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Butane-2D-Skeletal.svg Butane-3D-space-filling.png
CAS number [106-97-8]
Molecular formula C4H10
Molar mass 58.124 g/mol
Appearance Colorless gas
Density 2.48 g/l, gas (15 °C, 1 atm)
Melting point

−138.4 °C (135.4 K)

Boiling point

−0.5 °C (272.6 K)

Solubility in water 6.1 mg/100 ml (20 °C)
EU classification Highly flammable (F+)
NFPA 704

NFPA 704.svg

Flash point −60 °C
Related Compounds
Related alkanes Propane; Pentane
Related compounds Isobutane; Cyclobutane
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Butane, also called n-butane (normal butane), is an unbranched alkane with four carbon atoms in each molecule. Its molecular formula may be written as CH3CH2CH2CH3. Butane is also used as a collective term for both n-butane and its only other isomer, isobutane (also called i-butane or methylpropane), CH(CH3)3. Both isomers of butane are highly flammable, colorless gases at ordinary temperatures and atmospheric pressure. They can be extracted from natural gas or obtained by refining petroleum.

Butane is useful for many applications. Bottled butane gas is a fuel for cooking and camping. It is also used as a component of gasoline (petrol), as a feedstock component for the production of base petrochemicals in steam cracking, and as a fuel for cigarette lighters. When butane is blended with propane and other hydrocarbons, the mixture is referred to commercially as liquefied petroleum gas (LPG), which is a fuel for heating appliances and vehicles.


Recent concerns regarding depletion of the ozone layer by freon gases (chlorofluorocarbons or halomethanes) have led to increased use of isobutane and LPG as refrigerants, especially in domestic refrigerators and freezers, and as propellants in aerosol sprays.

Isobutane1.png Isobutane2.png
IUPAC name Isobutane
Other names 2-Methylpropane
CAS number [75-28-5]
Molecular formula C4H10
Molar mass 58.12 g mol-1
Appearance colorless gas
Density 2.51 g/l, gas (15 °C, 1 atm);593.4 kg · m-3, liquid
Melting point

-159.6 °C, 114 K, -255 °F

Boiling point

-11.7 °C, 261 K, 11 °F

Solubility in water Insoluble
MSDS External MSDS
EU classification Highly flammable (F+)
NFPA 704

NFPA 704.svg

R-phrases R12
S-phrases S2, S9, S16
Flash point flammable gas
460 °C
Explosive limits 1.8–8.4 percent
Related Compounds
Related alkane Butane
Related compounds Isopentane
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)


The name butane was derived by back-formation from the name butyric acid. The latter is a carboxylic acid with four carbon atoms, including the carbon atom in the carboxyl group. The molecular formula of butyric acid may be written as CH3CH2CH2COOH.


At ordinary temperatures and pressures, n-butane is a colorless gas. Its boiling point is −0.5 °C (272.6 K), and its melting point is −138.4 °C (135.4 K). Likewise, i-butane, the structural isomer of n-butane is a colorless gas, with a boiling point of -11.7 °C (261 K) and a melting point of -159.6 °C (114 K). Both isomeric forms can be readily liquefied at room temperature by compression.

Structural isomers

A molecule of either isomer, n-butane or i-butane, is made up of four carbon atoms and ten hydrogen atoms, so their common molecular formula is C4H10. However, the molecular structures of these isomers differ. In particular, a molecule of n-butane consists of a linear arrangement of the four carbon atoms, so that it can also be represented as CH3-CH2-CH2-CH3. By contrast, a molecule of i-butane has three carbon atoms attached directly to a central carbon atom. The structures of these two isomers are shown in the diagrams below.


When oxygen is plentiful, butane burns to form carbon dioxide and water vapor; when oxygen is limited, carbon (soot) or carbon monoxide may also be formed. The reaction may be written as follows:

2C4H10 + 13O2 → 8CO2 + 10H2O

n-Butane is the feedstock for DuPont's catalytic process for the preparation of maleic anhydride (C2H2(CO)2O), as shown by the following reaction:

CH3CH2CH2CH3 + 3.5O2 → C2H2(CO)2O + 4H2O

n-Butane, like all hydrocarbons, undergoes free radical chlorination producing both 1-chlorobutane and 2-chlorobutane, as well as more highly chlorinated derivatives.

