Difference between revisions of "Kimberlite" - New World Encyclopedia

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[[image:kimberlite_core_sample.jpg|thumb|141px|Hewn kimberlite core sample from the [[James Bay|James Bay Lowlands]] region of Northern [[Ontario]], [[Canada]]. Grains of green [[olivine]] and purplish red [[garnet]] are visible. The sample is 13 centimeters (5 inches) long.]]
 
  
'''Kimberlite''' is a type of [[igneous rock]] best known for occasionally containing [[diamond]]s. Its [[mineral]] content usually includes [[olivine]], [[phlogopite]], [[pyroxene]], and [[garnet]], accompanied by a variety of trace minerals. Kimberlite occurs in the [[crust (geology)|Earth's crust]] in vertical structures known as '''kimberlite pipes'''.
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[[image:kimberlite_core_sample.jpg|thumb|141px|Hewn kimberlite core sample from the [[James Bay|James Bay Lowlands]] region of Northern [[Ontario]], [[Canada]]. Grains of green [[olivine]] and purplish red [[garnet]] are visible. The sample is 13 centimeters (five inches) long.]]
  
Kimberlite is an [[ultrapotassic igneous rocks|ultrapotassic]], [[ultramafic]], [[igneous]] rock.
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'''Kimberlite''' is a type of [[igneous rock]] that is [[ultramafic]] and [[ultrapotassic igneous rocks|ultrapotassic]]. Its [[mineral]] content usually includes [[olivine]], [[phlogopite]], [[pyroxene]], and [[garnet]], accompanied by a variety of trace minerals. Kimberlite occurs in the [[Earth]]'s crust in vertical structures known as ''kimberlite pipes''. These pipes are the most important source of mined [[diamond]]s today. In addition, the scientific study of kimberlite helps reveal some of the geological processes that take place within the Earth's crust and mantle.
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== Etymology ==
  
* Kimberlite pipes are the most important source of mined diamonds today.
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The rock ''kimberlite'' was named after [[Kimberley, South Africa]], where it was first recognized. Kimberley [[diamond]]s were originally found in [[weathering|weathered]] kimberlite, which was colored yellow by [[limonite]], and was therefore called ''[[yellow ground]]''. Deeper workings produced less altered rock, [[serpentinite|serpentinized]] kimberlite, which miners call ''[[blue ground]]''.
  
 
== Formation ==
 
== Formation ==
  
Kimberlites are found as [[dike (geology)|dikes]] and [[volcanic pipe]]s that are the source for rare, relatively small explosive volcanoes ([[maar]]s). Kimberlites in the Guyana Shield, in Venezuela and French Guyana, form thin, tabular dipping sills.
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The general consensus is that kimberlites are formed deep within the mantle, at depths between 150 and 450 kilometers, from anomalously enriched exotic mantle compositions. They are erupted rapidly and violently, often with the release of considerable amounts of carbon dioxide (CO<sub>2</sub>) and volatile components. The violent explosions produce vertical columns of rock—volcanic pipes or kimberlite pipes—that rise from the magma reservoirs. The depth of melting and the process of generation makes kimberlites prone to hosting diamond [[xenocryst]]s.<ref>A xenocryst is an individual foreign crystal included within an igneous body.</ref>
  
The general consensus reached on kimberlites is that they are formed deep within the mantle, at depths between 150 and 450 kilometers, from anomalously enriched exotic mantle compositions. They are erupted rapidly and violently, often with the release of considerable amounts of carbon dioxide (CO<sub>2</sub>) and volatile components.  
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The morphology of kimberlite pipes is varied, but it generally includes a sheeted dike complex of vertically dipping feeder dikes in the root of the pipe, extending down to the mantle. Within 1.5-2 kilometers (km) of the surface, as the magma explodes upward, it expands to form a conical to cylindrical zone called the ''[[diatreme]]'', which erupts to the surface.
  
The depth of melting and the process of generation makes kimberlites prone to hosting diamond [[xenocryst]]s.
+
The surface expression is rarely preserved, but it is usually similar to a maar [[volcano]]. The diameter of a kimberlite pipe at the surface is typically a few hundred meters to a kilometer.
  
