Difference between revisions of "Petroleum" - New World Encyclopedia

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[[Image:Oil well3419.jpg|frame|[[Nodding donkey]] pumping an oil well near [[Sarnia, Ontario]], 2001]]
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:''"Crude oil" redirects here.''
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[[Image:Oil well.jpg|thumb|right|250px|[[Pumpjack]] pumping an oil well near [[Lubbock, Texas]]]]
  
'''Petroleum''' (from [[Greek]] ''petra'' – [[rock (geology)|rock]] and ''oleum'' – [[oil]]), '''crude oil''', sometimes colloquially called ''black gold'', is a thick, dark brown or greenish [[liquid]]. A widely believed myth is that the oil itself is [[flammable]], however it is actually the gas that evaporates from the oil that is flammable. Petroleum exists in the upper strata of some areas of the [[Earth]]'s [[Crust (geology)|crust]]. Another name is '''naphtha''', from [[Persian language|Persian]] ''naft'' or ''nafátá'' (to flow). It consists of a complex mixture of various [[hydrocarbon|hydrocarbons]], largely of the [[alkane]] series, but may vary much in appearance, composition, and purity. It is an important "[[primary energy]]" source ([http://www.iea.org/bookshop/add.aspx?id=144 IEA Key World Energy Statistics]). Petroleum is also the raw material for many [[chemical]] products, including [[solvent]]s, [[fertilizer]]s, [[pesticide]]s, and [[plastic]]s.
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'''Petroleum''' ([[Latin]] ''Petroleum'' derived from [[Greek language|Greek]] πέτρα (Latin ''petra'') - rock + έλαιον (Latin ''oleum'') - oil) or '''crude oil''' is a naturally occurring liquid found in formations in the [[Earth]] consisting of a complex mixture of [[hydrocarbon]]s (mostly [[alkane]]s) of various lengths. The approximate length range is C<sub>5</sub>H<sub>12</sub> to C<sub>18</sub>H<sub>38</sub>. Any shorter hydrocarbons are considered [[natural gas]] or [[natural gas liquids]], while long-chain hydrocarbons are more viscous, and the longest chains are [[paraffin|paraffin wax]]. In its naturally occurring form, it may contain other nonmetallic elements such as [[sulfur]], [[oxygen]], and [[nitrogen]].<ref> Manual of Petroleum Measurement Standards (MPMS), by the American Petroleum Institute</ref> It is usually black or dark brown (although it may be yellowish or even greenish) but varies greatly in appearance, depending on its composition. Crude oil may also be found in semi-solid form mixed with sand, as in the [[Athabasca oil sands]] in [[Canada]], where it may be referred to as crude [[bitumen]].
  
