Promethium

From New World Encyclopedia
Revision as of 14:47, 2 April 2008 by AdminBot (contribs)
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)
Jump to: navigation, search
61 neodymiumpromethiumsamarium
-

Pm

Np
Pm-TableImage.png
General
Name, Symbol, Number promethium, Pm, 61
Chemical series lanthanides
Group, Period, Block n/a, 6, f
Appearance metallic
Atomic mass [145](0) g/mol
Electron configuration [Xe] 4f5 6s2
Electrons per shell 2, 8, 18, 23, 8, 2
Physical properties
Phase solid
Density (near r.t.) 7.26 g/cm³
Melting point 1315 K
(1042 °C, 1908 °F)
Boiling point 3273 K
(3000 °C, 5432 °F)
Heat of fusion 7.13 kJ/mol
Heat of vaporization 289 kJ/mol
Atomic properties
Crystal structure hexagonal
Oxidation states 3
(mildly basic oxide)
Electronegativity  ? 1.13 (Pauling scale)
Ionization energies
(more)
1st: 540 kJ/mol
2nd: 1050 kJ/mol
3rd: 2150 kJ/mol
Atomic radius 185 pm
Atomic radius (calc.) 205 pm
Miscellaneous
Magnetic ordering no data
Electrical resistivity (r.t.) est. 0.75 µΩ·m
Thermal conductivity (300 K) 17.9 W/(m·K)
Thermal expansion (r.t.) (α, poly)
est. 11 µm/(m·K)
Speed of sound (thin rod) (r.t.) (α form) est. 46 m/s
Shear modulus (α form) est. 18 GPa
Bulk modulus (α form) est. 33 GPa
Poisson ratio (α form) est. 0.28
CAS registry number 7440-12-2
Notable isotopes
Main article: Isotopes of promethium
iso NA half-life DM DE (MeV) DP
145Pm syn 17.7 y ε 0.163 145Nd
146Pm syn 5.53 y ε 1.472 146Nd
β- 1.542 146Sm
147Pm syn 2.6234 y β- 0.224 147Sm

Promethium (chemical symbol Pm, atomic number 61) is a metallic element that is a member of the lanthanide series of chemical elements. All of its isotopes are radioactive. As a source of beta radiation, it is used in thickness gauges and in light signals in which a phosphor is activated by the beta rays. It is also used in a type of nuclear battery. In the future, it may be used as a portable X-ray source, or as a source of auxiliary heat or power for space probes and satellites.

Contents

Occurrence

Promethium can be formed as a product of uranium fission. Only trace amounts can be found in naturally occurring uranium ores. For example, a sample of pitchblende was found to contain promethium at a concentration of four parts per quintillion (1018) by mass.[1]

Promethium has also been identified in the spectrum of the star HR 465 in Andromeda, and possibly HD 101065 (Przybylski's star) and HD 965.[2]

History

The existence of promethium was first predicted by Bohuslav Brauner in 1902; this prediction was supported by Henry Moseley in 1914, who found a gap for a missing element which would have atomic number 61, but was unknown (however, Moseley of course had no sample of the element to verify this). Several groups claimed to have produced the element, but they could not confirm their discoveries because of the difficulty of separating promethium from other elements. Promethium was first produced and proved to exist at Oak Ridge National Laboratory (ORNL) in 1945 by Jacob A. Marinsky, Lawrence E. Glendenin and Charles D. Coryell by separation and analysis of the fission products of uranium fuel irradiated in the Graphite Reactor; however, being too busy with defense-related research during World War II, they did not announce their discovery until 1947.[3] The name promethium is derived from Prometheus in Greek mythology, who stole the fire of the sky and gave it to mankind. The name was suggested by Grace Mary Coryell, Charles Coryell's wife, who felt that they were stealing fire from the gods.

In 1963, ion-exchange methods were used at ORNL to prepare about ten grams of promethium from nuclear reactor fuel processing wastes.

Today, promethium is still recovered from the byproducts of uranium fission; it can also be produced by bombarding 146Nd with neutrons, turning it into 147Nd which decays into 147Pm through beta decay with a half-life of 11 days.

Notable characteristics

Promethium is an inner transition metal (or lanthanide) that lies in period six of the periodic table, between neodymium and samarium. Pure promethium exists in two allotropic forms and its chemistry is similar to that of other lanthanides.

