's substance is pressed into tablet form).
• The magnesium ion is necessary for all life (see magnesium in biological systems), so magnesium salts are an additive for foods, fertilizers (Mg is a component of chlorophyll), and culture media.

Precautions

Magnesium metal and alloys are highly flammable in their pure form when molten, as a powder, or in ribbon form. Burning or molten magnesium metal reacts violently with water. Magnesium powder is an explosive hazard. One should wear safety glasses while working with magnesium. The bright white light (including ultraviolet) produced by burning magnesium can damage the eyes. Water should not be used to extinguish magnesium fires, because it can actually feed the fire, according to the reaction:

Mg _(s) + 2 H₂O _(v) → Mg(OH)_{2 (aq)} + H_{2 (g)}

or in words:

Magnesium _(solid) + steam → Magnesium hydroxide _(aqueous) + Hydrogen _(gas)

Carbon dioxide fire extinguishers should not be used either, because magnesium can burn in carbon dioxide (forming magnesium oxide, MgO, and carbon). A Class D dry chemical fire extinguisher should be used if available, or else the fire should be covered with sand or magnesium foundry flux. An easy way to put out small metal fires is to place a polyethene bag filled with dry sand on top of the fire. The heat of the fire will melt the bag and the sand will flow out onto the fire.

See also

• El Mutún in Bolivia, where 70% of the world's magnesium and iron are located
• Magnesium minerals
• Magnesium compounds

External links

• WebElements.com – Magnesium
• Magnesium Deficiency
• The Magnesium Website
• Dietary Reference Intake
• Computational Chemistry Wiki
• Comprehensive online resource for magnesium metal industry professionals. Magnesium news, events, market, directory, forum, e-mail, and more.

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