==Origin==
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Petroleum is used mostly, by volume, for producing [[fuel oil]] and [[gasoline]] ([[petrol]]), both important "[[primary energy]]" sources. In a typical [[barrel]] 84 percent (37 of 42 [[gallon]]s) of the hydrocarbons present in petroleum is converted into energy-rich fuels (petroleum-based fuels), including gasoline, diesel, jet, heating, and other fuel oils, and [[liquefied petroleum gas]].<ref>[http://www.eia.doe.gov/kids/energyfacts/sources/non-renewable/oil.html#Howused "Crude oil is made into different fuels"]. Energy Kids Page. Retrieved August 25, 2007.</ref>
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Due to its high [[energy density]], easy [[transport]]ability and [[oil reserves|relative abundance]], it has become the world's most important source of energy since the mid-1950s. Petroleum is also the raw material for many [[chemical]] products, including [[solvent]]s, [[fertilizer]]s, [[pesticide]]s, and [[plastic]]s; the 16 percent not used for energy production is converted into these other materials.
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{{toc}}
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Petroleum is found in [[porosity|porous]] [[rock formations]] in the upper [[strata]] of some areas of the [[Earth]]'s [[crust (geology)|crust]]. There is also petroleum in [[oil sands]]. Known [[oil reserves|reserves of petroleum]] are typically estimated at around 1.2 trillion barrels without oil sands <ref>[http://www.eia.doe.gov/emeu/international/reserves.html EIA reserves estimates]. Energy Information Administration. Retrieved August 25, 2007.</ref>, or 3.74 trillion barrels with oil sands<ref> [http://www.cera.com/aspx/cda/public1/news/pressReleases/pressReleaseDetails.aspx?CID=8444 CERA report on total world oil]. CERA. Retrieved August 25, 2007.</ref> However, oil production from oil sands is currently severely limited. Consumption is currently around 84 million barrels per day, or 4.9 trillion liters per year. Because of [[reservoir engineering]] difficulties, recoverable oil reserves are significantly less than total oil-in-place. At current consumption levels, and assuming that oil will be consumed only from reservoirs, known reserves would be gone in about 32 years, around 2039, potentially leading to a global [[energy crisis]]. However, this ignores any new discoveries, changes in consumption, using oil sands, using synthetic petroleum, and other factors. 
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[[Image:Ignacy Lukasiewicz.jpg|thumb|right|250px|[[Ignacy Łukasiewicz]] - inventor of the refining of kerosene from crude oil.]]
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==Formation==
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===Chemistry===
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[[Image:Octane molecule 3D model.png|thumb|right|250px|[[Octane]], a [[hydrocarbon]] found in petroleum, lines are [[single bond]]s, black [[spheres]] are [[carbon]], white spheres are [[hydrogen]]]]
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The chemical structure of petroleum is composed of [[hydrocarbon]] [[chains]] of different lengths. These different hydrocarbon chemicals are separated by [[distillation]] at an oil refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbons. The general formula for these [[alkanes]] is ''C<sub>n</sub>H<sub>2n+2</sub>''. For example [[2,2,4-trimethylpentane]] (isooctane), widely used in [[gasoline]], has a chemical formula of ''C<sub>8</sub>H<sub>18</sub>'' and it reacts with oxygen [[exothermic]]ally:<ref>WebMO[http://www.webmo.net/curriculum/heat_of_combustion/heat_of_combustion_key.html Heat of Combustion of Fuels.]Classroom-tested WebMO Exercises. Retrieved August 25, 2007.</ref>
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<!-- Alternate way to display
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C<sub>8</sub>H<sub>18</sub>''(aq)'' + 12.5O<sub>2</sub>''(g)'' &rarr; 8CO<sub>2</sub>''(g)'' + 9H<sub>2</sub>O''(g)'' + heat
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—>
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<math>2C_8 H_{18(l)} + 25O_{2(g)} \rightarrow \; 16CO_{2(g)} + 18H_2 O_{(l)} + heat</math>
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Incomplete combustion of petroleum or gasoline results in emission of poisonous gases such as [[carbon monoxide]] and/or [[nitric oxide]]. For example:
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<!-- Alternate way to display
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C<sub>8</sub>H<sub>18</sub>''(aq)'' + 12.5O<sub>2</sub>''(g)'' + N<sub>2</sub>''(g)'' &rarr; 6CO<sub>2</sub>''(g)'' + 2CO''(g)'' + 2NO''(g)'' + 9H<sub>2</sub>O''(g)'' + heat
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—>
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<math>C_8 H_{18(l)} + 12.5O_{2(g)} + N_{2(g)} \rightarrow \; 6CO_{2(g)} + 2CO_{(g)} +2NO_{(g)} + 9H_2 O_{(l)} + heat</math>
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Formation of petroleum occurs in a variety of mostly [[endothermic]] reactions in high temperature and/or pressure. For example, a [[kerogen]] may break down into [[hydrocarbons]] of different lengths.<ref>[http://www.osti.gov/bridge/servlets/purl/10169154-cT5xip/10169154.PDF Petroleum Study]. DOE "Technical and Scientific Information" Bridge. Retrieved August 25, 2007.</ref>
  
 
===Biogenic theory===
 
===Biogenic theory===
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Most [[geology|geologist]]s view crude oil  and [[natural gas]] as the product of [[diagenesis|compression and heating]] of ancient [[organic compound|organic materials]] over [[geologic time scale|geological time]]. According to this [[theory]], oil is formed from the preserved remains of [[prehistory|prehistoric]] [[zooplankton]] and [[algae]] which have been settled to the sea (or lake) bottom in large quantities under [[anoxic sea water|anoxic conditions]]. [[Terrestrial plant]]s, on the other hand, tend to form [[coal]]. Over geological time this organic [[matter]], mixed with [[mud]], is buried under heavy layers of sediment. The resulting high levels of [[heat]] and [[pressure]] cause the organic matter to chemically change during diagenesis, first into a waxy material known as [[kerogen]] which is found in various [[oil shales]] around the world, and then with more heat into liquid and gaseous hydrocarbons in a process known as [[catagenesis (geology)|catagenesis]]. Because most hydrocarbons are [[buoyancy|lighter]] than rock or water, these sometimes migrate upward through adjacent rock layers until they become trapped beneath impermeable rocks, within porous rocks called [[oil reservoir|reservoirs]]. Concentration of hydrocarbons in a trap forms an [[oil field]], from which the liquid can be extracted by [[drill]]ing and [[pump]]ing. Geologists often refer to an "oil window" which is the temperature range that oil forms in—below the minimum temperature oil remains trapped in the form of kerogen, and above the maximum temperature the oil is converted to natural gas through the process of [[thermal cracking]]. Though this happens at different depths in different locations around the world, a 'typical' depth for the oil window might be 4&ndash;6&nbsp;km. Note that even if oil is formed at extreme depths, it may be trapped at much shallower depths, even if it is not formed there (the [[Athabasca Oil Sands]] is one example). Three conditions must be present for oil reservoirs to form: first, a source rock rich in organic material buried deep enough for subterranean heat to cook it into oil; second, a [[porous]] and [[permeability (fluid)|permeable]] reservoir rock for it to accumulate in; and last a cap rock (seal) that prevents it from escaping to the surface.
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The vast majority of oil that has been produced by the earth has long ago escaped to the surface and been [[biodegradation|biodegraded]] by oil-eating bacteria. Oil companies are looking for the small fraction that has been trapped by this rare combination of circumstances. [[Oil sands]] are reservoirs of partially biodegraded oil still in the process of escaping, but contain so much migrating oil that, although most of it has escaped, vast amounts are still present - more than can be found in conventional oil reservoirs. On the other hand, [[oil shale]]s are source rocks that have never been buried deep enough to convert their trapped kerogen into oil.
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The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where kerogen is broken down to oil and natural gas by a set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions. The first set was originally patented in 1694 under British Crown Patent No. 330 covering,
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<blockquote>"a way to extract and make great quantityes of pitch, tarr, and oyle out of a sort of stone."</blockquote>
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The latter set is regularly used in [[petrochemical]] plants and [[oil refineries]].
  