Kimberlite pipes are the result of explosive [[Volcanic pipe|diatreme]] [[volcanism]] from very deep [[Earth's mantle|mantle]] derived sources. These volcanic explosions produce vertical columns of rock that rise from deep magma reservoirs. The morphology of kimberlite pipes are varied but generally include a sheeted dyke complex of tabular, vertically dipping feeder dykes in the root of the pipe which extend down to the mantle. Within 1.5-2 kilometers (km) of the surface, the highly pressured magma explodes upward and expands to form a conical to cylindrical [[diatreme]], which erupts to surface. The surface expression is rarely preserved but is usually similar to a maar volcano. The diameter of a kimberlite pipe at the surface is typically a few hundred meters to a kilometer.
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Many kimberlite pipes are believed to have formed about 70 to 150 million years ago, but in Southern Africa, there are several that formed between 60 to 1,600 million years ago (Mitchell, 1995, p. 16).
 
 
Many kimberlite pipes are believed to have formed about 70 to 150 million years ago, but in Southern Africa, there are several formed between 60 to 1600 million years ago.<ref>Roger Howard Mitchell - Kimberlites, Orangeites, and Related Rocks, page 16.</ref>
 
  
 
== Petrology ==
 
== Petrology ==
  
Kimberlites are divided into Group I (basaltic) and Group II (micaceous) kimberlites. This division is made along mineralogical grounds.  
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Based on their mineralogy, kimberlites are divided into Group I (basaltic) and Group II (micaceous) kimberlites.
  
The mineralogy of Group I kimberlites is considered to represent the products of melting of [[lherzolite]] and [[harzburgite]], [[eclogite]] and [[peridotite]] under lower mantle conditions. The mineralogy of Group II kimberlites may represent a similar melting environment to that of Group I kimberlites, the difference in mineralogy being caused by the preponderance of water versus carbon dioxide.  
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The mineralogy of Group I kimberlites is considered to represent the products of melting of [[lherzolite]] and [[harzburgite]], [[eclogite]] and [[peridotite]] under lower mantle conditions. The [[mineralogy]] of Group II kimberlites may represent a similar melting environment to that of Group I kimberlites, the difference in mineralogy being caused by the preponderance of [[water]] versus [[carbon dioxide]].  
  
 
=== Group I kimberlites ===
 
=== Group I kimberlites ===
  
Group I kimberlites are of CO<sub>2</sub>-rich ultramafic potassic igneous rocks dominated by a primary mineral assemblage of forsteritic olivine, magnesian ilmenite, chromian pyrope, almandine-pyrope, chromian diopside (in some cases subcalcic), phlogopite, enstatite and of Ti-poor chromite. Group I kimberlites exhibit a distinctive inequigranular texture cause by macrocrystic (0.5-10 mm) to megacrystic (10-200 mm) phenocrysts of olivine, pyrope, chromian diopside, magnesian ilmenite and phlogopite in a fine to medium grained groundmass.  
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Group I kimberlites consist of carbon dioxide (CO<sub>2</sub>)-rich ultramafic potassic igneous rocks dominated by a primary mineral assemblage of forsteritic olivine, magnesian ilmenite, chromian pyrope, almandine-pyrope, chromian diopside (in some cases subcalcic), phlogopite, enstatite, and titanium-poor chromite.
  
The groundmass mineralogy, which more closely resembles a true composition of the igneous rock, contains forsteritic [[olivine]], [[pyrope]] garnet, Cr-[[diopside]], magnesian [[ilmenite]] and [[spinel]].
+
The groundmass mineralogy, which more closely resembles a true composition of the igneous rock, contains forsteritic [[olivine]], [[pyrope]] garnet, Cr-[[diopside]], magnesian [[ilmenite]], and [[spinel]].
  
 
=== Group II kimberlites ===
 
=== Group II kimberlites ===
  
Group-II kimberlites (or '''orangeites''') are [[ultrapotassic igneous rocks|ultrapotassic]], [[peralkaline igneous rocks|peralkaline]] rocks rich in volatiles (dominantly H<sub>2</sub>O). The distinctive characteristic of orangeites is [[phlogopite]] macrocrysts and microphenocrysts, together with groundmass micas that vary in composition from phlogopite to "tetraferriphlogopite" (anomalously Fe-rich phlogopite). Resorbed olivine macrocrysts and euhedral primary crystals of groundmass olivine are common but not essential constituents.  
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Group-II kimberlites (or ''orangeites'') are [[ultrapotassic igneous rocks|ultrapotassic]], [[peralkaline igneous rocks|peralkaline]] rocks rich in volatiles (mainly water). The distinctive characteristic of orangeites is [[phlogopite]] macrocrysts and microphenocrysts, together with groundmass micas that vary in composition from phlogopite to "tetraferriphlogopite" (anomalously iron-rich phlogopite). Resorbed olivine macrocrysts and euhedral primary crystals of groundmass olivine are common but not essential constituents.  
  
