Difference between revisions of "Sphalerite" - New World Encyclopedia

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[[Image:Sphalerite4.jpg|thumb|Sphalerite sample]]
 
[[Image:Sphalerite2.jpg|thumb|Another sphalerite sample]]
 
[[Image:Sphalerite-unit-cell-3D-balls.png|thumb|The unit cell of sphalerite]]
 
  
'''Sphalerite''' is a [[mineral]] that consists largely of [[zinc sulfide]] (ZnS) in [[crystal]]line form, but it almost always contains variable amounts of [[iron]]. It is the chief [[ore]] of [[zinc]]. When iron content is high it is an opaque black variety, '''marmatite''' ((Zn,Fe)S). It is usually found in association with [[galena]], [[pyrite]], and other [[sulfide]]s along with [[calcite]], [[dolomite]], and [[fluorite]]. Miners have referred to sphalerite as ''zinc blende'', ''mock lead'', ''false galena'', and ''black-jack''.
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[[Image:Sphalerite4.jpg|thumb|The black color of this sphalerite sample indicates a high [[iron]] content.]]
  
The mineral crystallizes in the [[cubic (crystal system)|cubic]] [[crystal system]]. In the crystal structure, zinc and sulfur atoms are tetrahedrally coordinated. The structure is closely related to the structure of [[diamond]]. The [[hexagonal (crystal system)|hexagonal]] analog is known as the [[wurtzite]] structure. The lattice constant for zinc sulfide in the zincblende crystal structure is 0.542 [[nanometer|nm]].
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'''Sphalerite''' is a [[mineral]] that consists largely of [[zinc sulfide]] in [[crystal]]line form, but it almost always contains variable amounts of [[iron]]. Its chemical formula may therefore be written as (Zn,Fe)S. Its color is usually yellow, brown, or gray to gray-black, and it may be shiny or dull. This mineral is the chief [[ore]] of [[zinc]], the fourth most common metal in use. In addition, appropriate crystals of sphalerite have been fashioned into [[gemstone]]s.
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[[Image:Sphalerite2.jpg|thumb|The various colors of this sphalerite sample indicate the presence of various impurities.]]
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[[Image:Sphalerite-unit-cell-3D-balls.png|thumb|The unit cell in a [[crystal]] of sphalerite.]]
  
Its color is usually yellow, brown, or gray to gray-black, and it may be shiny or dull.  Its [[luster]] is resinous.  It has a yellow or light brown [[Mineral#Streak|streak]], a [[Mohs hardness scale|hardness]] of 3.5 - 4, and a [[specific gravity]] of 3.9-4.1.  Some specimens have a red [[iridescence]] within the gray-black crystals; these are called "ruby sphalerite." The pale yellow and red varieties have very little iron and are translucent.  The darker more opaque varieties contain more iron. Some specimens are also [[fluorescence|fluorescent]] in [[ultraviolet]] light. The [[refractive index]] of sphalerite (as measured via [[sodium light]], 589.3 nm) is 2.37. Sphalerite crystallizes in the [[Cubic (crystal system)|isometric]] crystal system and possesses perfect dodecahedral [[Cleavage (crystal)|cleavage]]. Gemmy, pale specimens from [[Franklin, New Jersey]] are highly fluorescent orange or blue under longwave ultraviolet light and are known as ''cleiophane'', an almost pure ZnS variety.
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== Occurrence ==
  
