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'''Sir Humphry Davy, 1st Baronet''', [[Fellow of the Royal Society|FRS]] (17 December 1778 &ndash; 29 May 1829) was an esteemed [[Briton|British]] [[chemist]] and [[physicist]]. He was born in [[Penzance, Cornwall]], [[United Kingdom]] and both his brother [[John Davy (chemist)|John Davy]] and cousin [[Edmund Davy]] were also noted chemists. [[Berzelius]] called Davy's 1806 Bakerian Lecture "[http://www.english.upenn.edu/Projects/knarf/Davy/davy5.html On some Chemical Agencies of Electricity]" "one of the best memoirs which has ever enriched the theory of chemistry."<ref>J.J. Berzelius, ''Traite de chimie'', trans. Jourdian and Esslinger, vol. 1, pg. 164. 1st Swedish ed. (''Larbok i kemien''),  Stockholm (1818), this ed., 8 vol., Paris (1829-33).</ref>  This paper was central to any [[chemical affinity]] theory in the first half of the nineteenth century.<ref name="Levere" >{{cite book | last = Levere | first = Trevor, H. | title = Affinity and Matter – Elements of Chemical Philosophy 1800-1865 | publisher = Gordon and Breach Science Publishers | year = 1971 | id = ISBN 2881245838}}</ref>
+
Sir Humphry Davy, 1st Baronet, FRS (17 December 1778 29 May 1829) was an esteemed British chemist and physicist who vastly expanded chemical knowledge by isolating and identifying a host of new elements and by linking the action of acids to hydrogen instead of oxygen. He was also an inventor, and the mentor of Michael Faraday, who for many years was Davy’s assistant and whose researches in electricity and magnetism formed the foundation for our modern understanding of that field.
  
 
== Biography ==
 
== Biography ==
  
Sir Humphry revelled in his status, as his lectures gathered many spectators. Davy became well known due to his experiments with the physiological action of some [[gas]]es, including laughing gas ([[nitrous oxide]]) - to which he was addicted, once stating that its properties bestowed all of the benefits of alcohol but was devoid of its flaws. Davy later damaged his eyesight in a laboratory accident with [[nitrogen trichloride]]. In 1801, he was nominated [[professor]] at the [[Royal Institution]] of Great Britain and Fellow of the [[Royal Society]], over which he would later preside.
+
Davy was born in Penzance, Cornwall, United Kingdom, the son of Robert Davy and Grace Millett. He grew up in a household of humble means. When he turned 14, his parents managed to send him to Cardew’s school in Truro, where he put in a mixed performance. He left Cardew around the time of his father’s death a year later, and by age 17 was apprenticed to a physician. By age 19, he began more formal studies of chemistry and geometry. When he turned 20, he was appointed by a physician, Thomas Beddoes, as superintendent of the laboratory for the then newly-established Medical Pneumatic Institution of Bristol. The purpose of the institute was to investigate medical applications for newly discovered “airs” or gases such as oxygen, hydrogen and carbon dioxide, the chemical properties of which were beginning to become known.
 +
His earliest researches, dating back to 1799, led to his first important discovery, nitrous oxide, often known as laughing gas, which in more modern times has been used as an anesthetic during surgery. This discovery, and the fame it brought, led to his invitation by scientist Benjamin Thompson (Count Rumford) (1753-1814), to head the laboratory at the Royal Institution in London. Upon taking up his duties, Davy immediately instituted a series of lectures on chemistry, which became very popular and increased his fame.
  
 
==Electrochemistry work==
 
==Electrochemistry work==
 
[[Image:Humphrydavy.jpg|thumb|left|100px|Humphry Davy in his youth.]]
 
[[Image:Humphrydavy.jpg|thumb|left|100px|Humphry Davy in his youth.]]
  