Most [[geology|geologist]]s view crude oil, like [[coal]] and [[natural gas]], as the product of [[diagenesis|compression and heating]] of ancient [[vegetation]] over [[geological time scale]]s. According to this [[theory]], it is formed from the decayed remains of [[prehistory|prehistoric]] [[marine]] [[animal]]s and terrestrial [[plant]]s. Over many [[century|centuries]] this [[organic]] [[matter]], mixed with [[mud]], is buried under thick [[sedimentary]] layers of material. The resulting high levels of [[heat]] and [[pressure]] cause the remains to metamorphose, first into a waxy material known as [[kerogen]], and then into liquid and gaseous hydrocarbons in a process known as [[catagenesis (geology)|catagenesis]]. These then migrate through adjacent rock layers until they become trapped underground in [[pore|porous]] rocks called [[reservoir]]s, forming an [[oil field]], from which the liquid can be extracted by [[drill]]ing and [[pump]]ing.
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===Abiogenic theory===
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{{main|Abiogenic petroleum origin}}
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The idea of [[abiogenic petroleum origin]] was championed in the [[Western world]] by astronomer [[Thomas Gold]] based on thoughts from [[Russia]], mainly on studies of [[Nikolai Kudryavtsev]]. The idea proposes that hydrocarbons of purely geological origin exist in the [[planet]]. Hydrocarbons are less dense than aqueous pore fluids, and are proposed to migrate upward through deep fracture networks. [[extremophile|Thermophilic]], rock-dwelling [[microorganism|microbial life]]-forms are proposed to be in part responsible for the [[biomarker]]s found in petroleum.
  
These reactions are thought to be very temperature sensitive:  reactions that produce recognizable oil kick in at about 130&nbsp;°C, and those that continue the breakdown of oil to natural gas kick in by about 180&nbsp;°C.  The range of 130 - 150&nbsp;°C is generally considered the "oil window".  Though this corresponds to different depths for different locations around the world, a 'typical' depth for an oil window might be 4 - 5 km.  Three conditions must be present for oil reservoirs to form:  a rich source rock, a migration conduit, and a trap (seal) that forms the reservoir.
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This theory is a minority opinion, especially amongst geologists; no oil companies are currently known to explore for oil based on this theory.
  
The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where kerogen breaks down to oil and natural gas by a large set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions.
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==Classification==
  
===Abiogenic theory===
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The [[oil industry]] classifies "crude" by the location of its origin (e.g., "West Texas Intermediate, WTI" or "Brent") and often by its [[API gravity|relative weight]] or [[viscosity]] ("[[Light crude oil|light]]," "intermediate" or "[[Heavy crude oil|heavy]]"); refiners may also refer to it as "[[sweet crude oil|sweet]]," which means it contains relatively little [[sulfur]], or as "[[sour crude oil|sour]]," which means it contains substantial amounts of sulfur and requires more refining in order to meet current product specifications. Each crude oil has unique molecular characteristics which are understood by the use of [[Crude oil assay|crude oil assay analysis]] in petroleum laboratories.
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[[barrel (unit)|Barrel]]s from an area in which the crude oil's molecular characteristics have been determined and the oil has been classified are used as pricing [[Benchmark (crude oil)|references]] throughout the world. These references are known as Crude oil benchmarks:
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* [[Brent Crude]], comprising 15 oils from fields in the [[Brent oilfield|Brent]] and [[Ninian]] systems in the [[East Shetland Basin]] of the [[North Sea]]. The oil is landed at [[Sullom Voe]] terminal in the [[Shetlands]]. Oil production from Europe, Africa and Middle Eastern oil flowing West tends to be priced off the price of this oil, which forms a [[benchmark]].
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* [[West Texas Intermediate]] (WTI) for North American oil.
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* [[Dubai Crude|Dubai]], used as benchmark for Middle East oil flowing to the [[Asia]]-[[Pacific]] region.
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* Tapis (from [[Malaysia]], used as a reference for light Far East oil)
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* Minas (from [[Indonesia]], used as a reference for heavy Far East oil)
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* The [[OPEC Reference Basket]], a weighted average of oil blends from various [[OPEC]] (The Organization of the Petroleum Exporting Countries) countries.
  
