Difference between revisions of "Filtration" - New World Encyclopedia

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{{otheruses4|operation of solid-fluid separation|the mathematical concept|filtration (mathematics)|the equipment used|filter}}
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[[Image:Filtration diagram.svg|right|thumb|300px|Diagram of a simple filtration.]]
[[Image:Filtration diagram.svg|right|thumb|300px|diagram of a simple filtration]]
 
'''Filtration''' is a mechanical or physical operation which is used for the separation of solids from fluids (liquids or gases) by interposing a medium to fluid flow through which the fluid can pass, but the solids (or at least part of the solids) in the fluid are retained. It has to be emphasized that the separation is NOT complete, and it will depend on the pore size and the thickness of the medium as well as the mechanisms that occur during filtration.
 
  
* Filtration is used for the purification of fluids: for instance separating dust from the atmosphere to clean ambient air.  
+
'''Filtration''' is a mechanical or physical operation by which solids are separated from fluids (liquids or gases) in a mixture with the help of a medium that is called a '''filter.''' When the mixture is brought in contact with a filter, the filter allows the fluid to pass through, but it retains at least part of the solid material. The fluid that passes through the filter is called the '''filtrate,''' and the solid material that remains on the filter is called the '''residue.''' Depending on the application, either one or both components may be isolated.
+
{{toc}}
* Filtration, as a physical operation is very important in chemistry for the separation of materials of different chemical composition in solution (or solids which can be dissolved) by first using a reagent to precipitate one of the materials and then use a filter to separate the solid from the other material(s).
+
Filtration methods are often used to remove harmful substances from [[air]] or [[water]], such as to reduce [[air pollution]] or to make water potable. Chemists often use filtration to separate materials of different chemical compositions. On an industrial scale, filtration is used by the oil, gas, food and beverage, and pharmaceutical industries, among others. Municipalities use filtration techniques when treating sewage and purifying water.
  
* Filtration is also important and widely used as one of the unit operations of chemical engineering.
+
==Methods==
 +
The filtration process separates solid particles from a fluid in a suspension, and the fluid can be either a [[liquid]] or a [[gas]] (or a [[supercritical fluid]]). There are various methods of filtration. In each case, the particles to be removed are trapped by the filter, while the fluid passes through it.
  
It is important not to confuse '''filtration''' with '''sieving'''. In sieving there is only a single layer of medium where size separation occurs purely by the fact that the fraction of the particulate solid matter which is too large to be able to pass through the holes of the sieve, scientifically called ''oversize'' (See [[particle size distribution]]) are retained. In filtration a multilayer medium is involved, where other mechanisms are included as well, for instance direct interception, diffusion and centrifugal action, where in this latter those particles, which  are unable to follow the tortuous channels of the filter will also adhere to the structure of the medium and are retained.<ref>Lecture notes, Postgraduate course on Filtration and Size separation at the Department of Chemical Engineering, University of Lougborough, England</ref>   
+
The simplest method of filtration is to pass a suspension of a solid in a fluid through a porous interface so that the solid is trapped, but the fluid passes through. This principle relies on the difference in sizes of the particles that make up the fluid and those that make up the solid. In the laboratory, a [[Büchner funnel]] or [[Hirsch funnel]] may be used, with a [[filter paper]] serving as the porous barrier.
  
Depending on the application, either one or both of the components may be isolated. Examples of filtration include A) a [[coffee filter]] to keep the coffee separate from the grounds and B) the use of [[HEPA]] filters in [[air conditioning]] to remove particles from air.
+
For example, an experiment to demonstrate the existence of [[Microorganism|microscopic organisms]] involves the comparison of unfiltered water with water passed through unglazed [[porcelain]]. When left in sealed containers, the filtered water takes longer to go foul, showing that even microscopic organisms (such as [[bacterium|bacteria]]) can be removed from fluids by appropriately designed filtration.
  
