In nuclear physics, a nuclear reaction is a process in which two atomic nuclei or nuclear particles collide to produce products different from the initial particles. In principle, a nuclear reaction can involve the collision of more than two nuclei or subatomic particles, but the probability of three or more particles colliding at the same time is extremely small, and such an event is exceptionally rare.
In the case of radioactive decay, the transformation is spontaneous, but in the case of a nuclear reaction, it is initiated by the collision. If the particles collide and separate without changing, the process is called an elastic collision rather than a reaction.
Contents |
In the example shown in the figure on the right, ^{6}Li and deuterium react to form a highly excited ^{8}Be intermediate nucleus, which then decays into two alpha particles.
Kinetic energy may be released during the course of a reaction (exothermic reaction) or kinetic energy may have to be supplied for the reaction to take place (endothermic reaction). This can be calculated by reference to a table of very accurate particle rest masses.^{[1]} According to the reference tables, the 63Li nucleus has a relative atomic mass of 6.015 atomic mass units (abbreviated u), the deuteron has 2.014 u, and the helium-4 nucleus has 4.0026u. Thus:
In a nuclear reaction, the total relativistic energy is conserved. The "missing" rest mass must therefore reappear as kinetic energy released in the reaction; its source is the nuclear binding energy. Using Einstein's mass-energy equivalence formula E = mc², the amount of energy released can be determined. First, one needs the energy equivalent of one atomic mass unit:
Hence, the energy released is 0.0238 × 931 MeV = 22.4 MeV.
Expressed differently: The mass is reduced by 0.3 percent, corresponding to 0.3 percent of 90 PJ/kg is 300 TJ/kg.
This is a large amount of energy for a nuclear reaction; the amount is so high because the binding energy per nucleon of the helium-4 nucleus is unusually high, because the He-4 nucleus is doubly magic. The He-4 nucleus is unusually stable and tightly-bound for the same reason that the helium atom is inert: Each pair of protons and neutrons in He-4 occupies a filled 1s nuclear orbital in the same way that the pair of electrons in the helium atom occupy a filled 1s electron orbital. Consequently, alpha particles appear frequently on the right hand side of nuclear reactions.
The energy released in a nuclear reaction can appear mainly in one of three ways:
When the product nucleus is metastable, this is indicated by placing an asterisk ("*") next to its atomic number. This energy is eventually released through nuclear decay.
A small amount of energy may also emerge in the form of X-rays. Generally, the product nucleus has a different atomic number, and thus the configuration of its electron shells is wrong. As the electrons rearrange themselves and drop to lower energy levels, internal transition X-rays (those with precisely defined emission lines) may be emitted.
In writing down the reaction equation, in a way analogous to a chemical equation, one may in addition give the reaction energy on the right side:
For the particular case discussed above, the reaction energy has already been calculated as Q = 22.4 MeV. Hence:
The reaction energy (the "Q-value") is positive for exothermal reactions and negative for endothermal reactions. On the one hand, it is the difference between the sums of kinetic energies on the final side and on the initial side. But on the other hand, it is also the difference between the nuclear rest masses on the initial side and on the final side (in this way, the Q-value has been calculated above).
If the reaction equation is balanced, that does not mean that the reaction really occurs. The rate at which reactions occur depends on the particle energy, the particle flux, and the reaction cross section.
In the initial collision which begins the reaction, the particles must approach closely enough so that the short range strong force can affect them. As most common nuclear particles are positively charged, this means they must overcome considerable electrostatic repulsion before the reaction can begin. Even if the target nucleus is part of a neutral atom, the other particle must penetrate well beyond the electron cloud and closely approach the nucleus, which is positively charged. Thus, such particles must be first accelerated to high energy, for example by:
Also, since the force of repulsion is proportional to the product of the two charges, reactions between heavy nuclei are rarer, and require higher initiating energy, than those between a heavy and light nucleus; while reactions between two light nuclei are commoner still.