Characteristic primary phases in the groundmass include: zoned pyroxenes (cores of diopside rimmed by Ti-aegirine); spinel-group minerals (magnesian [[chromite]] to titaniferous [[magnetite]]); Sr- and REE-rich [[perovskite]]; Sr-rich [[apatite]]; REE-rich phosphates ([[monazite]], daqingshanite); potassian barian [[hollandite]] group minerals; Nb-bearing [[rutile]] and Mn-bearing [[ilmenite]].
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Characteristic primary phases in the groundmass include: zoned pyroxenes (cores of diopside rimmed by Ti-aegirine); spinel-group minerals (magnesian [[chromite]] to titaniferous [[magnetite]]); Sr- and REE-rich [[perovskite]]; Sr-rich [[apatite]]; REE-rich phosphates ([[monazite]], daqingshanite); potassian barian [[hollandite]] group minerals; Nb-bearing [[rutile]], and Mn-bearing [[ilmenite]].
  
 
=== Kimberlitic indicator minerals ===
 
=== Kimberlitic indicator minerals ===
  
Kimberlites are peculiar igneous rocks because they contain a variety of mineral species with peculiar chemical compositions. These minerals—such as potassic richterite, chromian diopside (a [[pyroxene]]), chromium spinels, magnesian ilmenite, and garnets rich in [[pyrope]] plus chromium—are generally absent from most other igneous rocks, making them particularly useful as indicators for kimberlites.
+
Kimberlites are peculiar igneous rocks because they contain a variety of mineral species with peculiar chemical compositions. These minerals—such as potassic richterite, chromian diopside (a [[pyroxene]]), chromium spinels, magnesian ilmenite, and garnets rich in [[pyrope]] plus chromium—are generally absent from most other igneous rocks, making them particularly useful as indicators for kimberlites.
  
The indicator minerals are generally sought in stream sediments in modern [[alluvium|alluvial material]]. Their presence, when found, may be indicative of the presence of kimberlite within the erosional watershed, which has produced the alluvium.
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The indicator minerals are generally sought in stream sediments in modern [[alluvium|alluvial material]]. Their presence, when found, may be indicative of the presence of kimberlite within the erosional watershed that produced the alluvium.
  
 
== Geochemistry ==
 
== Geochemistry ==
  
The geochemistry of Kimberlites is defined by the following parameters:
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The geochemistry of kimberlites is defined by the following parameters:
* Ultramafic; MgO >12% and generally >15%
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* Ultramafic: magnesium oxide (greater than 12 percent and generally greater than 15 percent).
* Ultrapotassic; Molar K<sub>2</sub>O/Al<sub>2</sub>O<sub>3</sub> >3
+
* Ultrapotassic: molar ratio of potassium oxide (K<sub>2</sub>O) to aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) is greater than three.
* Near-primitive Ni (>400ppm), Cr (>1000ppm), Co (>150ppm)
+
* Near-primitive nickel (greater than 400 ppm), chromium (greater than 1000 ppm), cobalt (greater than 150 ppm).
* Enrichment in rare earth elements (REE)
+
* Enrichment in rare earth elements (REE).
* Moderate to high LILE enrichment; ΣLILE = >1,000ppm [LILE = large-ion lithophile elements, such as K, Ba, Rb, Cs, Sr.]
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* Moderate to high LILE enrichment; sum of LILE is greater than 1,000 ppm (LILE = large-ion lithophile elements, such as K, Ba, Rb, Cs, Sr).
* High H<sub>2</sub>O and CO<sub>2</sub> content
+
* High content of water and carbon dioxide.
  
 
== Economic importance ==
 
== Economic importance ==
  
Kimberlites are the most important source of primary [[diamonds]]. Many kimberlite pipes also produce rich [[alluvial]] diamond [[placer deposit]]s. However, only about 1 in 200 kimberlite pipes contain gem-quality diamonds.
+
Kimberlites are the most important source of primary [[diamonds]]. Many kimberlite pipes also produce rich [[alluvial]] diamond [[placer deposit]]s. However, only about one in 200 kimberlite pipes contain gem-quality diamonds.
 
The deposits occurring at [[Kimberley, South Africa|Kimberley]], [[South Africa]] were the first recognized and the source of the name. The Kimberley [[diamond]]s were originally found in [[weathering|weathered]] kimberlite which was colored yellow by [[limonite]], and so was called ''[[yellow ground]]''. Deeper workings encountered less altered rock, [[serpentinite|serpentinized]] kimberlite, which miners call ''[[blue ground]]''.
 