In 1800, [[Alessandro Volta]] announced his invention of the first electric pile or [[battery (electricity)|battery]]. Davy used this electric battery to separate [[salt]]s by what is now known as [[electrolysis]]. With many batteries in series he was able to separate elemental [[potassium]] and [[sodium]] in 1807 and [[calcium]], [[strontium]], [[barium]], and [[magnesium]] in 1808, which is when he also discovered and named [[aluminum]]. He also studied the energies involved in separating these salts, which is now the field of [[electrochemistry]]. According to the historian Christopher Lawrence, in the book ''Romanticism and the Sciences'', his electrolytic work was driven by [[Romanticism in science|Romantic beliefs]] in a unity in nature, composed of polar forces.
+
The experiments of Luigi Galvani, accounts of which were published in 1791, showed that electricity could be generated by placing metal in contact with the nerves and muscles in a frog’s leg. This principle was taken up by Alessandro Volta between 1796 and 1800, which, combined with his own observations, led him to create the first electric battery. It was later shown that water and other substances could be decomposed into their constituent elements through chemical action at the poles of a battery. This discovery captured the interest of Davy, who had at his disposal at the Royal Institution just such a battery. As a result of preliminary experiments, Davy proposed that the action that brings two elements together to form a compound is electrical. He set about to create a table of the energies needed to decompose a number of compounds through electrolysis. These results, and Davy’s conclusions, were set forward in the Bakerian Lecture of 1806, and established the direction research in electrochemical action was to take for decades hence.
 +
In 1807 Davy applied what was then one of the most powerful electric batteries to the decomposition of potassium and sodium salts, and succeeded in isolating the two metals and demonstrating that they were elements. The next year, using the same method, he isolated and identifying the elements calcium, magnesium, barium and strontium. In 1810, using an improved and more powerful version of his voltaic battery, Davy produced the first arc light using poles of carbon to produce an electric arc.
 +
Chemists at this time believed, in accordance with the conclusions of Lavoisier, that acids were oxygen-based. But Davy’s investigation of hydrochloric acid (a compound of hydrogen and chlorine only), published in 1811, demonstrated that the compound contained no oxygen. He also clearly stated that chlorine, which at the time was thought to be a compound of hydrochloric acid and oxygen, was actually an element, and gave it the name it has today. This discovery led to the identification of iodine and flourine as elements as well, and to a new understanding of acids as hydrogen-based.
  
 
==Retirement and further work==
 
==Retirement and further work==
  
In 1812 he was knighted, gave a farewell lecture to the Royal Institution, and married a wealthy widow, [[Jane Apreece]]. While generally acknowledged as being faithful to his wife, their relationship was stormy and in his later years Davy travelled to continental Europe alone. In October 1813 he and his wife, accompanied by [[Michael Faraday]] as his scientific assistant (and valet) traveled to [[France]] to collect a medal that [[Napoleon Bonaparte]] had awarded Davy for his electro-chemical work. Whilst in Paris Davy was asked by [[Joseph Louis Gay-Lussac|Gay-Lussac]] to investigate a mysterious substance isolated by [[Barnard Courtois]]. Davy showed it to be an element, which is now called [[iodine]]. The party left Paris on December 29, travelling south through [[Montpellier]] and [[Nice]] and then to [[Italy]].
+
In 1812 Davy was knighted by King George III, gave a farewell lecture to the Royal Institution, and married a wealthy widow, Jane Apreece.  
 +
Later that year, Davy and his wife traveled through Scotland, but after their return to London, he was injured in an explosion in his laboratory while investigating a chemical compound of nitrogen and chlorine. It was this fateful injury that caused Davy to hire Michael Faraday as a secretary. Only months later, Faraday was asked by Davy to assume the role of laboratory assistant at the Royal Institution. By October 1813 Davy and his wife, accompanied by Faraday, who was also compelled to act as the couple’s valet, were on their way to France to collect a medal that Napoleon Bonaparte had awarded Davy for his electro-chemical work. Whilst in Paris, Davy was shown a mysterious substance isolated by Barnard Courtois. Davy pronounced it to be an element, which is now called iodine.
 +
In Florence, in a series of experiments, Davy, with Faraday's assistance, succeeded in using the sun's rays to ignite diamond, and proved that it was composed of pure carbon. The entourage also visited Alessandro Volta.
 +
Based on a series of lectures delivered at the request of the Board of Agriculture, Davy published ''Elements of Agricultural Chemistry'' in 1813.
 +
After his return to England in 1815, Davy invented the Davy lamp, a safe method of illumination used by miners. He thought that this was one of his greatest achievements, but his claim to the invention, for which he demanded no royalties, was later challenged by others.
  
After passing through Genoa, they went to [[Florence]], where, in a series of experiments starting on Sunday March 27, Davy, with Faraday's assistance, succeed in using the sun's rays to ignite [[diamond]], and proved that it was composed of pure [[carbon]]. Davy's party continued on to [[Rome]], and also visited [[Naples]] and [[Mount Vesuvius]].
+
===Later Years===
By the June 17, they were in [[Milan]], where they met [[Alessandro Volta]], and continued north to [[Geneva]]. They returned to Italy via [[Munich]] and [[Innsbruck]], passed though [[Venice]] and returned to [[Rome]]. Their plans to travel to [[Greece]] and [[Constantinople]] (Istanbul) were abandoned after Napoleon's escape from [[Elba]], and they returned to England.
 