Neutrons, on the other hand, have no electric charge to cause repulsion, and are able to effect a nuclear reaction at very low energies. In fact at extremely low particle energies (corresponding, say, to thermal equilibrium at room temperature), the neutron's de Broglie wavelength is greatly increased, possibly greatly increasing its capture cross section, at energies close to resonances of the nuclei involved. Thus low energy neutrons may be even more reactive than high energy neutrons.
While the number of possible nuclear reactions is immense, there are several types which are more common, or otherwise notable. Some examples include:
An intermediate energy projectile transfers energy or picks up or loses nucleons to the nucleus in a single quick (10^{−21} second) event. Energy and momentum transfer are relatively small. These are particularly useful in experimental nuclear physics, because the reaction mechanisms are often simple enough to calculate with sufficient accuracy to probe the structure of the target nucleus.
Only energy and momentum are transferred.
Usually at moderately low energy, one or more nucleons are transferred between the projectile and target. These are useful in studying outer shell structure of nuclei.
Either a low energy projectile is absorbed or a higher energy particle transfers energy to the nucleus, leaving it with too much energy to be fully bound together. On a time scale of about 10^{−19} seconds, particles, usually neutrons, are "boiled" off. That is, it remains together until enough energy happens to be concentrated in one neutron to escape the mutual attraction. Charged particles rarely boil off because of the coulomb barrier. The excited quasi-bound nucleus is called a compound nucleus. Low energy (e, e' xn), (γ, xn) (the xn indicating one or more neutrons) occurs when the gamma or virtual gamma energy is near the Giant dipole resonance. These increase the need for radiation shielding around electron accelerators
Applying the methods of scattering by two potentials, the plane wave of each free charged particle is replaced by the exact solution for a charged particle moving in the presence of another point charge.
Direct nuclear reactions are most often calculated by some form of distorted wave Born approximation. Applying scattering by two potentials, the coulomb solutions and neutron plane waves are replaced by the optical model wave functions for the incident and outgoing particles moving in and near the nucleus. These are obtained mostly from elastic scattering experiments, and from inelastic scattering to vibrational and rotational collective excitations. The reaction itself is then modeled by the Born approximation. That is, the excitation or transfer process is treated as a first order perturbation on elastic scattering. An early improvement on this was to exactly treat the coupling between a small number of excited states, known as coupled channels Born approximation.
A nuclear chain reaction occurs when, on average, more than one nuclear reaction is caused by another nuclear reaction, thus leading to an exponential increase in the number of nuclear reactions.
An uncontrolled chain reaction within a sufficiently large amount of fission fuel (critical mass) can lead to an explosive energy release and is the concept behind nuclear weapons. The chain reaction could also be adequately controlled and used as an energy source (nuclear reactor).
Some fission equations, showing averages:
This excludes 10 MeV for unusable and hardly detectable neutrinos.
When a heavy atom undergoes nuclear fission, it breaks into two or more fission fragments. The fission fragments consist of atoms of a lighter weight than the original heavy atom. The sum of their masses do not precisely equal that of the heavy atom, even while accounting for the incident neutron. The difference (mass difference) consists of ejected neutrons and the release of binding energy. The neutrons leave the reaction at high speed, and may collide with other heavy atoms in a phenomenon known as "fission capture." This could result in nuclear fission, forming the basis of a chain reaction.
The average generation time is the average time from neutron emission to fission capture. The neutrons travel only short distances, on the order of 10cm (the diameter of a critical mass);. An average neutron's speed varies around 10,000km/s, resulting in a timescale on the order of 10ns. This quantity is often referred to as a shake.
The effective neutron multiplication factor or κ, is the average number of neutrons that go on to cause another fission reaction. The remaining neutrons either fail to induce fission, or are never absorbed and exit the system. The value of κ for a combination of two masses is always greater that of its components. In some cases its value is equal to the sum of the component κ values. The magnitude of the difference depends on velocity and distance, as well as physical orientation. Passing a small sphere through a small hole produces a particularly large κ: Like firing a fissile "bullet" into a shaped fissile target.
