Chalcedony
Chalcedony is one of the cryptocrystalline[1] varieties of the mineral quartz. It may be semitransparent or translucent and has a waxy luster. It is usually white to gray, grayish-blue or some shade of brown, sometimes nearly black. Other shades have been given different names. A clear red or reddish brown variety is known as carnelian (also spelled cornelian) or sard (colored with iron oxide); a green variety (colored by nickel oxide) is called chrysoprase. Prase is a dull green form, and onyx is black and white banded. Plasma is a bright to emerald-green chalcedony that is sometimes found with small spots of jasper resembling blood drops—the latter form is referred to as bloodstone or heliotrope. Flint is also a variety of chalcedony.
People living along the Central Asian trade routes used various forms of chalcedony, including carnelian, to carve intaglios, ring bezels (the upper faceted portion of a gem projecting from the ring setting), and beads that show strong Graeco-Roman influence. Fine examples of first century objects made from chalcedony, possibly Kushan, were found in recent years at Tillya-tepe in north-western Afghanistan. Hot wax would not stick to it so it was often used to make seal impressions.
The term chalcedony is derived from the name of the ancient Greek town Chalkedon in Asia Minor, in modern English usually spelled Chalcedon, today the Kadıköy district of Istanbul.
Properties
Chalcedony is more soluble than quartz under low-temperature conditions. The technique of crystallography shows that the crystalline structure of chalcedony is identical to that of quartz, leading one to expect that they should have the same solubility as well. Chalcedony, however, is composed of extremely fine-grained crystals (described as cryptocrystalline), and it therefore has a very high surface area-to-volume ratio. It is believed that this property of chalcedony is responsible for its higher solubility.
Onyx
Onyx is a banded variety of chalcedony. The colors of its bands range from white to almost every color. Commonly, specimens of onyx available contain colors of white, tan, and brown. Sardonyx is a variant in which the colored bands are sard (shades of red) rather than black.
It is usually cut as a cabochon, or into beads, and is also used for intaglios and cameos, where the bands make the image contrast with the ground. Some onyx is natural but much is produced by the staining of agate.
One can view a close variant of this material in St.Mary's Church at Żebbuġ, Gozo.
The name has sometimes been used, incorrectly, to label other banded lapidary materials, such as banded calcite found in Mexico, Pakistan, and other places, and often carved, polished and sold. This material is much softer than true onyx, and much more readily available. The majority of carved items sold as 'Onyx' today are this carbonate material. [1]
| Chemical composition and name | SiO2 - Silicon dioxide |
| Hardness (Mohs scale) | 7 |
| Specific gravity | 2.65 - 2.667 |
| Refractive index (R.I.) | 1.543 - 1.552 to 1.545 - 1.554 |
| Birefringence | 0.009 |
| Optic sign | Positive |
| Optical character | Uniaxial |
Culture and historical/mythical usage
According to Rebbenu Bachya, the word Shoham in the verse Exodus 28:20 means "Onyx" and was the stone on the Ephod representing the Tribe of Joseph. There were also two Shoham stones on the shoulders of the Ephod.
In the Dreamlands, a fictional location in the works of the author H. P. Lovecraft, the palaces of Kadath are built of onyx.
Solubility of quartz and chalcedony in pure water
This table gives equilibrium concentrations of total dissolved silicon as calculated by PHREEQC using the llnl.dat database.
| Temperature | Quartz Solubility (mg/L) | Chalcedony Solubility (mg/L) |
|---|---|---|
| 0.01ºC | 0.68 | 1.34 |
| 25.0ºC | 2.64 | 4.92 |
| 50.0ºC | 6.95 | 12.35 |
| 75.0ºC | 14.21 | 24.23 |
| 100.0ºC | 24.59 | 40.44 |
See also
Footnotes
- ↑ The term cryptocrystalline refers to a structure that consists of tiny crystals that can be seen only at high magnification.
ReferencesISBN links support NWE through referral fees
- Hurlbut, Cornelius S.; Klein, Cornelis (1985). Manual of Mineralogy (20th ed.). New York: John Wiley and Sons. ISBN 0-471-80580-7.
- Weinstein, Michael (1967). The World of Jewel Stones. New York, NY: Sheridan House. ASIN: B000IN1RC4.
External links
- http://www.mindat.org/min-960.html
- http://minerals.usgs.gov/minerals/pubs/commodity/gemstones/sp14-95/chalcedony.html
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