The filtration process separates particles and fluid from a suspension, and the fluid can be either a [[liquid]] or a [[gas]] (or a [[supercritical fluid]]). To separate a mixture of chemical compounds, a [[solvent]] is chosen which dissolves one component, while not dissolving the other. By dissolving the mixture in the chosen solvent, one component will go into the solution and pass through the filter, while the other will be retained. This is one of the most important techniques used by chemists to purify compounds.
+
Some methods are based on the principle of [[electrostatic]] attraction between oppositely charged particles. These types of filters may become clogged, or their active sites may be filled by the unwanted materials. However, most chemical filters are designed so that the filter can be flushed with a chemical that will remove the unwanted materials, allowing the filter to be reused.
  
Filtration also cleans up water streams or other river streams. Furnaces use filtration to prevent the furnace elements from fouling with particulates.  Pneumatic conveying systems often employ filtration to stop or slow the flow of material that is transported, through the use of a [[dust collector|baghouse]].
+
To separate a mixture of solid chemical compounds, a chemist may choose a [[solvent]] that dissolves one component but does not dissolve the other. When this mixture is filtered, the component in solution passes through the filter, while the other is retained by the filter. This is one of the most important techniques used by chemists to purify compounds.
  
The remainder of this article focuses primarily on liquid filtration.
+
Alternatively, if several compounds are in solution, the chemist may add a reagent that precipitates one or more of the compounds. The mixture may then be filtered to separate the precipitate from the dissolved materials.
  
==Methods==
+
=== Regulating flow rate through the filter ===
There are many different methods of filtration; all aim to attain the [[separation of mixtures|separation]] of 4,000,000 or more substances. This is achieved by some form of interaction between the substance or objects to be removed and the filter. In addition the substance that is to pass through the filter must be a [[fluid]], i.e. a [[liquid]] or [[gas]].
+
To separate solid particles from a liquid, the easiest technique is to allow the liquid to flow through the filter by gravity. For chemical plants, this is usually the most economical method. In the laboratory, pressure in the form of compressed air may be applied to hasten the filtration process, although this may clog the filter or allow the passage of fine particles. Alternatively, the liquid may be drawn through the filter by the use of a pump.
 
 
The simplest method of filtration is to pass a solution of a solid and fluid through a porous interface so that the solid is trapped, while the fluid passes through. This principle relies upon the size difference between the particles making up the fluid, and the particles making up the solid.  In the laboratory, a [[Büchner funnel]] is often used, with a [[filter paper]] serving as the porous barrier.
 
 
 
For example an experiment to prove the existence of [[Microorganism|microscopic organisms]] involves the comparison of water passed through unglazed [[porcelain]] and unfiltered water. When left in sealed containers the filtered water takes longer to go foul, showing that very small items (such as [[bacterium|bacteria]]) can be removed from fluids by filtration.{{Fact|date=March 2007}} Alternate methods often take the form of [[electrostatic]] attractions. These form of filters again have the problem of either becoming clogged, or the active sites on the filter all become used by the undesirable. However, most chemical filters are designed so that the filter can be flushed with a chemical that will remove the undesirables and allow the filter to be re-used.
 
 
 
==Flowing==
 
Liquids usually flow through the filter by gravity. This is the simplest method, and can be seen in the coffeemaker example. For chemical plants, this is usually the most economical method as well. In the laboratory, pressure in the form of compressed air may be applied to make the filtration process faster, though this may lead to clogging or the passage of fine particles. Alternatively, the liquid may flow through the filter by the force exerted by a pump. In this case, the filter need not be mounted vertically.
 
  
 
==Filter media==
 
==Filter media==
There are two main types of filter media &mdash;  a solid sieve which traps the solid particles, with or without the aid of filter paper, and a bed of granular material which retains the solid particles as it passes. The first type allows the solid particles, i.e. the residue, to be collected intact; the second type does not permit this. However, the second type is less prone to clogging due to the greater surface area where the particles can be trapped. Also, when the solid particles are very fine, it is often cheaper and easier to discard the contaminated granules than to clean the solid sieve.
+
There are two main types of filter media: A solid [[sieve]] that traps the solid particles, with or without the aid of filter paper; and a bed of granular material that retains the solid particles as they attempt to pass through. The first type allows the solid particles (that is, the residue) to be collected intact; the second type does not permit this. However, the second type is less prone to clogging because the particles can be trapped over a greater surface area. Also, when the solid particles are very fine, it is often cheaper and easier to discard the contaminated granules than to clean the solid sieve.
  