Scientists have distinguished the following cases:
When k is close to 1, this calculation somewhat over-estimates the "doubling rate." When a uranium nucleus absorbs a neutron it enters a very-short-lived excited state which then decays by several possible routes. Typically it decays into two fragments, fission products, typically isotopes of Iodine and Cesium, with expulsion of a number of neutrons. The fission products are themselves unstable, with a wide range of lifetimes, but typically several seconds, and decay producing further neutrons.
It is usual to split the population of neutrons which are emitted into two sorts—"prompt neutrons" and "delayed neutrons." Typically, the "delayed neutron fraction" is less than 1 percent of the whole. In a nuclear reactor, the variable k is typically around 1 to have a steady process. When a value of k = 1 is achieved, when all neutrons produced are considered, the reaction is said to be "critical." This is the situation achieved in a nuclear reactor. The power changes are then slow, and controllable (that is, with control rods). When k = 1 is achieved counting only the "prompt" neutrons, the reaction is said to be "prompt critical"—much shorter doubling rates can then occur, depending on the excess criticality (k-1). The change in reactivity needed to go from critical to prompt critical (i.e. the delayed neutron fraction) is defined as a dollar.
The value of k is increased by a neutron reflector surrounding the fissile material, and also by increasing the density of the fissile material: The probability for a neutron per cm traveled to hit a nucleus is proportional to the density, while the distance traveled before leaving the system is only reduced by the cube root of the density. In the implosion method for nuclear weapons, detonation takes place by increasing the density with a conventional explosive.
Suppose a fission caused by a neutron hitting a nucleus produces 3 neutrons (i.e. 2 extra). Also suppose k > 1. The probability that a neutron causes a fission is k / 3. The probability that a free neutron does not cause a chain reaction is (1 - k / 3) (no fission at all) plus the probability of at least one fission, while none of the 3 neutrons produced causes a chain reaction. The latter has a probability of k / 3 times the cube of the first-mentioned probability that a free neutron does not cause a chain reaction. This equation can be solved easily, giving a probability of a chain reaction of
which ranges from 0 for k = 1 to 1 for k = 3.
For values of k which are little above 1 we get approximately k - 1.
Detonation of a nuclear weapon involves bringing fissile material into its optimal supercritical state very rapidly. During part of this process the assembly is supercritical, but not yet in optimal state for a chain reaction. Free neutrons, in particular from spontaneous fissions, can cause predetonation. To keep the probability low, the duration of this period is minimized and fissile and other materials are used for which there are not too many spontaneous fissions. In fact, the combination has to be such that it is unlikely that there is even a single spontaneous fission during the period of assembly. In particular the gun method cannot be used with plutonium.
The concept was first developed by Leó Szilárd in 1933. He supposedly thought of the idea while waiting for a red light. He patented the concept the following year.
Leo Szilárd attempted to create a chain reaction using beryllium and indium in 1936, but was unsuccessful. In 1939, Leo Szilárd and Enrico Fermi discovered neutron multiplication in Uranium, proving that the chain reaction was possible.
The first artificial self-sustaining nuclear chain reaction was initiated by the Metallurgical Laboratory, led by Enrico Fermi and Leó Szilárd, in a racquets court below the bleachers of Stagg Field at the University of Chicago on December 2, 1942, as part of the Manhattan Project.
The only known natural self-sustaining nuclear chain reactions were discovered at Oklo in September 1972.
All links retrieved October 13, 2016.
New World Encyclopedia writers and editors rewrote and completed the Wikipedia article in accordance with New World Encyclopedia standards. This article abides by terms of the Creative Commons CC-by-sa 3.0 License (CC-by-sa), which may be used and disseminated with proper attribution. Credit is due under the terms of this license that can reference both the New World Encyclopedia contributors and the selfless volunteer contributors of the Wikimedia Foundation. To cite this article click here for a list of acceptable citing formats.The history of earlier contributions by wikipedians is accessible to researchers here:
The history of this article since it was imported to New World Encyclopedia:
Note: Some restrictions may apply to use of individual images which are separately licensed.