  
===Agricultural chemistry===
+
In 1818, Davy was awarded a [[baronet|baronetcy]] and two years later became president of the Royal Society, a post he would hold until 1827.
  
In 1813 Davy published the ''Elements of agricultural chemistry'' the translation of a course of lectures prepared for the Board of agriculture. The work was the first texbook of agricultural chemistry in the history of agrarian knowledges ."<ref> Antonio Saltini, ''Storia delle scienze agrarie'', vol II, ''I secoli della rivoluzione agraria'', Edagricole, Bologna, 1984, pp.633-648.</ref>.
+
In 1820s, Davy and his friend, William Hyde Wollaston, took up research in electricity and magnetism. Faraday also conducted research in the field, and published several papers, including one that demonstrated a way to create a motor from the magnetic force generated by a current-carrying wire. Davy felt that Faraday had taken credit for research that others had done, but Faraday refused to back down. This created friction between the two men, and apparently stalled Faraday’s research in the field, which he did not take up again until after Davy’s death. Davy was known to have been opposed to the election of Faraday as a fellow of the Royal Society, but Faraday was elected over his objections.
 +
In 1824 Davy proposed and eventually mounted chunks of iron to the hull of a copper clad ship in the first use of cathodic protection. Whilst this was effective in preventing the corrosion of copper, it eliminated the anti-fouling properties of the copper hull, leading to the attachment of molluscs and barnacles to the "protected" hull, slowing these ships and requiring extensive time in dry docks for defouling operations.
 +
Davy’s mother died in 1826, and Davy took sick soon after. His illness worsened over time, but he continued to write, completing “Hints and Experiments in Physical Science,” and a memoir. As his physical condition deteriorated, he traveled to Europe, spending some time in Italy, where he was joined by his wife. Davy appeared to be making a recovery, and the couple went to Geneva, where Davy, unexpectedly, died in the early morning hours of May 29th, 1829.
  
===Davy lamp===
+
==Assessment==
 
+
Davy left many piecemeal contributions to chemistry, but no overarching theory to which he could lay claim. Perhaps his most important discoveries were his researches into the nature of chlorine, which not only proved that the gas was an element, but also shed new light on the nature of acids. His identification of interatomic forces with electricity was also an important milestone.
After his return to England in 1815, Davy went on to produce the [[Davy lamp]] which was used by miners, although there is evidence to show that Davy "invented" his device at about the same time as an engineer, [[George Stephenson]], but claimed all the credit for the invention.
+
Faraday was able to push forward the boundaries of the breaking theories of his time. He did much to popularize science through his lectures, which were well attended and tickets to which were often scarce and hard to come by.  
 
+
In his later years, as his career waned, he seemed to be more of an obstacle to progress than the cheerleader he was in earlier years. Throwing cold water on a protégé who would later be hailed as one of the greatest scientists that ever lived was not the best way to improve one’s image for posterity. It would seem that he got what he wanted out of his career, but in the end found it all wanting, in contrast to Faraday, for example, whose religious convictions led him to believe that he was more a servant of the divine than a cheerleader for science. Still, Davy’s hunger for experimental truth may have rubbed off on Faraday, who by the estimation of some commentators was said to have been the greatest experimental scientist of all time.
He also showed that [[oxygen]] could not be obtained from the substance known as [[Chlorine|oxymuriatic acid]] and proved the substance to be an element, which he named chlorine. (However [[Carl Scheele]] is credited as the discoverer of chlorine. Scheele had discovered it 36 years before Davy, but was unable to publish his findings.)  This discovery overturned [[Antoine Lavoisier|Lavoisier's]] definition of acids as compounds of oxygen.
 
 
 
===Acid and bases studies===
 
 
 
In 1815 Davy suggested that acids were substances that contained replaceable [[hydrogen]] &ndash; hydrogen that could be partly or totally replaced by [[metals]]. When acids reacted with metals they formed [[salt]]s. [[Base (chemistry)|Base]]s were substances that reacted with acids to form salts and water. These definitions worked well for most of the century. Today we use the [[Brønsted-Lowry]] theory of acids and bases.
 
 
 
In 1818, he was awarded a [[baronet|baronetcy]] and two years later he became President of the [[Royal Society]].
 