[[Thomas Gold]] was the most widely known [[Western world|Western]] proponent of the [[Russia|Russian]]-[[Ukraine|Ukrainian]] theory of [[abiogenic petroleum origin]]. This theory suggests that large amounts of [[carbon]] exist naturally in the [[planet]], some in the form of hydrocarbons.  Hydrocarbons are less dense than aqueous pore fluids, and migrate upward through deep fracture networks.  [[extremophile|Thermophilic]], rock-dwelling [[microorganism|microbial life]]-forms are in part responsible for the [[biomarker]]s found in petroleum.  However, their role in the formation, alteration, or contamination of the various hydrocarbon deposits is not yet understood{{ref|Kenney2001}}.  Thermodynamic calculations{{ref|Kenney2002}} and experimental studies confirm that n-alkanes (common petroleum components) do not spontaneously evolve from [[methane]] at pressures typically found in sedimentary basins, and so the theory of an abiogenic origin of hydrocarbons suggests deep generation (below 200 km) (see [http://www.gasresources.net/ results]).
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==Means of production==
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{{main|Petroleum Industry}}
  
==Composition==
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===Extraction===
  
In [[refining]], the component chemicals of petroleum are separated by [[fractional distillation]], which is a separation based on relative [[boiling points]] (or equivalently relative [[volatility]]).  The different products (in order of boiling points) include light gases (e.g. methane, [[ethane]], [[propane]]), [[gasoline]], [[jet fuel]], [[kerosene]], [[diesel]], [[gasoil]], [[paraffin wax]], and [[asphalt]].  Subtler techniques, such as [[gas chromatography]], [[HPLC]], and [[GC-MS]], can separate some fractions of petroleum into individual compounds; these are [[analytical chemistry]] methods used mainly in [[quality control]] in [[oil refinery|refineries]].
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{{Main|Extraction of petroleum}}
  
Strictly speaking, petroleum consists of hydrocarbons (compounds of [[hydrogen]] and carbon) and non-hydrocarbon fractions, which might also include [[nitrogen]], [[sulfur]], [[oxygen]], or traces of [[metal]]s such as [[vanadium]] or [[nickel]], such [[chemical element|element]]s often constituting less than 1% of the whole.
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The most common method of obtaining petroleum is extracting it from [[oil well]]s found in [[oil field]]s. After the well has been located, various methods are used to recover the petroleum. Primary recovery methods are used to extract oil that is brought to the surface by underground pressure, and can generally recover about 20 percent of the oil present. After the oil pressure has depleted to the point that the oil is no longer brought to the surface, secondary recovery methods draw another 5 to 10 percent of the oil in the well to the surface. Finally, when secondary oil recovery methods are no longer viable, tertiary recovery methods reduce the [[viscosity]] of the oil in order to bring more to the surface.
  
The four lightest [[alkanes]] &mdash; CH<sub>4</sub> (methane), C<sub>2</sub>H<sub>6</sub> (ethane), C<sub>3</sub>H<sub>8</sub>
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===Alternative methods===
(propane) and C<sub>4</sub>H<sub>10</sub> ([[butane]]) &mdash; are all gases, boiling at -161.6&nbsp;°C, -88.6&nbsp;°C, -42&nbsp;°C, and -0.5&nbsp;°C, respectively (-258.9°, -127.5°, -43.6°, and +31.1° F).
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During the last [[Oil price increases of 2004-2006|oil price peak]], other alternatives to producing oil gained importance. The best known such methods involve extracting oil from sources such as [[oil shale]] or [[tar sands]]. These resources are known to exist in large quantities; however, extracting the oil at low cost without negatively impacting the environment remains a challenge.
  