Promethium has one semi-stable isotope (145) that is a soft beta emitter. It does not emit gamma rays, but beta particles impinging on elements of high atomic numbers can generate X-rays. Promethium salts luminesce in the dark with a pale blue or greenish glow due to their high radioactivity.

Isotopes

36 radioisotopes of promethium have been characterized, with the most stable being 145Pm with a half-life of 17.7 years, 146Pm with a half-life of 5.53 years, and 147Pm with a half-life of 2.6234 years. All of the remaining radioactive isotopes have half-lives that are less than 364 days, and the majority of these have half lives that are less than 27 seconds. This element also has 11 meta states with the most stable being 148Pmm (T½ 41.29 days), 152Pmm2 (T½ 13.8 minutes) and 152Pmm (T½ 7.52 minutes).

The isotopes of promethium range in atomic weight from 127.9482600 u (128Pm) to 162.9535200 u (163Pm). The primary decay mode before the longest-lived isotope, 145Pm, is electron capture, and the primary mode after is beta minus decay. The primary decay products before 145Pm are neodymium (Nd) isotopes and the primary products after are samarium (Sm) isotopes.

Stability of promethium isotopes

Beside technetium, promethium is one of the two elements with an atom number less than 83 that solely has unstable isotopes, which is a rarely occurring effect of the liquid drop model and stabilities of neighbor element isotopes.

Compounds

Promethium compounds include:

Applications

Uses for promethium include:

  • Beta radiation source for thickness gauges.
  • Light source for signals that require reliable, independent operation (using phosphor to absorb the beta radiation and produce light).
  • In a nuclear battery in which photocells convert the light into electric current, yielding a useful life of about five years using 147-Pm.
  • Promethium(III) chloride (PmCl3) mixed with zinc sulfide (ZnS) was used for a while as luminous paint for watches after radium was discontinued. Still used for some luminous paint applications.
  • Possibly in the future as a portable X-ray source, as an auxiliary heat or power source for space probes and satellites.

Precautions

Promethium must be handled with great care because of its high radioactivity. In particular, promethium can emit X-rays during its beta decay. Note that its half-life is less than that of plutonium-239 by a factor of multiple thousands to tens of thousands. Promethium has no biological role.

See also

Notes

  1. Attrep, Moses, Jr. and and P. K. Kuroda (May 1968). Promethium in pitchblende. Journal of Inorganic and Nuclear Chemistry 30 (3): 699–703.
  2. Cowley, C. R. and W. P. Bidelman, S. Hubrig, G. Mathys, and D. J. Bord (2004). On the possible presence of promethium in the spectra of HD 101065 (Przybylski's star) and HD 965. Astronomy & Astrophysics 419: 1087–1093.
  3. (2003). Discovery of Promethium. ORNL Review 36 (1). Retrieved December 14, 2007.

References

  • Chang, Raymond. 2006. Chemistry. 9th ed. New York: McGraw-Hill Science/Engineering/Math. ISBN 0073221031
  • Cotton, F. Albert, and Geoffrey Wilkinson. 1980. Advanced Inorganic Chemistry. 4th ed. New York: Wiley. ISBN 0-471-02775-8
  • Greenwood, N.N. and A. Earnshaw. 1998. Chemistry of the Elements. 2nd ed. Oxford, UK; Burlington, MA: Butterworth-Heinemann, Elsevier Science. ISBN 0750633654
  • "Promethium" Los Alamos National Laboratory, Chemistry Division. Retrieved December 14, 2007.
  • Stwertka, Albert. 1998. Guide to the Elements. Rev. ed. Oxford, UK: Oxford University Press. ISBN 0-19-508083-1

External links

Credits

New World Encyclopedia writers and editors rewrote and completed the Wikipedia article in accordance with New World Encyclopedia standards. This article abides by terms of the Creative Commons CC-by-sa 3.0 License (CC-by-sa), which may be used and disseminated with proper attribution. Credit is due under the terms of this license that can reference both the New World Encyclopedia contributors and the selfless volunteer contributors of the Wikimedia Foundation. To cite this article click here for a list of acceptable citing formats.The history of earlier contributions by wikipedians is accessible to researchers here:

Note: Some restrictions may apply to use of individual images which are separately licensed.

Research begins here...