 
 
==Further electrochemistry studies==
 
 
 
In 1824 he proposed and eventually mounted chunks of iron to the hull of a copper clad ship in the first use of [[cathodic protection]]. Whilst this was effective in preventing the corrosion of copper, it eliminated the [[bottom paint|anti-fouling properties]] of the copper hull, leading to the attachment of molluscs and barnacles to the "protected" hull, slowing these ships and requiring extensive time in dry docks for defouling operations.He discoverd Calcium in 1808 in London England.
 
 
 
==Death==
 
 
 
Davy died in [[Switzerland]] in 1829, his various inhalations of chemicals finally taking its toll on his health. He is buried in the Plain Palais Cemetery in [[Geneva]].
 
 
 
Davy's laboratory assistant, [[Michael Faraday]], went on to enhance Davy's work and in the end became more famous and influential &ndash; to such an extent that Davy is supposed to have claimed Faraday as his greatest discovery. However, he later accused Faraday of [[plagiarism]], causing Faraday (the first Fullerian Professor of Chemistry) to cease all research in [[classical electromagnetism|electromagnetism]] until his mentor's death.
 
  
 
==In memory of Davy==
 
==In memory of Davy==

Revision as of 21:40, 17 March 2007

Sir Humphry Davy

File:Sir Humphry Davy2.jpg
Sir Humphry Davy
Born

December 17, 1778
Penzance, Cornwall, United Kingdom

Died May 29, 1829

Geneva, Switzerland

Field Physicist and Chemist
Institutions Royal Institution
Notable students  Michael Faraday
Known for Electrolysis, Chlorine, Davy lamp

Sir Humphry Davy, 1st Baronet, FRS (17 December 1778 – 29 May 1829) was an esteemed British chemist and physicist who vastly expanded chemical knowledge by isolating and identifying a host of new elements and by linking the action of acids to hydrogen instead of oxygen. He was also an inventor, and the mentor of Michael Faraday, who for many years was Davy’s assistant and whose researches in electricity and magnetism formed the foundation for our modern understanding of that field.

Biography

Davy was born in Penzance, Cornwall, United Kingdom, the son of Robert Davy and Grace Millett. He grew up in a household of humble means. When he turned 14, his parents managed to send him to Cardew’s school in Truro, where he put in a mixed performance. He left Cardew around the time of his father’s death a year later, and by age 17 was apprenticed to a physician. By age 19, he began more formal studies of chemistry and geometry. When he turned 20, he was appointed by a physician, Thomas Beddoes, as superintendent of the laboratory for the then newly-established Medical Pneumatic Institution of Bristol. The purpose of the institute was to investigate medical applications for newly discovered “airs” or gases such as oxygen, hydrogen and carbon dioxide, the chemical properties of which were beginning to become known. His earliest researches, dating back to 1799, led to his first important discovery, nitrous oxide, often known as laughing gas, which in more modern times has been used as an anesthetic during surgery. This discovery, and the fame it brought, led to his invitation by scientist Benjamin Thompson (Count Rumford) (1753-1814), to head the laboratory at the Royal Institution in London. Upon taking up his duties, Davy immediately instituted a series of lectures on chemistry, which became very popular and increased his fame.

Electrochemistry work

Humphry Davy in his youth.

The experiments of Luigi Galvani, accounts of which were published in 1791, showed that electricity could be generated by placing metal in contact with the nerves and muscles in a frog’s leg. This principle was taken up by Alessandro Volta between 1796 and 1800, which, combined with his own observations, led him to create the first electric battery. It was later shown that water and other substances could be decomposed into their constituent elements through chemical action at the poles of a battery. This discovery captured the interest of Davy, who had at his disposal at the Royal Institution just such a battery. As a result of preliminary experiments, Davy proposed that the action that brings two elements together to form a compound is electrical. He set about to create a table of the energies needed to decompose a number of compounds through electrolysis. These results, and Davy’s conclusions, were set forward in the Bakerian Lecture of 1806, and established the direction research in electrochemical action was to take for decades hence. In 1807 Davy applied what was then one of the most powerful electric batteries to the decomposition of potassium and sodium salts, and succeeded in isolating the two metals and demonstrating that they were elements. The next year, using the same method, he isolated and identifying the elements calcium, magnesium, barium and strontium. In 1810, using an improved and more powerful version of his voltaic battery, Davy produced the first arc light using poles of carbon to produce an electric arc. Chemists at this time believed, in accordance with the conclusions of Lavoisier, that acids were oxygen-based. But Davy’s investigation of hydrochloric acid (a compound of hydrogen and chlorine only), published in 1811, demonstrated that the compound contained no oxygen. He also clearly stated that chlorine, which at the time was thought to be a compound of hydrochloric acid and oxygen, was actually an element, and gave it the name it has today. This discovery led to the identification of iodine and flourine as elements as well, and to a new understanding of acids as hydrogen-based.

