Mineral

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An assortment of minerals. Photo from U.S. Geological Survey.

Minerals are inorganic crystalline compounds formed by natural processes. They range in composition from pure elements and simple salts to complex silicates with thousands of known forms. They are identified and classified according to their physical properties and chemical compositions. Many minerals are the raw materials from which metals are extracted; others are used as gemstones. Some, such as gypsum, are constituents of cement, plaster, and paint; others, such as quartz, are important for electronics and telecommunications equipment. Unfortunately, human history is also marked by examples of people who have stolen, plundered, and fought over valuable minerals. These types of interactions with nature are a result of our distorted sense of values, and ignorance of the types of relationships that can make us truly happy.

Contents

Mineral definition and classification

A mineral is defined as a naturally occurring, inorganic solid with a definite chemical composition and crystalline structure. Most minerals are formed through geochemical processes, but some (carbonates and phosphates) are produced by biological systems.

Mineral-like substances that do not strictly meet this definition are sometimes classified as mineraloids. Other naturally occurring substances are called nonminerals. "Industrial minerals" is a market term and refers to commercially valuable, mined materials.

Minerals that are closely related in composition and structure are grouped together. For example, the feldspar group of minerals, which make up as much as 60 percent of the Earth's crust, can be subdivided into potassium feldspars and plagioclase feldspars. The latter subgroup consists of a continuous series of minerals, from sodium-rich albite (NaAlSi3O8) to calcium-rich anorthite (CaAl2Si2O8), with four recognized intermediate compositions.

The quartz, mica, and feldspar groups of minerals are common, while others have been found in only one or two locations worldwide. Over half the known mineral species are so rare that they have been found in only a handful of samples, and many are known from only one or two small grains.

Atomic-scale crystal structure of olivine (magnesium iron silicate), as viewed along one axis (the a axis). Oxygen is shown in red, silicon in pink, and magnesium/iron in blue. A projection of the unit cell is indicated by the black rectangle.

The crystal structure of a mineral is the orderly, geometric arrangement of atoms or ions in the mineral's internal structure. There are 14 basic crystal lattice arrangements of atoms in three dimensions, and these are referred to as the 14 "Bravais lattices." Each of these lattices can be classified into one of the six "crystal systems." All currently recognized crystal structures fit into one Bravais lattice and one crystal system. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by a technique known as X-ray diffraction.

The typical, outward appearance of a mineral is called the "crystal habit." Some crystal habits are distinctive of certain minerals, but in most cases, a mineral exhibits a variety of habits that are influenced by the growth conditions of the crystals. A mineral may show good crystal habit or form, or it may be massive, granular, or compact with only microscopically visible crystals. An inexperienced observer may be misled by a mineral's crystal habit, as the crystal system can be hidden or disguised.

Chemistry and crystal structure (and crystal habit) together define a mineral. The task of classification can range from being simple to complex. In some cases, knowledge of some properties may be sufficient for complete identification. In other cases, classification of a mineral may require more complex chemical or X-ray diffraction analyses. These methods can be costly and time-consuming, and may risk damaging the sample.

When two or more minerals have the same chemical composition but differ in crystal structure, they are known as polymorphs. For example, pyrite and marcasite are both iron sulfide, but their arrangement of atoms differs. Similarly, some minerals have different chemical compositions but the same crystal structure. For example, halite (made from sodium and chlorine), galena (made from lead and sulfur), and periclase (made from magnesium and oxygen) share the same cubic crystal structure.

Crystal structure greatly influences a mineral's physical properties. For example, both diamond and graphite are pure carbon), but graphite is very soft, while diamond is the hardest of all known minerals. The reason for this difference is that the carbon atoms in graphite are arranged into sheets that can easily slide past one another, while the carbon atoms in diamond form a strong, interlocking three-dimensional network.

There are currently just over 4,000 known minerals, according to the International Mineralogical Association, which is responsible for the approval and naming of newly discovered mineral species.

Rocks

A rock is an aggregate of two or more minerals, and it may also include organic remains. In some rocks, one mineral may be predominant. For example, limestone is a sedimentary rock composed almost entirely of the mineral calcite. Other rocks contain many minerals, and the specific minerals in a rock can vary widely.