  
 
== Related rock types ==
 
== Related rock types ==
 +
 
* [[Lamproite]]
 
* [[Lamproite]]
 
* [[Lamprophyre]]
 
* [[Lamprophyre]]
Line 81: Line 79:
 
== References ==
 
== References ==
  
* Farndon, John. 2006. ''The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks''. London: Lorenz Books. ISBN 0754815412.
+
* Farndon, John. ''The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks''. London: Lorenz Books, 2006. ISBN 0754815412
 
+
* Klein, Cornelis, and Barbara Dutrow. ''Manual of Mineral Science''. 23rd ed. New York: John Wiley, 2007. ISBN 978-0471721574
* Klein, Cornelis, and Barbara Dutrow. 2007. ''Manual of Mineral Science''. 23rd ed. New York: John Wiley. ISBN 978-0471721574.
+
* Mitchell, Roger Howard. ''Kimberlites, Orangeites, and Related Rocks''. New York: Springer, 1995. ISBN 0306450224
 
+
* Pellant, Chris. ''Rocks and Minerals''. Smithsonian Handbooks. New York: Dorling Kindersley, 2002. ISBN 0789491060
* Mitchell, Roger Howard. 1995. ''Kimberlites, Orangeites, and Related Rocks''. Springer. ISBN 0306450224.
+
* Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. ''Rocks, Gems and Minerals''. Rev. ed. New York: St. Martin's Press, 2001. ISBN 1582381321
 
 
* Pellant, Chris. 2002. ''Rocks and Minerals''. Smithsonian Handbooks. New York: Dorling Kindersley. ISBN 0789491060.
 
 
 
* Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. 2001. ''Rocks, Gems and Minerals''. Rev. ed. New York: St. Martin's Press. ISBN 1582381321.
 
  
 
== External links ==
 
== External links ==
 
+
All links retrieved April 17, 2018.
*[http://www.eos.ubc.ca/research/diamonds/kopylova/introduction.html Kimberlite: Introduction.] Retrieved May 21, 2007.
+
*[http://www.eos.ubc.ca/research/diamonds/kimberlites.html Kimberlites] Diamond Exploration Laboratory
 
 
*[http://www.em.gov.bc.ca/Mining/Geolsurv/MetallicMinerals/MineralDepositProfiles/profiles/n02.htm Kimberlite-hosted diamonds.] Retrieved May 21, 2007.
 
  
 
[[Category:Physical sciences]]
 
[[Category:Physical sciences]]

Latest revision as of 14:33, 17 April 2018


Hewn kimberlite core sample from the James Bay Lowlands region of Northern Ontario, Canada. Grains of green olivine and purplish red garnet are visible. The sample is 13 centimeters (five inches) long.

Kimberlite is a type of igneous rock that is ultramafic and ultrapotassic. Its mineral content usually includes olivine, phlogopite, pyroxene, and garnet, accompanied by a variety of trace minerals. Kimberlite occurs in the Earth's crust in vertical structures known as kimberlite pipes. These pipes are the most important source of mined diamonds today. In addition, the scientific study of kimberlite helps reveal some of the geological processes that take place within the Earth's crust and mantle.

Etymology

The rock kimberlite was named after Kimberley, South Africa, where it was first recognized. Kimberley diamonds were originally found in weathered kimberlite, which was colored yellow by limonite, and was therefore called yellow ground. Deeper workings produced less altered rock, serpentinized kimberlite, which miners call blue ground.

Formation

The general consensus is that kimberlites are formed deep within the mantle, at depths between 150 and 450 kilometers, from anomalously enriched exotic mantle compositions. They are erupted rapidly and violently, often with the release of considerable amounts of carbon dioxide (CO2) and volatile components. The violent explosions produce vertical columns of rock—volcanic pipes or kimberlite pipes—that rise from the magma reservoirs. The depth of melting and the process of generation makes kimberlites prone to hosting diamond xenocrysts.[1]

The morphology of kimberlite pipes is varied, but it generally includes a sheeted dike complex of vertically dipping feeder dikes in the root of the pipe, extending down to the mantle. Within 1.5-2 kilometers (km) of the surface, as the magma explodes upward, it expands to form a conical to cylindrical zone called the diatreme, which erupts to the surface.

The surface expression is rarely preserved, but it is usually similar to a maar volcano. The diameter of a kimberlite pipe at the surface is typically a few hundred meters to a kilometer.

Many kimberlite pipes are believed to have formed about 70 to 150 million years ago, but in Southern Africa, there are several that formed between 60 to 1,600 million years ago (Mitchell, 1995, p. 16).

