Difference between revisions of "Nitrogen fixation" - New World Encyclopedia

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'''Nitrogen fixation''' is the process by which [[nitrogen]] is taken from its relatively inert molecular form (N<sub>2</sub>) in the [[Earth's atmosphere|atmosphere]] and converted into nitrogen compounds useful for other chemical processes (such as, notably, [[ammonia]], [[nitrate]] and [[nitrogen dioxide]]).
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'''Nitrogen fixation''' is the process by which nitrogen is taken from its relatively inert molecular form (N<sub>2</sub>) in the [[atmosphere]] and converted into nitrogen compounds useful for other chemical processes (such as, notably, ammonia, nitrate and nitrogen dioxide).
  
Nitrogen fixation is performed naturally by a number of different [[prokaryote]]s, including [[bacterium|bacteria]], and [[actinobacteria]] certain types of [[anaerobe|anaerobic]] bacteria. Many higher plants, and some animals ([[termite]]s), have formed associations with these microorganisms.
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Nitrogen fixation is performed naturally by a number of different prokaryotes, including bacteria, and actinobacteria certain types of anaerobic [[bacteria]]. Many higher plants, and some [[animal]]s (termites), have formed associations with these microorganisms.
  
 
==Biological Nitrogen Fixation==
 
==Biological Nitrogen Fixation==
 
[[Image:Nitrogen_Cycle.jpg|center|thumb|320px|right|Schematic representation of the [[nitrogen cycle]].]]
 
[[Image:Nitrogen_Cycle.jpg|center|thumb|320px|right|Schematic representation of the [[nitrogen cycle]].]]
Biological Nitrogen Fixation ('''BNF''') occurs when atmospheric nitrogen is converted to ammonia by a bacterial enzyme called [[nitrogenase]]. Microorganisms that fix nitrogen are called [[diazotroph]]s. The formula for BNF is:
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Biological Nitrogen Fixation ('''BNF''') occurs when [[atmosphere|atmospheric]] nitrogen is converted to ammonia by a [[bacteria|bacterial]] enzyme called nitrogenase. Microorganisms that fix nitrogen are called diazotrophs. The formula for BNF is:
 
 
:  N<sub>2</sub> + 8H<sup>+</sup> + 8e<sup>-</sup> + 16 ATP &rarr; 2NH<sub>3</sub>  + H<sub>2</sub> + 16ADP + 16 [[phosphate|P<sub>i</sub>]]
 
 
 
Although [[ammonia]] (NH<sub>3</sub>) is the direct product of this reaction, it is quickly ionized to [[ammonium]] (NH<sub>4</sub><sup>+</sup>). In free-living diazotrophs, the nitrogenase-generated ammonium is assimilated into [[glutamate]] through the glutamine synthetase/glutamate synthase pathway.  Biological nitrogen fixation was discovered by the Dutch microbiologist [[Martinus Beijerinck]].
 
 
 
  
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:  N<sub>2</sub> + 8H<sup>+</sup> + 8e<sup>-</sup> + 16 ATP &rarr; 2NH<sub>3</sub>  + H<sub>2</sub> + 16ADP + 16 P<sub>i</sub>
  
 +
Although ammonia (NH<sub>3</sub>) is the direct product of this reaction, it is quickly ionized to ammonium (NH<sub>4</sub><sup>+</sup>). In free-living diazotrophs, the nitrogenase-generated ammonium is assimilated into glutamate through the glutamine synthetase/glutamate synthase pathway.  Biological nitrogen fixation was discovered by the Dutch microbiologist Martinus Beijerinck.
  
 
==Leguminous nitrogen-fixing plants==
 
==Leguminous nitrogen-fixing plants==
The best-known are [[Fabaceae|legume]]s (such as [[clover]], beans, alfalfa and peanuts,) which contain [[symbiosis|symbiotic]] bacteria called [[rhizobia]] within [[root nodule|nodules]] in their [[root|root systems]], producing nitrogen compounds that help the plant to grow and compete with other plants. When the plant dies, the nitrogen helps  to fertilize the [[soil]]. The great majority of legumes have this association, but a few genera (e.g., ''[[Styphnolobium]]'') do not.
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The best-known are [[legume]]s (such as clover, beans, alfalfa and peanuts,) which contain [[symbiosis|symbiotic]] bacteria called rhizobia within nodules in their [[root|root systems]], producing nitrogen compounds that help the [[plant]] to grow and compete with other plants. When the plant dies, the nitrogen helps  to fertilize the soil. The great majority of [[legume]]s have this association, but a few genera (e.g., ''Styphnolobium'') do not.
  