The chains in the C<sub>5-7</sub> range are all light, easily vaporized, clear [[naphtha|naphthas]]. They are used as [[solvent]]s, [[dry cleaning]] fluids, and other quick-drying products. The chains from C<sub>6</sub>H<sub>14</sub> through C<sub>12</sub>H<sub>26</sub> are blended together and used for gasoline. [[Kerosene]] is made up of chains in the C<sub>10</sub> to C<sub>15</sub> range, followed by [[diesel fuel]]/[[heating oil]] (C<sub>10</sub> to C<sub>20</sub>) and heavier [[fuel oil]]s as the ones used in [[ship]] [[engine]]s. These petroleum compounds are all liquid at [[room temperature]].
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It is also possible to transform [[natural gas]] or [[coal]] into oil (or, more precisely, the various hydrocarbons found in oil). The best-known such method is the [[Fischer-Tropsch process]]. It was a concept pioneered in [[Nazi Germany]] when [[International trade|import]]s of petroleum were restricted due to war and [[Germany]] found a method to extract oil from coal. It was known as ''Ersatz'' ("substitute" in [[German language|German]]), and accounted for nearly half the total oil used in [[World War II|WWII]] by Germany. However, the process was used only as a last resort as naturally occurring oil was much cheaper. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper. The method involves converting high ash coal into [[synthetic oil]] in a multi-stage process. Ideally, a [[ton]] of coal produces nearly 200 [[liter]]s (1.25 bbl, 52 US gallons) of crude, with [[by-product]]s ranging from tar to [[Abundance of the chemical elements|rare chemicals]].
  
[[lubrication oil|Lubricating oils]] and semi-solid [[grease]]s (including [[Vaseline]]®) range from C<sub>16</sub> up to C<sub>20</sub>.
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Currently, two companies have commercialized their Fischer-Tropsch technology. Shell in [[Bintulu]], [[Malaysia]], uses [[natural gas]] as a [[feedstock]], and produces primarily low-[[sulfur]] [[diesel]] fuels.<ref>[http://www.shell.com.my/smds Shell Middle Distillate Synthesis Malaysia]. Shell Oil. Retrieved August 25, 2007.</ref> [[Sasol]]<ref>[http://www.sasol.com Sasol corporate website]. Retrieved August 25, 2007.</ref> in [[South Africa]] uses coal as a feedstock, and produces a variety of synthetic petroleum products.
  
Chains above C<sub>20</sub> form solids, starting with [[paraffin]] wax, then [[tar]] and [[asphaltic]] [[bitumen]].
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The process is today used in [[South Africa]] to produce most of the country's [[diesel]] fuel from coal by the company [[Sasol]]. The process was used in South Africa to meet its energy needs during its isolation under [[Apartheid]]. This process has received renewed attention in the quest to produce low [[sulfur]] diesel fuel in order to minimize [[the environment]]al impact from the use of diesel [[engine]]s.  
  
Boiling ranges of petroleum atmospheric pressure distillation fractions in degrees [[Celsius]]:
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An alternative method of converting coal into petroleum is the [[Karrick process]], which was pioneered in the 1930s in the [[United States]]. It uses high temperatures in the absence of ambient air, to [[distill]] the short-chain hydrocarbons of petroleum out of coal.
  
* [[petrol ether]]: 40 - 70&nbsp;°C (used as solvent)
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More recently explored is [[thermal depolymerization]] (TDP), a process for the reduction of complex [[organic material]]s into light [[crude oil]]. Using pressure and heat, long chain [[polymer]]s of [[hydrogen]], [[oxygen]], and [[carbon]] decompose into short-chain petroleum [[hydrocarbons]]. This mimics the natural [[geology|geological]] processes thought to be involved in the production of [[fossil fuel]]s. In theory, TDP can convert any organic waste into petroleum.
* light [[petrol]]: 60 - 100&nbsp;°C ([[automobile]] fuel)
 
* heavy petrol: 100 - 150&nbsp;°C (automobile fuel)
 
* light kerosene: 120 - 150&nbsp;°C (household solvent and fuel)
 
* kerosene: 150 - 300&nbsp;°C ([[jet engine]] fuel)
 
* gasoil: 250 - 350&nbsp;°C (diesel fuel/ heating)
 
* lubrication oil: > 300&nbsp;°C ([[engine oil]])
 
* remaining fractions: [[tar]], [[asphalt]], [[residual fuel]]
 
  
==Extraction==
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==History==
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Petroleum, in some form or other, is not a substance new in the world's history. More than four thousand years ago, according to [[Herodotus]] and confirmed by [[Diodorus Siculus]], [[asphalt]] was employed in the construction of the walls and towers of [[Babylon]]; there were oil pits near Ardericca (near Babylon), and a pitch spring on [[Zacynthus]].<ref>''Encyclopedia Britannica,'' (1911 ed.) "Petroleum." </ref> Great quantities of it were found on the banks of the river [[Issus (river)|Issus]], one of the tributaries of the [[Euphrates]]. Ancient [[Persian Empire|Persian]] tablets indicate the medicinal and lighting uses of petroleum in the upper levels of their society.
  