Petrology

Based on their mineralogy, kimberlites are divided into Group I (basaltic) and Group II (micaceous) kimberlites.

The mineralogy of Group I kimberlites is considered to represent the products of melting of lherzolite and harzburgite, eclogite and peridotite under lower mantle conditions. The mineralogy of Group II kimberlites may represent a similar melting environment to that of Group I kimberlites, the difference in mineralogy being caused by the preponderance of water versus carbon dioxide.

Group I kimberlites

Group I kimberlites consist of carbon dioxide (CO2)-rich ultramafic potassic igneous rocks dominated by a primary mineral assemblage of forsteritic olivine, magnesian ilmenite, chromian pyrope, almandine-pyrope, chromian diopside (in some cases subcalcic), phlogopite, enstatite, and titanium-poor chromite.

The groundmass mineralogy, which more closely resembles a true composition of the igneous rock, contains forsteritic olivine, pyrope garnet, Cr-diopside, magnesian ilmenite, and spinel.

Group II kimberlites

Group-II kimberlites (or orangeites) are ultrapotassic, peralkaline rocks rich in volatiles (mainly water). The distinctive characteristic of orangeites is phlogopite macrocrysts and microphenocrysts, together with groundmass micas that vary in composition from phlogopite to "tetraferriphlogopite" (anomalously iron-rich phlogopite). Resorbed olivine macrocrysts and euhedral primary crystals of groundmass olivine are common but not essential constituents.

Characteristic primary phases in the groundmass include: zoned pyroxenes (cores of diopside rimmed by Ti-aegirine); spinel-group minerals (magnesian chromite to titaniferous magnetite); Sr- and REE-rich perovskite; Sr-rich apatite; REE-rich phosphates (monazite, daqingshanite); potassian barian hollandite group minerals; Nb-bearing rutile, and Mn-bearing ilmenite.

Kimberlitic indicator minerals

Kimberlites are peculiar igneous rocks because they contain a variety of mineral species with peculiar chemical compositions. These minerals—such as potassic richterite, chromian diopside (a pyroxene), chromium spinels, magnesian ilmenite, and garnets rich in pyrope plus chromium—are generally absent from most other igneous rocks, making them particularly useful as indicators for kimberlites.

The indicator minerals are generally sought in stream sediments in modern alluvial material. Their presence, when found, may be indicative of the presence of kimberlite within the erosional watershed that produced the alluvium.

Geochemistry

The geochemistry of kimberlites is defined by the following parameters:

  • Ultramafic: magnesium oxide (greater than 12 percent and generally greater than 15 percent).
  • Ultrapotassic: molar ratio of potassium oxide (K2O) to aluminum oxide (Al2O3) is greater than three.
  • Near-primitive nickel (greater than 400 ppm), chromium (greater than 1000 ppm), cobalt (greater than 150 ppm).
  • Enrichment in rare earth elements (REE).
  • Moderate to high LILE enrichment; sum of LILE is greater than 1,000 ppm (LILE = large-ion lithophile elements, such as K, Ba, Rb, Cs, Sr).
  • High content of water and carbon dioxide.

Economic importance

Kimberlites are the most important source of primary diamonds. Many kimberlite pipes also produce rich alluvial diamond placer deposits. However, only about one in 200 kimberlite pipes contain gem-quality diamonds.

Related rock types

  • Lamproite
  • Lamprophyre
  • Nepheline syenite
  • Ultrapotassic igneous rocks
  • Kalsititic rocks

See also

Notes

  1. A xenocryst is an individual foreign crystal included within an igneous body.

References
ISBN links support NWE through referral fees

  • Farndon, John. The Practical Encyclopedia of Rocks & Minerals: How to Find, Identify, Collect and Maintain the World's best Specimens, with over 1000 Photographs and Artworks. London: Lorenz Books, 2006. ISBN 0754815412
  • Klein, Cornelis, and Barbara Dutrow. Manual of Mineral Science. 23rd ed. New York: John Wiley, 2007. ISBN 978-0471721574
  • Mitchell, Roger Howard. Kimberlites, Orangeites, and Related Rocks. New York: Springer, 1995. ISBN 0306450224
  • Pellant, Chris. Rocks and Minerals. Smithsonian Handbooks. New York: Dorling Kindersley, 2002. ISBN 0789491060
  • Shaffer, Paul R., Herbert S. Zim, and Raymond Perlman. Rocks, Gems and Minerals. Rev. ed. New York: St. Martin's Press, 2001. ISBN 1582381321

External links

All links retrieved April 17, 2018.

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