 
==Non-leguminous nitrogen fixing plants==
 
==Non-leguminous nitrogen fixing plants==
 
Plants from many other families have similar associations, including:
 
Plants from many other families have similar associations, including:
*[[Lobaria]] lichen and some other [[lichen]]s
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*Lobaria lichen and some other lichens
*[[Mosquito fern]] (''Azolla'' species)
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*Mosquito fern (''Azolla'' species)
 
*[[Cycad]]s
 
*[[Cycad]]s
*[[Gunnera]]
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*Gunnera
*[[Alder]] (''<i>Alnus</i>'' species)
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*Alder (''<i>Alnus</i>'' species)
*[[Ceanothus]] (''<i>Ceanothus</i>'' species)
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*Ceanothus (''<i>Ceanothus</i>'' species)
*[[Myrica|Wax myrtle]] (''<i>Myrica</i>'' species)
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*Wax myrtle (''<i>Myrica</i>'' species)
*[[Mountain-mahogany]] (''<i>Cercocarpus</i>'' species)
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*Mountain-mahogany (''<i>Cercocarpus</i>'' species)
*[[Bitterbrush]] (''<i>Purshia tridentata</i>'')
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*Bitterbrush (''<i>Purshia tridentata</i>'')
*[[Buffalo berry]] (''<i>Shepherdia argentea</i>'')
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*Buffalo berry (''<i>Shepherdia argentea</i>'')
*[[Casuarina|Ironwood]] (''<i>Casuarina</i>'' species), [[Allocasuarina|Sheoak]] (''<i>Allocasuarina</i>'' species), and other genera in the [[Casuarinaceae]]
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*Ironwood (''<i>Casuarina</i>'' species), Sheoak (''<i>Allocasuarina</i>'' [[species]]), and other genera in the Casuarinaceae
  
 
==Chemical nitrogen fixation==
 
==Chemical nitrogen fixation==
Nitrogen can also be artificially fixed for use in [[fertilizer]], explosives, or in other products. The most popular method is by the [[Haber process]]. Artificial fertilizer production has achieved such scale that it is now the largest source of fixed nitrogen in the [[Earth]]'s [[ecosystem]].
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Nitrogen can also be artificially fixed for use in fertilizer, explosives, or in other products. The most popular method is by the Haber process. Artificial fertilizer production has achieved such scale that it is now the largest source of fixed nitrogen in the [[Earth]]'s [[ecosystem]].
 
 
== See also ==
 
*[[Denitrification]]
 
*[[George Washington Carver]]
 
*[[Nitrification]]
 
*[[Nitrogen cycle]]
 
*[[Nitrogen deficiency]]
 
  
 
== External links ==
 
== External links ==

Revision as of 01:25, 23 July 2006

Nitrogen fixation is the process by which nitrogen is taken from its relatively inert molecular form (N2) in the atmosphere and converted into nitrogen compounds useful for other chemical processes (such as, notably, ammonia, nitrate and nitrogen dioxide).

Nitrogen fixation is performed naturally by a number of different prokaryotes, including bacteria, and actinobacteria certain types of anaerobic bacteria. Many higher plants, and some animals (termites), have formed associations with these microorganisms.

Biological Nitrogen Fixation

Schematic representation of the nitrogen cycle.

Biological Nitrogen Fixation (BNF) occurs when atmospheric nitrogen is converted to ammonia by a bacterial enzyme called nitrogenase. Microorganisms that fix nitrogen are called diazotrophs. The formula for BNF is:

N2 + 8H+ + 8e- + 16 ATP → 2NH3 + H2 + 16ADP + 16 Pi

Although ammonia (NH3) is the direct product of this reaction, it is quickly ionized to ammonium (NH4+). In free-living diazotrophs, the nitrogenase-generated ammonium is assimilated into glutamate through the glutamine synthetase/glutamate synthase pathway. Biological nitrogen fixation was discovered by the Dutch microbiologist Martinus Beijerinck.

Leguminous nitrogen-fixing plants

The best-known are legumes (such as clover, beans, alfalfa and peanuts,) which contain symbiotic bacteria called rhizobia within nodules in their root systems, producing nitrogen compounds that help the plant to grow and compete with other plants. When the plant dies, the nitrogen helps to fertilize the soil. The great majority of legumes have this association, but a few genera (e.g., Styphnolobium) do not.

Non-leguminous nitrogen fixing plants

Plants from many other families have similar associations, including:

  • Lobaria lichen and some other lichens
  • Mosquito fern (Azolla species)
  • Cycads
  • Gunnera
  • Alder (Alnus species)
  • Ceanothus (Ceanothus species)
  • Wax myrtle (Myrica species)
  • Mountain-mahogany (Cercocarpus species)
  • Bitterbrush (Purshia tridentata)
  • Buffalo berry (Shepherdia argentea)
  • Ironwood (Casuarina species), Sheoak (Allocasuarina species), and other genera in the Casuarinaceae

Chemical nitrogen fixation

Nitrogen can also be artificially fixed for use in fertilizer, explosives, or in other products. The most popular method is by the Haber process. Artificial fertilizer production has achieved such scale that it is now the largest source of fixed nitrogen in the Earth's ecosystem.

External links

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