Physical properties

When identifying and classifying a mineral, the following physical properties are taken into consideration.

  • Crystal structure and habit, noted above.
Talc is an extremely soft mineral, with a hardness of 1 on the Mohs scale.
  • The physical hardness (scratch resistance) of a mineral is usually measured on the Mohs scale, which ranges from 1 to 10. A mineral with a given Mohs hardness can scratch the surface of any mineral ranked lower in hardness. Certain minerals have been chosen to define the scale, as given below.
1- talc
2- gypsum
3- calcite
4- fluorite
5- apatite
6- orthoclase feldspar
7- quartz
8- topaz
9- corundum
10- diamond
Galena (lead sulfide) has a metallic luster.
  • Luster indicates the way the mineral's surface interacts with light. It can range from metallic to glassy (vitreous) to dull.
Metallic - high reflectivity like metal (e.g., galena)
Sub-metallic - slightly less than metallic reflectivity (e.g., magnetite)
Vitreous - the luster of broken glass (e.g., quartz)
Pearly - very soft light shown by some layer silicates (e.g., talc)
Silky - soft light shown by fibrous materials (e.g., gypsum)
Dull/earthy - shown by finely crystallized minerals (e.g., kidney ore variety of hematite)
  • Color indicates the mineral's appearance as observed by the naked eye. Technically, it means the color of reflected light, if the mineral is opaque, or the color of transmitted light, if the mineral is translucent.
  • Streak refers to the color of the powder produced from a mineral after it has been rubbed on an unglazed porcelain streak plate.
  • Cleavage describes the way a mineral may split apart along various planes. In thin section, cleavage is visible as thin, parallel lines across a mineral.
  • Fracture describes how a mineral breaks when broken contrary to its natural cleavage planes. For example, a chonchoidal fracture is a smooth fracture with concentric ridges of the type shown by glass.
  • Specific gravity corresponds to the density of the material compared to that of water. Most minerals, including all rock-forming minerals, have a specific gravity of 2.5–3.5. Some, however, are noticeably more or less dense. For example, the specific gravity of several sulphide minerals is higher than that of the common, rock-forming minerals.
  • Other properties: fluorescence (response to ultraviolet light), magnetism, radioactivity, tenacity (response to mechanically induced changes of shape or form), and reactivity to dilute acids.

Chemical properties

The classification of minerals is also based on their chemical composition. Here they are categorized by their anion groups. The list below, which follows the Dana classification system, is in approximate order of abundance of the minerals in the Earth's crust.

Silicate class

The mica group of minerals belongs to the silicate class.

The largest group of minerals by far are the silicates (most rocks are more than 95 percent silicates). They are composed largely of silicon and oxygen, with the addition of ions such as aluminum, magnesium, iron, and calcium. Some important rock-forming silicates include the following groups: feldspars, quartz, olivines, pyroxenes, amphiboles, garnets, and micas.

Carbonate class

The carbonate minerals consist of those that contain the anion CO32-. They include calcite and aragonite (both calcium carbonate), dolomite (magnesium/calcium carbonate), and siderite (iron carbonate). Carbonates are commonly formed by marine organisms that secrete shells. When these organisms die, their shells settle out of the water and accumulate on the seafloor. Carbonates are also found in evaporitic settings (for example, the Great Salt Lake, Utah) and in karst regions, where the dissolution and reprecipitation of carbonates leads to the formation of caves, stalactites and stalagmites. The carbonate class includes the nitrate and borate minerals.

Sulfate class

Anhydrite is a sulfate mineral (anhydrous calcium sulfate). This sample came from Chihuahua, Mexico.

The sulfates contain the sulfate anion, SO42-. Sulfates commonly form in evaporitic settings, where highly saline waters slowly evaporate, allowing the formation of sulfates and halides at the water-sediment interface. Sulfates also occur in hydrothermal vein systems as gangue minerals, along with sulfide ore minerals. Another occurrence is as secondary oxidation products of original sulfide minerals. Common sulfates include anhydrite (calcium sulfate), celestite (strontium sulfate), barite (barium sulfate), and gypsum (hydrated calcium sulfate). The sulfate class also includes the chromate, molybdate, selenate, sulfite, tellurate, and tungstate minerals.