Crystals of suitable size and transparency have been fashioned into [[gemstone]]s, usually featuring the [[brilliant (diamond cut)|brilliant cut]] to best display sphalerite's high [[dispersion (optics)|dispersion]] of 0.156 (B-G interval)—over three times that of [[diamond]]. Freshly cut gems are lively with an adamantine luster and could conceivably be mistaken for a fancy-colored diamond in passing, but due to sphalerite's softness and fragility the gems are best left unset as collector's or [[museum]] pieces (although some have been set into pendants). Collectors may pay a premium for stones over one [[carat (mass)|carat]] (200 mg), as clean crystals are usually quite small. Gem-quality material is usually a yellowish to honey brown, red to orange, or green; the two most important sources are the Chivera mine, [[Cananea]], [[Sonora]], [[Mexico]]; and the [[Picos de Europa]], [[Cordillera Cantabrica]], near [[Santander, Cantabria|Santander]] on [[Spain]]'s northern coast.
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Sphalerite is usually found in association with other minerals, particularly [[galena]], [[pyrite]], and other [[sulfide]]s, along with [[calcite]], [[dolomite]], and [[fluorite]]. Miners have referred to sphalerite as ''zinc blende'', ''mock lead'', ''false galena'', and ''black-jack''.
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Significant quantities of this mineral have been found in many parts of the world, including [[Australia]], [[Burma]], [[Germany]], [[England]], [[Italy]], [[Spain]], and [[Peru]]. In the [[United States]], it is found in Elmwood, Tennessee; Joplin, Missouri; and Rosiclare, Illinois.
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== Properties ==
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As noted above, sphalerite can be found in various colors, particularly yellow, brown, and gray to gray-black. It has a yellow or light brown [[Mineral#Streak|streak]]. Its [[Mohs hardness scale|hardness]] rating is 3.5-4 on the Mohs scale, its [[specific gravity]] is 3.9-4.1, and its [[refractive index]] is 2.37 (when measured using [[sodium light]] at 589.3 nanometers). Its [[dispersion (optics)|dispersion]] of light is more than three times that of [[diamond]].
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Some specimens, called "ruby sphalerite," have a red [[iridescence]] within the gray-black crystals. The pale yellow and red varieties have very little [[iron]] and are translucent. The darker, more opaque varieties contain more iron. An opaque, black variety with a high iron content is known as ''marmatite''. Gemmy, pale specimens (such as from [[Franklin, New Jersey]]) are highly fluorescent orange or blue under longwave ultraviolet light and are known as ''cleiophane'', an almost pure variety of zinc sulfide.
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Sphalerite crystallizes in the [[Cubic (crystal system)|isometric]] crystal system and possesses perfect dodecahedral [[Cleavage (crystal)|cleavage]]. In the crystal structure, [[zinc]] and [[sulfur]] [[atom]]s are tetrahedrally coordinated. This structure is closely related to that of [[diamond]].
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Two other minerals, [[wurtzite]] and matraite, are polymorphs of sphalerite. They share the same chemistry (zinc iron sulfide) but have different crystalline structures.
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== Uses ==
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Sphalerite is mainly used for the extraction of zinc, the fourth most common metal in use, trailing only [[iron]], [[aluminum]], and [[copper]] in annual production. In addition, crystals of suitable size and transparency have been fashioned into [[gemstone]]s, usually featuring the [[brilliant (diamond cut)|brilliant cut]] to best display the stone's high optical [[dispersion (optics)|dispersion]]. Freshly cut gems have a lively, adamantine luster and could be mistaken for fancy-colored diamonds, but given sphalerite's softness and fragility, the gems are best left unset as collector's items or [[museum]] pieces. Some specimens, however, have been set into pendants. Gem-quality material is usually a yellowish to honey brown, red to orange, or green; the two most important sources are the Chivera mine, [[Cananea]], [[Sonora]], [[Mexico]]; and the [[Picos de Europa]], [[Cordillera Cantabrica]], near [[Santander, Cantabria|Santander]] on [[Spain]]'s northern coast.
  
 
== See also ==
 
== See also ==
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==References==
 
==References==
  
* Farndon, John. 2006. ''The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks''. London: Lorenz Books. ISBN 0754815412.
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* Farndon, John. 2006. ''The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks''. London: Lorenz Books. ISBN 0754815412
 
+
* Klein, Cornelis, and Barbara Dutrow. 2007. ''Manual of Mineral Science''. 23rd ed. New York: John Wiley. ISBN 978-0471721574
* Klein, Cornelis, and Barbara Dutrow. 2007. ''Manual of Mineral Science''. 23rd ed. New York: John Wiley. ISBN 978-0471721574.
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* Mindat.org. 2007. [http://www.mindat.org/min-3727.html Sphalerite] ''Mindat.org''. Retrieved November 7, 2007.
 
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* Mineral Gallery. 2006. The Mineral Sphalerite ''Amethyst Galleries''.
* Pellant, Chris. 2002. ''Rocks and Minerals''. Smithsonian Handbooks. New York: Dorling Kindersley. ISBN 0789491060.
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* Pellant, Chris. 2002. ''Rocks and Minerals''. Smithsonian Handbooks. New York: Dorling Kindersley. ISBN 0789491060
 
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* Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. 2001. ''Rocks, Gems and Minerals''. Rev. ed. New York: St. Martin's Press. ISBN 1582381321
* Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. 2001. ''Rocks, Gems and Minerals''. Rev. ed. New York: St. Martin's Press. ISBN 1582381321.
 
 
 
* Mindat.org. 2007. [http://www.mindat.org/min-3727.html Sphalerite.] ''Mindat.org''. Retrieved April 10, 2007.
 
 
 
* Mineral Gallery. 2006. [http://mineral.galleries.com/minerals/sulfides/sphaleri/sphaleri.htm The Mineral Sphalerite.] ''Amethyst Galleries''. Retrieved April 10, 2007.
 