 
Filter media can be cleaned by rinsing with solvents or detergents. Alternatively, in engineering applications, such as swimming pool water treatment plants, they may be cleaned by [[backwashing]].
 
Filter media can be cleaned by rinsing with solvents or detergents. Alternatively, in engineering applications, such as swimming pool water treatment plants, they may be cleaned by [[backwashing]].
  
Examples of the first type include '''filter paper''' used with a Buchner, Hirsch, filter funnel or other similar funnel. A '''sintered-glass funnel''' is often used in chemistry laboratories because it is able to trap very fine particles, while permitting the particles to be removed by a spatula.
+
Examples of the first type include '''filter paper''' used with a Büchner funnel, Hirsch funnel, or other similar funnel. A '''sintered-glass funnel''' is often used in chemistry laboratories because it can trap very fine particles, and the particles can be removed with a spatula.
  
Examples of the second type include filters at municipal and swimming pool water treatment plants, where the granular material is sand. In the laboratory, [[Celite]] or [[diatomaceous earth]] is packed in a [[Pasteur pipette]] (microscale) or loaded on top of a sintered-glass funnel to serve as the filter bed.
+
Examples of the second type include filters at municipal and swimming pool water treatment plants, where the granular material is sand. In the laboratory, the filter bed may be formed from [[Celite]] ([[diatomaceous earth]] or kieselguhr) packed in a [[Pasteur pipette]] (microscale) or loaded on top of a sintered glass funnel.
  
 
+
When selecting the filter medium, one should consider whether the filter has the following properties:
The following points should be considerd while selecting the filter media:
+
* Ability to trap the solid particles
* ability to build the solid.
+
* Minimum resistance for the filtrate to flow through
* minimum resistance to flow the filtrate.
+
* Resistance to chemical attack
* resistance to chemical attack.
+
* Minimum cost
* minimum cost.
+
* Long life
* long life.
 
  
 
==Filter aid==
 
==Filter aid==
 +
Certain filter aids may be used to assist the filtration process. They are often inorganic mineral powders or organic fibrous materials. Examples include [[diatomaceous earth]], wood cellulose, and other inert porous solids.
  
Certain filter aids may be used to aid filtration. These are often incompressible diatomaceous earth or kieselguhr, which is composed primarily of [[silica]]. Also used are wood cellulose and other inert porous solids.
+
These filter aids can be used in two different ways. They can be used as a precoat (on the filter medium) before the [[slurry]] is filtered. This prevents gelatinous-type solids from plugging the filter medium and it gives a clearer filtrate. Alternatively, they can be added to the slurry before filtration. This increases the [[porosity]] of the cake and reduces resistance of the cake during filtration. In a rotary filter, the filter aid may be applied as a precoat; subsequently, thin slices of this layer are sliced off with the cake.
 
 
These filter aids can be used in two different ways. They can be used as a precoat before the [[slurry]] is filtered. This will prevent gelatinous-type solids from plugging the filter medium and also give a clearer filtrate. They can also be added to the [[slurry]] before filtration. This increases the [[porosity]] of the cake and reduces resistance of the cake during filtration. In a rotary filter, the filter aid may be applied as a precoat; subsequently, thin slices of this layer are sliced off with the cake.
 
  
 
The use of filter aids is usually limited to cases where the cake is discarded or where the [[precipitate]] can be separated chemically from the filter.
 
The use of filter aids is usually limited to cases where the cake is discarded or where the [[precipitate]] can be separated chemically from the filter.
 
==Alternatives==
 
{{Separation processes}}
 
Filtration is a more efficient method for the [[separation of mixtures]] than [[decantation]], but is much more time consuming. If very small amounts of [[solution]] are involved, most of the solution may be soaked up by the filter medium.
 
 
An alternative to filtration is [[centrifugation]] &mdash; instead of filtering the mixture of solid and liquid particles, the mixture is centrifuged to force the (usually) denser solid to the bottom, where it often forms a firm cake. The liquid above can then be decanted. This method is especially useful for separating solids which do not filter well, such as gelatinous or fine particles. These solids can clog or pass through the filter, respectively.
 