Retirement and further work

In 1812 Davy was knighted by King George III, gave a farewell lecture to the Royal Institution, and married a wealthy widow, Jane Apreece. Later that year, Davy and his wife traveled through Scotland, but after their return to London, he was injured in an explosion in his laboratory while investigating a chemical compound of nitrogen and chlorine. It was this fateful injury that caused Davy to hire Michael Faraday as a secretary. Only months later, Faraday was asked by Davy to assume the role of laboratory assistant at the Royal Institution. By October 1813 Davy and his wife, accompanied by Faraday, who was also compelled to act as the couple’s valet, were on their way to France to collect a medal that Napoleon Bonaparte had awarded Davy for his electro-chemical work. Whilst in Paris, Davy was shown a mysterious substance isolated by Barnard Courtois. Davy pronounced it to be an element, which is now called iodine. In Florence, in a series of experiments, Davy, with Faraday's assistance, succeeded in using the sun's rays to ignite diamond, and proved that it was composed of pure carbon. The entourage also visited Alessandro Volta. Based on a series of lectures delivered at the request of the Board of Agriculture, Davy published Elements of Agricultural Chemistry in 1813. After his return to England in 1815, Davy invented the Davy lamp, a safe method of illumination used by miners. He thought that this was one of his greatest achievements, but his claim to the invention, for which he demanded no royalties, was later challenged by others.

Later Years

In 1818, Davy was awarded a baronetcy and two years later became president of the Royal Society, a post he would hold until 1827.

In 1820s, Davy and his friend, William Hyde Wollaston, took up research in electricity and magnetism. Faraday also conducted research in the field, and published several papers, including one that demonstrated a way to create a motor from the magnetic force generated by a current-carrying wire. Davy felt that Faraday had taken credit for research that others had done, but Faraday refused to back down. This created friction between the two men, and apparently stalled Faraday’s research in the field, which he did not take up again until after Davy’s death. Davy was known to have been opposed to the election of Faraday as a fellow of the Royal Society, but Faraday was elected over his objections. In 1824 Davy proposed and eventually mounted chunks of iron to the hull of a copper clad ship in the first use of cathodic protection. Whilst this was effective in preventing the corrosion of copper, it eliminated the anti-fouling properties of the copper hull, leading to the attachment of molluscs and barnacles to the "protected" hull, slowing these ships and requiring extensive time in dry docks for defouling operations. Davy’s mother died in 1826, and Davy took sick soon after. His illness worsened over time, but he continued to write, completing “Hints and Experiments in Physical Science,” and a memoir. As his physical condition deteriorated, he traveled to Europe, spending some time in Italy, where he was joined by his wife. Davy appeared to be making a recovery, and the couple went to Geneva, where Davy, unexpectedly, died in the early morning hours of May 29th, 1829.

Assessment

Davy left many piecemeal contributions to chemistry, but no overarching theory to which he could lay claim. Perhaps his most important discoveries were his researches into the nature of chlorine, which not only proved that the gas was an element, but also shed new light on the nature of acids. His identification of interatomic forces with electricity was also an important milestone. Faraday was able to push forward the boundaries of the breaking theories of his time. He did much to popularize science through his lectures, which were well attended and tickets to which were often scarce and hard to come by. In his later years, as his career waned, he seemed to be more of an obstacle to progress than the cheerleader he was in earlier years. Throwing cold water on a protégé who would later be hailed as one of the greatest scientists that ever lived was not the best way to improve one’s image for posterity. It would seem that he got what he wanted out of his career, but in the end found it all wanting, in contrast to Faraday, for example, whose religious convictions led him to believe that he was more a servant of the divine than a cheerleader for science. Still, Davy’s hunger for experimental truth may have rubbed off on Faraday, who by the estimation of some commentators was said to have been the greatest experimental scientist of all time.

In memory of Davy

Statue of Sir Humphry Davy located at Market Jew Street, Penzance, Cornwall.
  • In the town of Penzance in Cornwall a statue of Davy, its most famous son, stands in front of the imposing Market House at the top of Market Jew Street, the town's main high street.
  • A secondary school in Penzance is named Humphry Davy School [1]
  • A local pub in Penzance is named the Sir Humphry Davy pub. It is located at the end of Market Jew Street.
  • The lunar crater Davy is named after Sir Humphry Davy. It has a diameter of 34 km and coordinates of 11.8S, 8.1W.

Notes


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