  
 
==External links==
 
==External links==
 
+
All links retrieved February 7, 2023.
* [http://www.minerals.net/mineral/sulfides/sphaleri/sphaleri.htm Sphalerite - Minerals.net.] Retrieved April 10, 2007.
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* [http://www.minerals.net/mineral/sulfides/sphaleri/sphaleri.htm Sphalerite - Minerals.net]  
 
 
* [http://simplethinking.com/palache/sphalerite.stm Sphalerite - The Minerals of Franklin and Sterling Hill, New Jersey.] Retrieved April 10, 2007.
 
 
 
* [http://cst-www.nrl.navy.mil/lattice/struk/b3.html The Zincblende (B3) Structure.] Retrieved April 10, 2007.
 
  
 
[[Category:Physical sciences]]
 
[[Category:Physical sciences]]

Latest revision as of 15:21, 27 April 2023


The black color of this sphalerite sample indicates a high iron content.

Sphalerite is a mineral that consists largely of zinc sulfide in crystalline form, but it almost always contains variable amounts of iron. Its chemical formula may therefore be written as (Zn,Fe)S. Its color is usually yellow, brown, or gray to gray-black, and it may be shiny or dull. This mineral is the chief ore of zinc, the fourth most common metal in use. In addition, appropriate crystals of sphalerite have been fashioned into gemstones.

The various colors of this sphalerite sample indicate the presence of various impurities.
The unit cell in a crystal of sphalerite.

Occurrence

Sphalerite is usually found in association with other minerals, particularly galena, pyrite, and other sulfides, along with calcite, dolomite, and fluorite. Miners have referred to sphalerite as zinc blende, mock lead, false galena, and black-jack.

Significant quantities of this mineral have been found in many parts of the world, including Australia, Burma, Germany, England, Italy, Spain, and Peru. In the United States, it is found in Elmwood, Tennessee; Joplin, Missouri; and Rosiclare, Illinois.

Properties

As noted above, sphalerite can be found in various colors, particularly yellow, brown, and gray to gray-black. It has a yellow or light brown streak. Its hardness rating is 3.5-4 on the Mohs scale, its specific gravity is 3.9-4.1, and its refractive index is 2.37 (when measured using sodium light at 589.3 nanometers). Its dispersion of light is more than three times that of diamond.

Some specimens, called "ruby sphalerite," have a red iridescence within the gray-black crystals. The pale yellow and red varieties have very little iron and are translucent. The darker, more opaque varieties contain more iron. An opaque, black variety with a high iron content is known as marmatite. Gemmy, pale specimens (such as from Franklin, New Jersey) are highly fluorescent orange or blue under longwave ultraviolet light and are known as cleiophane, an almost pure variety of zinc sulfide.

Sphalerite crystallizes in the isometric crystal system and possesses perfect dodecahedral cleavage. In the crystal structure, zinc and sulfur atoms are tetrahedrally coordinated. This structure is closely related to that of diamond.

Two other minerals, wurtzite and matraite, are polymorphs of sphalerite. They share the same chemistry (zinc iron sulfide) but have different crystalline structures.

Uses

Sphalerite is mainly used for the extraction of zinc, the fourth most common metal in use, trailing only iron, aluminum, and copper in annual production. In addition, crystals of suitable size and transparency have been fashioned into gemstones, usually featuring the brilliant cut to best display the stone's high optical dispersion. Freshly cut gems have a lively, adamantine luster and could be mistaken for fancy-colored diamonds, but given sphalerite's softness and fragility, the gems are best left unset as collector's items or museum pieces. Some specimens, however, have been set into pendants. Gem-quality material is usually a yellowish to honey brown, red to orange, or green; the two most important sources are the Chivera mine, Cananea, Sonora, Mexico; and the Picos de Europa, Cordillera Cantabrica, near Santander on Spain's northern coast.

See also

References
ISBN links support NWE through referral fees

  • Farndon, John. 2006. The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks. London: Lorenz Books. ISBN 0754815412
  • Klein, Cornelis, and Barbara Dutrow. 2007. Manual of Mineral Science. 23rd ed. New York: John Wiley. ISBN 978-0471721574
  • Mindat.org. 2007. Sphalerite Mindat.org. Retrieved November 7, 2007.
  • Mineral Gallery. 2006. The Mineral Sphalerite Amethyst Galleries.
  • Pellant, Chris. 2002. Rocks and Minerals. Smithsonian Handbooks. New York: Dorling Kindersley. ISBN 0789491060
  • Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. 2001. Rocks, Gems and Minerals. Rev. ed. New York: St. Martin's Press. ISBN 1582381321

External links

All links retrieved February 7, 2023.

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