Halide class

The halides are a group of minerals that form salts such as fluorite (calcium fluoride), halite (sodium chloride), sylvite (potassium chloride), and sal ammoniac (ammonium chloride). Like the sulfates, halides are commonly found in evaporitic settings such as playa lakes (lakebeds that are usually dry) and landlocked seas, such as the Dead Sea and Great Salt Lake. The halide class includes the fluoride, chloride, and iodide minerals.

Oxide class

Oxides are extremely important in mining, as they form many of the ores from which valuable metals are extracted. They commonly occur as precipitates close to the Earth's surface, oxidation products of other minerals in the near-surface weathering zone, and as accessory minerals in igneous rocks of the crust and mantle. Common oxides include hematite (iron oxide), magnetite (iron oxide), chromite (chromium oxide), spinel (magnesium aluminium oxide, a common component of the mantle), rutile (titanium dioxide), and ice (hydrogen oxide). The oxide class includes the hydroxide minerals.

Sulfide class

Pyrite (iron disulfide), also known as fool's gold, is a sulfide mineral. Shown here is a mass of intergrown pyrite crystals.

Many sulfides are economically important as metal ores. Common sulfides include pyrite (iron sulfide, also known as fool's gold), chalcopyrite (copper iron sulfide), pentlandite (nickel iron sulfide), and galena (lead sulfide). The sulfide class also includes the selenides, tellurides, arsenides, antimonides, bismuthinides, and sulfo salts (containing sulfide and a second anion such as arsenide).

Phosphate class

The phosphate mineral group includes any mineral in which the anion takes the tetrahedral form AO4-n, where A can be phosphorus, antimony, arsenic or vanadium. The most common group of phosphates is apatite, consisting mainly of hydroxyapatite (hydroxylapatite), fluorapatite, and chlorapatite. Hydroxyapatite is an important biological mineral found in the teeth and bones of many animals.

Element class

The element group includes metals, metalloids, and nonmetals. Minerals in this group include gold, silver, copper, antimony, bismuth, graphite, and sulfur. This group also includes naturally occurring alloys (such as electrum, an alloy of gold and silver), phosphides, silicides, nitrides, and carbides (which are found naturally in a few, rare meteorites).

Uses

Minerals are extremely valuable for a wide variety of uses. Many of them are ores from which key elements are purified. Others are used as ornamental stones. Examples of the uses of some minerals are given below.

  • Chalcopyrite (copper iron sulfide) is an important ore of copper.
  • Chromite (iron magnesium chromium oxide) is the main ore of chromium and is also used as a refractory material.
  • Diamond (a carbon allotrope) is mined for its high value as a gemstone, but it is also an excellent abrasive.
  • Dolomite (calcium magnesium carbonate) is used as an ornamental stone and for cement manufacture.
  • Fluorite (calcium fluoride) is used to make opalescent glass, enamels for cooking utensils, and hydrofluoric acid, which etches glass.
  • Galena (lead sulfide) is a common ore of lead.
  • Gypsum (calcium sulfate dihydrate) is a constituent of blackboard chalk, cement, plaster, paint filler, pharmaceuticals, toothpaste, and more. It is also a calcium additive in breads and cereals.
  • Hematite (iron oxide) is the main ore of iron.
  • Mica (a group of silicates) is useful for making capacitors and electrical insulators.
  • Orthoclase feldspar (potassium aluminum silicate) is used to manufacture porcelain and is a component of scouring powder.
  • Pyrite (iron disulfide, fool's gold) is used in making jewelry and producing sulfur dioxide and sulfuric acid.
  • Quartz (silicon dioxide, with many varieties) has many uses, such as to make crystal oscillators for wristwatches and integrated circuits, precision mirrors for telescopes, and optical fibers for telecommunications. Several varieties of quartz are used as gemstones.

See also

  • Mineral water, water containing minerals or other dissolved substances that alter its taste or give it therapeutic value
  • Mining
  • Quarry
  • Dietary mineral

External links

All links retrieved November 3, 2014.

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