Generally the first stage in the extraction of crude oil is to drill a well into the underground reservoir. Historically, in the [[USA]] some [[oil field]]s existed where the oil rose naturally to the surface, but most of these fields have long since been depleted, except for certain remote locations in Alaska. Often many wells (called ''multilateral wells'') will be drilled into the same reservoir, to ensure that the extraction rate will be economically viable. Also, some wells (''secondary wells'') may be used to pump [[water]], [[steam]], [[acid]]s or various gas mixtures into the reservoir to raise or maintain the reservoir pressure, and so maintain an economic extraction rate.
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The first [[oil well]]s were drilled in [[China]] in the fourth century or earlier. They had depths of up to 243 meters (about 800 feet) and were drilled using [[drill bit|bits]] attached to [[bamboo]] poles. The oil was burned to evaporate [[brine]] and produce [[sodium chloride|salt]]. By the tenth century, extensive bamboo pipelines connected oil wells with salt springs. The ancient records of China and Japan are said to contain many allusions to the use of natural gas for lighting and heating. Petroleum was known as ''burning water'' in Japan in the seventh century.<ref>Ibid.</ref>
  
If the underground pressure in the oil reservoir is sufficient, then the oil will be forced to the surface under this pressure. Gaseous fuels or natural gas are usually present, which also supplies needed underground pressure. In this situation it is sufficient to place a complex arrangement of [[valve]]s (the [[Christmas tree (oilfield)|Christmas tree]]) on the [[well head]] to connect the well to a [[pipeline]] network for storage and processing. This is called primary oil recovery. Usually, only about 20% of the oil in a reservoir can be extracted this way.
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In the eighth century, the [[street]]s of the newly constructed [[Baghdad]] were paved with [[tar]], derived from easily accessible petroleum from natural fields in the region. In the 9th century, oil fields were exploited in the area around modern [[Baku]], [[Azerbaijan]], to produce [[naphtha]]. These fields were described by the [[geographer]] [[Masudi]] in the tenth century, and by [[Marco Polo]] in the thirteenth century, who described the output of those wells as hundreds of shiploads. Petroleum was first [[Distillation|distilled]] by [[Alchemy (Islam)|Muslim chemists]] in the ninth century, producing chemicals such as [[kerosene]].<ref>Kasem Ajram. ''The Miracle of Islam Science.'' (Lincolnshire, IL: Knowledge House Publishers, 1992. ISBN 0911119434).</ref> ''(See also: [[Islamic science]] and [[Timeline of science and technology in the Islamic world]].)''
  
Over the lifetime of the well the pressure will fall, and at some point there will be insufficient underground pressure to force the oil to the surface. If economical, and it often is, the remaining oil in the well is extracted using secondary oil recovery methods ''(see: [[energy balance]] and [[net energy gain]])''. Secondary oil recovery uses various techniques to aid in recovering oil from depleted or low-pressure reservoirs. Sometimes pumps, such as [[nodding donkey|beam pumps]] and [[Electrical Submersible Pumps|electrical submersible pumps]] (ESPs), are used to bring the oil to the surface. Other secondary recovery techniques increase the reservoir's pressure by [[Water injection (oil production)|water injection]], [[gas reinjection|natural gas reinjection]] and [[Gas Lift|gas lift]], which injects [[air]], [[carbon dioxide]] or some other gas into the reservoir. Together, primary and secondary recovery allow 25% to 35% of the reservoir's oil to be recovered.
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The earliest mention of American petroleum occurs in [[Sir Walter Raleigh]]'s account of the [[Trinidad]] [[Pitch Lake]] in 1595; whilst 37 years later, the account of a visit of a Franciscan, Joseph de la Roche d'Allion, to the oil springs of New York was published in Sagard's ''Histoire du Canada.'' A Russian traveller, Peter Kalm, in his work on America published in 1748 showed on a map the oil springs of Pennsylvania.<ref>''Encyclopedia Britannica'' (1911) </ref>
  
Tertiary oil recovery reduces the oil's [[viscosity]] to increase oil production. Tertiary recovery is started when secondary oil recovery techniques are no longer enough to sustain production, but only when the oil can still be extracted [[profit]]ably. This depends on the [[cost]] of the extraction method and the current [[price]] of crude oil. When prices are high, previously unprofitable wells are brought back into production and when they are low, production is curtailed. Thermally-enhanced oil recovery methods (TEOR) are tertiary recovery techniques that heat the oil and make it easier to extract. Steam injection is the most common form of TEOR, and is often done with a [[cogeneration]] plant. In this type of cogeneration plant, a [[gas turbine]] is used to generate [[electricity]] and the waste heat is used to produce steam, which is then injected into the reservoir. This form of recovery is used extensively to increase oil production in the [[San Joaquin Valley]], which has very heavy oil, yet accounts for 10% of the United State's oil production. In-situ [[burn]]ing is another form of TEOR, but instead of steam, some of the oil is burned to heat the surrounding oil. Occasionally, [[detergent]]s are also used to decrease oil viscosity. Tertiary recovery allows another 5% to 15% of the reservoir's oil to be recovered.
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The [[modern world|modern history]] of petroleum began in 1846 with the discovery of the process of refining [[kerosene]] from [[coal]] by [[Atlantic Canada]]'s [[Abraham Pineo Gesner]].  
  