Spectrum of the blue flame from a butane torch showing molecular radical band emission and Swan bands.


A butane gas cylinder that may be used for cooking.

Butane gas is sold bottled as a fuel for cooking and camping. When blended with propane and other hydrocarbons, it is referred to commercially as Liquified Petroleum Gas (LPG). It is also used as a component of gasoline (petrol), as a feedstock for the production of base petrochemicals in steam cracking, and as a fuel for cigarette lighters.

The highly purified form of isobutane is useful as a refrigerant and as a propellant in aerosol sprays. It is used, for instance, in household refrigerators and freezers, largely replacing the halomethanes that are believed to deplete the ozone layer. When used as a refrigerant or propellant, isobutane may be referred to as R-600a. It is also used as a feedstock in the petrochemical industry, such as for the synthesis of isooctane.[1]

When used as a refrigerant, the flammability of isobutane is not a major issue because the amount of this substance in an appliance is not enough to cause a combustible mix, given the amount of air in a room. The system operating pressure for butane is lower than that for the halomethanes, such as Dichlorodifluoromethane (R-12). Thus, the direct conversion of R-12 systems to butane, such as in automotive air conditioning systems, will not function optimally.

Effects and health issues

Inhaling butane can cause drowsiness, narcosis, asphyxia, cardiac arrhythmia, and frostbite. Inhalation can lead to instant death from asphyxiation. Butane is the most commonly misused volatile solvent in the UK, and was the cause of 52 percent of solvent-related deaths in 2000.[2] If butane is sprayed directly into the throat, the jet of fluid may cool rapidly to –20 °C by expansion, causing prolonged laryngospasm.[3] "Sudden Sniffer's Death syndrome," first described by Bass in 1970,[4] is the most common single cause of solvent-related death, resulting in 55 percent of known fatal cases.

See also


  1. www.chemistry.org, Patent Watch, July 31, 2006. Retrieved May 20, 2008.
  2. M.E. Field-Smith, B.K. Butland, J.D. Ramsey, and H.R. Anderson, Trends in Death Associated with Abuse of Volatile Substances 1971-2004, Report 19, Division of Community Health Sciences. Retrieved May 20, 2008.
  3. J. Ramsey, H.R. Anderson, K. Bloor, et al. An introduction to the practice, prevalence and chemical toxicology of volatile substance abuse. Hum. Toxicol. 8:261–269.
  4. M. Bass, Sudden sniffing death. JAMA 212: 2075–79.


  • McMurry, John. Organic Chemistry, 6th ed. Belmont, CA: Brooks/Cole, 2004. ISBN 0534420052.
  • Morrison, Robert T., and Robert N. Boyd. Organic Chemistry, 6th ed. Englewood Cliffs, NJ: Prentice Hall, 1992. ISBN 0136436692.
  • Olah, George A., and Árpád Molnár. Hydrocarbon Chemistry. Hoboken, NJ: Wiley-Interscience, 2003. ISBN 978-0471417828.
  • Solomons, T.W. Graham, and Craig B. Fryhle. Organic Chemistry, 8th ed. Hoboken, NJ: John Wiley, 2004. ISBN 0471417998.
  • Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 41,000 Organic and Inorganic Chemical Compounds: Coverage for C1 to C100 Organics and Ac to Zr Inorganics. Houston: Gulf Pub. Co., 2005. ISBN 978-0976511373.

External links

All links retrieved September 22, 2013.


























E numbers    
Colours (E100-199) • Preservatives (E200-299) • Antioxidants & Acidity regulators (E300-399) • Thickeners, stabilisers & emulsifiers (E400-499) • pH regulators & anti-caking agents (E500-599) • Flavour enhancers (E600-699) • Miscellaneous (E900-999) • Additional chemicals (E1100-1599)

Waxes (E900-909) • Synthetic glazes (E910-919) • Improving agents (E920-929) • Packaging gases (E930-949) • Sweeteners (E950-969) • Foaming agents (E990-999)

Argon (E938) • Helium (E939) • Dichlorodifluoromethane (E940) • Nitrogen (E941) • Nitrous oxide (E942) • Butane (E943a) • Isobutane (E943b) • Propane (E944) • Oxygen (E948) • Hydrogen (E949)


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