  
 
==Filter types==
 
==Filter types==
Line 67: Line 51:
 
*Continuous rotary filters
 
*Continuous rotary filters
  
==In kidney==
+
== Filtration vs. sieving ==
{{Main|Renal filtration}}
+
It is important not to confuse '''filtration''' with '''sieving.''' In sieving, there is only a single layer of medium where size separation occurs purely by the fact that the fraction of the particulate solid matter which is too large to be able to pass through the holes of the sieve, (scientifically called "oversize") are retained. In filtration, a multilayer medium is involved, where other mechanisms are included as well, for instance direct interception, diffusion, and centrifugal action, where in this latter those particles, which are unable to follow the tortuous channels of the filter, will also adhere to the structure of the medium and are retained.<ref>Lecture notes, Postgraduate course on Filtration and Size separation at the Department of Chemical Engineering, University of Lougborough, England.</ref>   
 +
 
 +
== Applications ==
 +
Filtration methods are used in the home, in research laboratories, in industrial processes, and in controlling environmental pollution. For example, a coffee filter is used to separate brewed coffee from the grounds, and [[HEPA]] filters are used in [[air conditioner]]s and [[vacuum cleaner]]s. Some filters are used to clean ambient air by removing dust from the atmosphere.
 +
 
 +
Chemists often use filtration to separate materials from mixtures of different chemical compositions.
 +
 
 +
On an industrial scale, filtration is used by the oil, gas, food and beverage, and pharmaceutical industries, among others. Municipalities use filtration techniques when treating sewage and purifying water.
 +
 
 +
Filtration cleans up river streams or other water streams. Furnaces use filtration to prevent the furnace elements from fouling with particulates. Pneumatic conveying systems often employ filtration to stop or slow the flow of material that is transported, through the use of a [[dust collector|baghouse]].
 +
 
 +
==In kidneys==
 
The [[kidney]] works by filtration of [[blood]] in the [[glomerulus]], followed by selectively reabsorbing many substances essential for the body.
 
The [[kidney]] works by filtration of [[blood]] in the [[glomerulus]], followed by selectively reabsorbing many substances essential for the body.
  
==See also==
+
==Alternatives==
{{wiktionary|filtration}}
+
Filtration is a more efficient method for the [[separation of mixtures]] than [[decantation]], but it is much more time consuming. If very small amounts of [[solution]] are involved, most of the solution may be soaked up by the filter medium.
* [[:Category:Filters]]
+
 
* [[Separation of mixtures]]  
+
An alternative to filtration is [[centrifugation]]&mdash;instead of filtering the mixture of solid and liquid particles, the mixture is centrifuged to force the (usually) denser solid to the bottom, where it often forms a firm cake. The liquid above can then be decanted. This method is especially useful for separating solids that do not filter well, such as gelatinous or fine particles. These solids can clog or pass through the filter, respectively.
* [[Microfiltration]]
 
* [[Ultrafiltration]]
 
* [[Nanofiltration]]
 
* [[Reverse osmosis]]
 
* [[Filter (water)]]
 
  
==Footnotes==
+
==Notes==
{{Reflist}}
+
<references/>
  
 
== References ==
 
== References ==
[http://www.airfilterengineering.com Air filter Engineering (M) Sdn. Bhd.]
+
* Cheremisinoff, Nicholas P. ''Liquid Filtration,'' 2nd ed. Boston: Butterworth-Heinemann, 1998. ISBN 0750670479.
 +
* Meltzer, Theodore H. and Maik W. Jornitz. ''Pharmaceutical Filtration: The Management of Organism Removal.'' Bethesda, Md: PDA, 2006. ISBN 193011477X.
 +
* Sutherland, Ken. ''Filters and Filtration Handbook,'' 5th ed. Oxford: Elsevier, 2006. ISBN 978-1856174640.
 +
 
 +
== External links ==
 +
All links retrieved March 26, 2024.
  
