Corundum

Corundum
Corundum USGOV.jpg
General
Category Mineral
Chemical formula aluminum oxide, Al2O3
Identification
Color Brown to grey, less often red, blue, white, yellow.
Crystal habit Steep bipyramidal, tabular, prismatic, rhombohedral crystals, massive or granular
Crystal system Trigonal Hexagonal Scalenohedral bar32/m
Twinning Polysynthetic twinning common
Cleavage None - parting in three directions
Fracture Conchoidal to uneven
Mohs Scale hardness 9
Luster Adamantine to vitreous
Refractive index nω=1.768 - 1.772 nε=1.760 - 1.763, Biref 0.009
Pleochroism None
Streak White
Specific gravity 3.95-4.1
Fusibility Infusible
Solubility Insoluble
Major varieties
Sapphire Any color except red
Ruby Red
Emery Granular

Corundum is a crystalline form of aluminum oxide and a rock-forming mineral. It is naturally clear but can have different colors when impurities are present. It is superior in hardness and therefore useful as an abrasive. In addition, transparent, colored specimens are valued as gems. These gemstones are called ruby, if red, or sapphires, for colors other than red.

Contents

The word "corundum" comes from the Tamil kurundam.

Occurrence

Corundum occurs as an accessory mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low silica igneous syenite and nepheline syenite intrusives. Other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites. Because of its hardness and resistance to weathering, it commonly occurs as a detrital mineral in stream and beach sands.

Corundum for abrasives is mined in Zimbabwe, Russia, and India. Historically it was mined from deposits associated with dunites in North Carolina and from a nepheline syenite in Craigmont, Ontario. Emery grade corundum is found on the Greek island of Naxos and near Peekskill, New York. Abrasive corundum is synthetically manufactured from bauxite.

Characteristics

Compared to most minerals, corundum is superior in hardness, rated as 9.0 Mohs. Its hardness is explained based on the structure of its crystals. The oxygen atoms are arranged in a hexagonal close-packing arrangement, with the smaller aluminum atoms occupying two-thirds of the octahedral gaps.

In addition to its hardness, the density of corundum is unusually high for a transparent mineral composed of the low atomic mass elements aluminum and oxygen. Its density is 4.02 g/cm3.

Applications

Given its high degree of hardness, corundum is commonly used as an abrasive, for applications ranging from huge machines to sandpaper. Some emery is a mix of corundum and other substances, and the mix is less abrasive, with an average Mohs hardness near 8.0. Also, as mentioned above, rubies and sapphires are different forms of corundum and they are valued as gemstones.

Synthetic Corundum

Gem-quality synthetic corundum is usually produced by the flame-fusion method (also called the Verneuil process). This allows the production of large quantities of sapphires and rubies. It is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Because of the simplicity of the methods involved in corundum synthesis, large quantities of these crystals became available on the market, significantly reducing the price in recent years. Apart from ornamental use, synthetic corundum (that is, sapphire) is also used to produce mechanical parts (tubes, rods, bearings, and other machined parts) and lasers.

Emery

Emery is a very hard rock type used to make abrasive powder. It consists largely of corundum, mixed with other species such as the iron-bearing spinels hercynite and magnetite, and also rutile (titania). Industrial emery may contain a variety of other minerals and synthetic compounds such as magnesia, mullite, and silica.

It is black or dark gray in color, less dense than translucent-brown corundum with a specific gravity of between 3.5 and 3.8. Because it can be a mix of minerals, no definite Mohs hardness can be assigned: the hardness of corundum is 9 and that of some spinel-group minerals is near 8, but the hardness of others such as magnetite is near 6.

Crushed or naturally eroded emery (known as black sand) is used as an abrasive—for example, on an emery board, as a traction enhancer in asphalt and tarmac mixtures, or as used in mechanical engineering as Emery cloth.

The Greek island of Naxos used to be the main source of this industrially important rock type. It has been mined on the eastern side of Naxos for well over two thousand years until recent times. However, demand for emery has decreased with the development of sintered carbide and oxide materials as abrasives.

See also

References

  • Farndon, John. 2006. The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks. Lorenz Books. ISBN 0754815412
  • Hurlbut, Cornelius S. and Cornelis Klein. 1985. Manual of Mineralogy (20th ed.). New York: John Wiley and Sons. ISBN 0471805807
  • Pellant, Chris. 2002. Smithsonian Handbooks: Rocks and Minerals. New York: DK Adult. ISBN 0789491060
  • Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman, 2001. Rocks, Gems and Minerals. Revised and updated edition. St. Martin's Press, Golden Guide. ISBN 1582381321

External links

All links retrieved March 24, 2017.

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