===Alternate means of producing oil===
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The first modern oil well was drilled in 1745 in Pechelbronn, Alsace (France) under the direction of Louis de La Sablonniere, by special appointment of King Louis XV.<ref> Pechelbronn [http://www.musee-du-petrole.com/site%20anglais/page%204.htm History of Pechelbronn oil]. The Oil Museum. Retrieved August 25, 2007.</ref> The Pechelbronn oil field  was alive until 1970, and was the birthplace of companies like Schlumberger. The first modern refinery was built there in 1857.<ref>Ibid.</ref>
  
As oil prices continue to escalate, other alternatives to producing oil have been gaining importance. The most viable of these is the coal to oil process, known as the [[Fischer-Tropsch process]], that aims to convert coal into crude oil. It was a concept pioneered in [[Nazi Germany]] when [[import]]s of petroleum were restricted due to war and [[Germany]] found a method to extract oil from coal. It was known as ''Ersatz'' ("substitute" in [[German language|German]]), and accounted for nearly half the total oil used in [[WWII]] by Germany. However, the process was used only as a last resort as naturally occuring oil was much cheaper. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper.
+
[[Poland]]'s [[Ignacy Łukasiewicz]] discovered a means of refining kerosene from the more readily available "rock oil" ("petr-oleum") in 1852 and the first rock oil mine was built in [[Bóbrka (Krosno)|Bóbrka]], near [[Krosno]] in southern Poland in the following year. These discoveries rapidly spread around the world, and [[Meerzoeff]] built the first Russian [[Oil refinery|refinery]] in the mature oil fields at [[Baku]] in 1861. At that time Baku produced about 90 percent of the world's oil.
  
The method involves converting high ash coal into synthetic oil in a multistage process. Ideally, a [[ton]] of coal produces nearly 200 [[liter]]s of crude, with [[by-product]]s ranging from tar to [[Abundance of the chemical elements|rare chemicals]].
+
[[Image:oilfield.jpg|frame|Oil field in [[California]], 1938.]]
  
Currently, two companies have commercialised their Fischer-Tropsch technology. [http://www.shell.com.my/smds Shell] in [[Bintulu]], [[Malaysia]], uses [[natural gas]] as a [[feedstock]], and produces primarily low-[[sulfur]] [[diesel]] fuels.  [http://www.sasol.com Sasol] in [[South Africa]] uses coal as a feedstock, and produces a variety of synthetic petroleum products.
+
The first commercial oil well drilled in [[North America]] was in Oil Springs, [[Ontario]], [[Canada]] in 1858, dug by James Miller Williams. The American petroleum [[industry]] began with [[Edwin Drake]]'s drilling of a 69-foot-deep oil well in 1859, on [[Oil Creek (Allegheny River)|Oil Creek]] near [[Titusville, Pennsylvania]], for the Seneca Oil Company (originally yielding 25 barrels a day, by the end of the year output was at the rate of 15 barrels).<ref> ''Encyclopedia Britannica.'' (1911) </ref> The industry grew slowly in the 1800s, driven by the demand for [[kerosene]] and [[oil lamp]]s. It became a major [[nation]]al concern in the early part of the twentieth century; the introduction of the [[internal combustion engine]] provided a demand that has largely sustained the industry to this day. Early "local" finds like those in [[Pennsylvania]] and Ontario were quickly exhausted, leading to "oil booms" in [[Texas]], [[Oklahoma]], and [[California]].
The process is today used in [[South Africa]] to produce most of the country's [[diesel]] fuel from coal by the company [[Sasol]]. The process was used in South Africa to meet its energy needs during its isolation under [[Apartheid]]. This process has received renewed attention in the quest to produce low [[sulfur]] [[diesel]] fuel in order to minimize [[the environment]]al impact from the use of diesel [[engine]]s.
 
  
==History==
+
Early production of crude petroleum in the United States:<ref>Ibid. </ref>
 +
* 1859: 2,000 barrels
 +
* 1869: 4,215,000 barrels
 +
* 1879: 19,914,146 barrels
 +
* 1889: 35,163,513 barrels
 +
* 1899: 57,084,428 barrels
 +
* 1906: 126,493,936 barrels
  
The first [[oil well]]s were drilled in [[China]] in the [[4th century]] or earlier. They had depth of up to 800 feet and were drilled using [[drill bit|bits]] attached to [[bamboo]] poles. The oil was burned to evaporate [[brine]] and produce [[sodium chloride|salt]].  By the [[10th century]], extensive [[bamboo]] pipelines connected oil wells with salt springs.
+
By 1910, significant oil fields had been discovered in [[Canada]] (specifically, in the province of [[Ontario]]), the [[Dutch East Indies]] (1885, in [[Sumatra]]), [[Iran]] (1908, in [[Masjed Soleiman]]), [[Peru]], [[Venezuela]], and [[Mexico]], and were being developed at an industrial level.
Ancient [[Persian]] tablets indicate the medicinal and lighting uses of petroleum in the upper echelons of their society.
 
