Lawrencium


103 nobeliumlawrenciumrutherfordium
Lu

Lr

(Upt)
Lr-TableImage.png
General
Name, Symbol, Number lawrencium, Lr, 103
Chemical series actinides
Group, Period, Block n/a, 7, d
Appearance unknown, probably silvery
white or metallic gray
Atomic mass (262) g/mol
Electron configuration probably [Rn] 5f14 7s2 6d1
Electrons per shell 2, 8, 18, 32, 32, 8, 3
Physical properties
Phase presumably a solid
Melting point 1900 K
(1627 °C, 2961 °F)
Atomic properties
Oxidation states 3
Electronegativity 1.3 (Pauling scale)
Ionization energies 1st: 470 kJ/mol
Miscellaneous
CAS registry number 22537-19-5
Notable isotopes
Main article: Isotopes of lawrencium
iso NA half-life DM DE (MeV) DP
262Lr syn ~4 h

Lawrencium (chemical symbol Lr, atomic number 103), once known as eka-lutetium, is a radioactive synthetic element in the periodic table. Its most stable isotope is 262Lr, with a half-life of approximately four hours. It is synthesized from californium and is of interest mainly for research purposes. It has no practical applications at this time.

Contents

Etymology

The origin of the name, preferred by the American Chemical Society, is in reference to Ernest O. Lawrence, inventor of the cyclotron. The symbol Lw was originally used but in 1963 it was changed to Lr. In August 1997, the International Union of Pure and Applied Chemistry (IUPAC) ratified the name lawrencium and symbol Lr during a meeting in Geneva. Unniltrium was sometimes used as a temporary, systematic element name until that time.

History

Lawrencium was discovered by Albert Ghiorso, Torbjørn Sikkeland, Almon Larsh and Robert M. Latimer on February 14, 1961, at the Berkeley Radiation Laboratory (now called Lawrence Berkeley National Laboratory) on the University of California, Berkeley campus. It was produced by bombarding a three milligram target composed of three isotopes of californium with boron-10 and boron-11 ions in the Heavy Ion Linear Accelerator (HILAC).

The transmutation nuclei became electrically charged, recoiled with a helium atmosphere and were collected on a thin copper conveyor tape. This tape was then moved in order to place the collected atoms in front of a series of solid-state detectors. The Berkeley team reported that the isotope 257103 was detected in this manner and decayed by emitting an 8.6 MeV alpha particle with a half-life of 4.2 seconds.

In 1967, researchers in Dubna, Russia reported that they were not able to confirm an alpha emitter with a half-life of 4.2 seconds as 257103. This assignment has since been changed to 258Lr or 259Lr. Eleven isotopes of element 103 have been synthesized with 262Lr being the longest lived, with a half-life of 216 minutes (it decays into 256No). The isotopes of lawrencium decay via alpha emission, spontaneous fission, and electron capture (in order of most to least common types).

Notable characteristics

If one were to follow a strict correlation between periodic table blocks and chemical series for neutral atoms, lawrencium would be described as a transition metal because it is in the d-block. The International Union of Pure and Applied Chemistry (IUPAC), however, recommends that it be classified as an actinide.[1]

The appearance of this element is unknown, but it is likely to be silvery-white or gray and metallic. If sufficient amounts of lawrencium were produced, it would pose a radiation hazard. Very little is known about the chemical properties of this element, but some preliminary work on a few atoms has indicated that it behaves in a manner similar to other actinides.

See also

Notes

  1. Nomenclature of Inorganic Chemistry IUPAC Chemical Nomenclature and Structure Representation Division. Retrieved September 24, 2007.

References

  • Emsley, John. Nature's Building Blocks: An A–Z Guide to the Elements. Oxford: Oxford Univ. Press, 2001. ISBN 0198503407
  • Greenwood, N.N., and A. Earnshaw. Chemistry of the Elements, 2nd ed. Oxford, UK; Burlington, MA: Butterworth-Heinemann, 1998. ISBN 0750633654 Online version Retrieved September 24, 2007.
  • Hampel, Clifford A. The Encyclopedia of the Chemical Elements. New York: Reinhold Book Corp, 1968. ISBN 0442155980
  • Morss, Lester R., Norman M. Edelstein, and Jean Fuger, eds. The Chemistry of the Actinide and Transactinide Elements. 3rd ed. 5 vols. Joseph J. Katz, adapter. Dordrecht: Springer, 2006. ISBN 1402035551
  • Stwertka, Albert. Guide to the Elements. Rev. ed. Oxford: Oxford University Press, 1998. ISBN 0-19-508083-1

External links

All links retrieved July 26, 2014.

  • Winter, Mark. Lawrencium The University of Sheffield and WebElements Ltd..

Credits

New World Encyclopedia writers and editors rewrote and completed the Wikipedia article in accordance with New World Encyclopedia standards. This article abides by terms of the Creative Commons CC-by-sa 3.0 License (CC-by-sa), which may be used and disseminated with proper attribution. Credit is due under the terms of this license that can reference both the New World Encyclopedia contributors and the selfless volunteer contributors of the Wikimedia Foundation. To cite this article click here for a list of acceptable citing formats.The history of earlier contributions by wikipedians is accessible to researchers here:

Note: Some restrictions may apply to use of individual images which are separately licensed.