[[Category:Analytical chemistry]]
+
* [http://www.filtsep.com Filtration + Separation.]  
[[Category:Laboratory techniques]]
+
* [http://www.filtration-and-separation.com Filtration & Separation.com.]  
[[Category:Separation processes]]
 
[[Category:Unit operations]]
 
[[Category:Alchemical processes]]
 
  
==Further reading==
+
[[Category:Physical sciences]]
*[http://www.filtsep.com www.filtsep.com]
+
[[Category:Chemistry]]
*[http://www.filtration-and-separation.com filtration equipment expert system and data analysis]
 
  
[[Category: Physical sciences]]
+
{{credit|209295495}}
[[Category: Chemistry]]
 

Latest revision as of 19:47, 26 March 2024

Diagram of a simple filtration.

Filtration is a mechanical or physical operation by which solids are separated from fluids (liquids or gases) in a mixture with the help of a medium that is called a filter. When the mixture is brought in contact with a filter, the filter allows the fluid to pass through, but it retains at least part of the solid material. The fluid that passes through the filter is called the filtrate, and the solid material that remains on the filter is called the residue. Depending on the application, either one or both components may be isolated.

Filtration methods are often used to remove harmful substances from air or water, such as to reduce air pollution or to make water potable. Chemists often use filtration to separate materials of different chemical compositions. On an industrial scale, filtration is used by the oil, gas, food and beverage, and pharmaceutical industries, among others. Municipalities use filtration techniques when treating sewage and purifying water.

Methods

The filtration process separates solid particles from a fluid in a suspension, and the fluid can be either a liquid or a gas (or a supercritical fluid). There are various methods of filtration. In each case, the particles to be removed are trapped by the filter, while the fluid passes through it.

The simplest method of filtration is to pass a suspension of a solid in a fluid through a porous interface so that the solid is trapped, but the fluid passes through. This principle relies on the difference in sizes of the particles that make up the fluid and those that make up the solid. In the laboratory, a Büchner funnel or Hirsch funnel may be used, with a filter paper serving as the porous barrier.

For example, an experiment to demonstrate the existence of microscopic organisms involves the comparison of unfiltered water with water passed through unglazed porcelain. When left in sealed containers, the filtered water takes longer to go foul, showing that even microscopic organisms (such as bacteria) can be removed from fluids by appropriately designed filtration.

Some methods are based on the principle of electrostatic attraction between oppositely charged particles. These types of filters may become clogged, or their active sites may be filled by the unwanted materials. However, most chemical filters are designed so that the filter can be flushed with a chemical that will remove the unwanted materials, allowing the filter to be reused.

To separate a mixture of solid chemical compounds, a chemist may choose a solvent that dissolves one component but does not dissolve the other. When this mixture is filtered, the component in solution passes through the filter, while the other is retained by the filter. This is one of the most important techniques used by chemists to purify compounds.

Alternatively, if several compounds are in solution, the chemist may add a reagent that precipitates one or more of the compounds. The mixture may then be filtered to separate the precipitate from the dissolved materials.

Regulating flow rate through the filter

To separate solid particles from a liquid, the easiest technique is to allow the liquid to flow through the filter by gravity. For chemical plants, this is usually the most economical method. In the laboratory, pressure in the form of compressed air may be applied to hasten the filtration process, although this may clog the filter or allow the passage of fine particles. Alternatively, the liquid may be drawn through the filter by the use of a pump.

Filter media

There are two main types of filter media: A solid sieve that traps the solid particles, with or without the aid of filter paper; and a bed of granular material that retains the solid particles as they attempt to pass through. The first type allows the solid particles (that is, the residue) to be collected intact; the second type does not permit this. However, the second type is less prone to clogging because the particles can be trapped over a greater surface area. Also, when the solid particles are very fine, it is often cheaper and easier to discard the contaminated granules than to clean the solid sieve.

Filter media can be cleaned by rinsing with solvents or detergents. Alternatively, in engineering applications, such as swimming pool water treatment plants, they may be cleaned by backwashing.

Examples of the first type include filter paper used with a Büchner funnel, Hirsch funnel, or other similar funnel. A sintered-glass funnel is often used in chemistry laboratories because it can trap very fine particles, and the particles can be removed with a spatula.

