Apatite

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Apatite
Apatite crystals.jpg
General
CategoryPhosphate mineral group
Chemical formulaCa5(PO4)3(F,Cl,OH)
Identification
ColorTransparent to translucent, usually green, less often colorless, yellow, blue to violet, pink, brown.[1]
Crystal habitTabular, prismatic crystals, massive, compact or granular
Crystal systemHexagonal Dipyramidal (6/m)[2]
Cleavage[0001] Indistinct, [1010] Indistinct[2]
FractureConchoidal to uneven[1]
Mohs Scale hardness5[1]
LusterVitreous[1] to subresinous
Refractive index1.634 - 1.638 (+.012, -.006)[1]
Optical PropertiesDouble refractive, uniaxial negative[1]
Birefringence.002-.008[1]
PleochroismBlue stones - strong, blue and yellow to colorless. Other colors are weak to very weak.[1]
StreakWhite
Specific gravity3.16 - 3.22[2]
DiaphaneityTransparent to translucent[2]

Apatite is a group of phosphate minerals, usually referring to hydroxylapatite, fluorapatite, and chlorapatite, named for high concentrations of OH-, F-, or Cl- ions, respectively, in the crystal. The formula of the admixture of the three most common species is written as Ca5(PO4)3(OH, F, Cl), and the formulae of the individual minerals are written as Ca5(PO4)3(OH), Ca5(PO4)3F and Ca5(PO4)3Cl, respectively.

Apatite is one of few minerals that are produced and used by biological micro-environmental systems. Hydroxylapatite is the major component of tooth enamel. A relatively unique form of apatite in which most of the OH groups are absent and containing many carbonate and acid phosphate substitutions is a large component of bone material.

Fluorapatite (or fluoroapatite) is more resistant to acid attack that is hydroxyapatite. For this reason, toothpaste typically contain a source of fluoride anions (e.g. sodium fluoride, sodium monofluorophosphate). Similarly, fluoridated water, allow exchange in the teeth of fluoride ions for hydroxy groups in apatite. Too much fluoride results in dental fluorosis and/or skeletal fluorosis.

In the United States, apatite is often used to fertilize tobacco. It partially starves the plant of nitrogen, which gives American cigarettes a different taste from those of other countries.

Fission tracks in apatite are commonly used to determine the thermal history of orogenic (mountain) belts and of sediments in sedimentary basins.

Phosphorite is the name given to impure, massive apatite.

Gemology

Apatite is infrequently used as a gemstone. Transparent stones of clean color have been faceted, and chatoyant specimens have been cabochon cut.[1] Chatoyant stones are known as cat's-eye apatite,[1] transparent green stones are known as asparagus stone,[1] and blue stones have been called moroxite.[3] Crystals of rutile may have grown in the crystal of apatite so when in the right light, the cut stone displays a cat's eye effect. Major sources for gem apatite are:[1] Brazil, Burma, and Mexico. Other sources include:[1] Canada, Czechoslovakia, Germany, India, Madagascar, Mozambique, Norway, South Africa, Spain, Sri Lanka, and the US.

See also

Apatite Crystal, Mexico
  • List of minerals
  • Thermal history modelling

References
ISBN links support NWE through referral fees

  1. 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 Gemological Institute of America, GIA Gem Reference Guide 1995, ISBN 0-87311-019-6
  2. 2.0 2.1 2.2 2.3 http://webmineral.com/data/Apatite.shtml Webmineral data
  3. Streeter, Edwin W., Precious Stones and Gems 6th edition, George Bell and Sons, London, 1898, p306

Further reading

  • Schmittner Karl-Erich and Giresse Pierre, 1999. Micro-environmental controls on biomineralization: superficial processes of apatite and calcite precipitation in Quaternary soils, Roussillon, France. Sedimentology 46/3: 463-476.

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