Examples of the second type include filters at municipal and swimming pool water treatment plants, where the granular material is sand. In the laboratory, the filter bed may be formed from Celite (diatomaceous earth or kieselguhr) packed in a Pasteur pipette (microscale) or loaded on top of a sintered glass funnel.

When selecting the filter medium, one should consider whether the filter has the following properties:

  • Ability to trap the solid particles
  • Minimum resistance for the filtrate to flow through
  • Resistance to chemical attack
  • Minimum cost
  • Long life

Filter aid

Certain filter aids may be used to assist the filtration process. They are often inorganic mineral powders or organic fibrous materials. Examples include diatomaceous earth, wood cellulose, and other inert porous solids.

These filter aids can be used in two different ways. They can be used as a precoat (on the filter medium) before the slurry is filtered. This prevents gelatinous-type solids from plugging the filter medium and it gives a clearer filtrate. Alternatively, they can be added to the slurry before filtration. This increases the porosity of the cake and reduces resistance of the cake during filtration. In a rotary filter, the filter aid may be applied as a precoat; subsequently, thin slices of this layer are sliced off with the cake.

The use of filter aids is usually limited to cases where the cake is discarded or where the precipitate can be separated chemically from the filter.

Filter types

  • Gravity filter (open system that operates with water column pressure only)
  • Pressure filter (closed system that operates under pressure from a pump)
  • Side stream filter (filter in a closed loop, that filters part of the media per cycle only)
  • Continuous rotary filters

Filtration vs. sieving

It is important not to confuse filtration with sieving. In sieving, there is only a single layer of medium where size separation occurs purely by the fact that the fraction of the particulate solid matter which is too large to be able to pass through the holes of the sieve, (scientifically called "oversize") are retained. In filtration, a multilayer medium is involved, where other mechanisms are included as well, for instance direct interception, diffusion, and centrifugal action, where in this latter those particles, which are unable to follow the tortuous channels of the filter, will also adhere to the structure of the medium and are retained.[1]

Applications

Filtration methods are used in the home, in research laboratories, in industrial processes, and in controlling environmental pollution. For example, a coffee filter is used to separate brewed coffee from the grounds, and HEPA filters are used in air conditioners and vacuum cleaners. Some filters are used to clean ambient air by removing dust from the atmosphere.

Chemists often use filtration to separate materials from mixtures of different chemical compositions.

On an industrial scale, filtration is used by the oil, gas, food and beverage, and pharmaceutical industries, among others. Municipalities use filtration techniques when treating sewage and purifying water.

Filtration cleans up river streams or other water streams. Furnaces use filtration to prevent the furnace elements from fouling with particulates. Pneumatic conveying systems often employ filtration to stop or slow the flow of material that is transported, through the use of a baghouse.

In kidneys

The kidney works by filtration of blood in the glomerulus, followed by selectively reabsorbing many substances essential for the body.

Alternatives

Filtration is a more efficient method for the separation of mixtures than decantation, but it is much more time consuming. If very small amounts of solution are involved, most of the solution may be soaked up by the filter medium.

An alternative to filtration is centrifugation—instead of filtering the mixture of solid and liquid particles, the mixture is centrifuged to force the (usually) denser solid to the bottom, where it often forms a firm cake. The liquid above can then be decanted. This method is especially useful for separating solids that do not filter well, such as gelatinous or fine particles. These solids can clog or pass through the filter, respectively.

Notes

  1. Lecture notes, Postgraduate course on Filtration and Size separation at the Department of Chemical Engineering, University of Lougborough, England.

References
ISBN links support NWE through referral fees

  • Cheremisinoff, Nicholas P. Liquid Filtration, 2nd ed. Boston: Butterworth-Heinemann, 1998. ISBN 0750670479.
  • Meltzer, Theodore H. and Maik W. Jornitz. Pharmaceutical Filtration: The Management of Organism Removal. Bethesda, Md: PDA, 2006. ISBN 193011477X.
  • Sutherland, Ken. Filters and Filtration Handbook, 5th ed. Oxford: Elsevier, 2006. ISBN 978-1856174640.

External links

All links retrieved March 26, 2024.

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