  
In the [[8th century]], the [[street]]s of the newly-constructed [[Baghdad]] were paved with [[tar]], derived from easily-accessible petroleum from natural fields in the region. In the [[9th century]], oil fields were exploited in [[Baku]], [[Azerbaijan]], to produce naphtha. These fields were described by the [[geographer]] [[Masudi]] in the [[10th century]], and by [[Marco Polo]] in the [[13th century]], who described the output of those wells as hundreds of shiploads. ''(See also: [[Timeline of Islamic science and technology]].)''
+
Even until the mid-1950s, [[coal]] was still the world's foremost fuel, but oil quickly took over. Following the [[1973 energy crisis]] and the [[1979 energy crisis]], there was significant [[News media|media]] coverage of oil supply levels. This brought to light the concern that oil is a limited resource that will eventually run out, at least as an economically viable energy source. At the time, the most common and popular predictions were always quite dire, and when they did not come true, many dismissed all such discussion.  The future of petroleum as a fuel remains somewhat controversial. ''[[USA Today]]'' newspaper (2004) reports that there are 40 years of petroleum left in the ground. Some would argue that because the total amount of petroleum is finite, the dire predictions of the 1970s have merely been postponed. Others argue that technology will continue to allow for the production of cheap hydrocarbons and that the earth has vast sources of unconventional petroleum reserves in the form of [[tar sands]], bitumen fields and [[oil shale]] that will allow for petroleum use to continue in the future, with both the Canadian tar sands and United States shale oil deposits representing potential reserves matching existing liquid petroleum deposits worldwide.
  
The [[modern world|modern history]] of oil began in [[1853]], with the discovery of the process of oil distillation. Crude oil was distilled into kerosene by [[Ignacy Lukasiewicz]], a [[Poland|Polish]] [[scientist]]. The first "rock oil" mine was created in [[Bobrka]], near [[Krosno]] in southern Poland in the following year and the first [[refinery]] (actually a [[distillery]]) was built in [[Ulaszowice]], also by Lukasiewicz. These discoveries rapidly spread around the world, and [[Meerzoeff]] built the first Russian refinery in the mature oil fields at [[Baku]] in [[1861]].
+
Today, about 90 percent of vehicular fuel needs are met by oil. Petroleum also makes up 40 percenr of total energy consumption in the United States, but is responsible for only 2 percent of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important [[commodity|commodities]]. Access to it was a major factor in several military conflicts including [[World War II]] and the [[Persian Gulf War]]s of the late twentieth and early twenty-first centuries. The top three oil producing countries are [[Saudi Arabia]], [[Russia]], and the [[United States]]. About 80 percent of the world's readily accessible reserves are located in the [[Middle East]], with 62.5 pervent coming from the Arab Five: Saudi Arabia (12.5 percent), [[UAE]], [[Iraq]], [[Qatar]] and [[Kuwait]]. However, with today's oil prices, Venezuela has larger reserves than Saudi Arabia due to crude reserves derived from [[bitumen]].
  
[[Image:oilfield.jpg|frame|Oil field in [[California]], 1938]]
+
==Uses==
 +
The chemical structure of petroleum is composed of [[hydrocarbon]] chains of different lengths. Because of this, petroleum may be taken to [[oil refinery|oil refineries]] and the hydrocarbon chemicals separated by [[distillation]] and treated by other [[chemical process]]es, to be used for a variety of purposes.  See [[Petroleum product|Petroleum products]]
  
The first modern oil well was drilled in [[1848]] by Russian engineer F.N. Semyenov, on the [[Aspheron Peninsula]] north-east of [[Baku]].
+
===Fuels===
 +
*[[Ethane]] and other short-chain [[alkanes]] which are used as fuel
 +
*[[Diesel|Diesel fuel]]
 +
*[[Fuel oil]]s
 +
*[[Gasoline]]
 +
*[[Jet fuel]]
 +
*[[Kerosene]]
 +
*[[Liquid petroleum gas]] (LPG)
  
The first commercial oil well drilled in North America was in Oil Springs, [[Ontario]], [[Canada]] in [[1858]], dug by James Miller Williams. The American petroleum [[industry]] began with [[Edwin Drake]]'s discovery of oil in [[1859]], near [[Titusville, Pennsylvania]]. The industry grew slowly in the [[1800s]], driven by the demand for [[kerosene]] and [[oil lamp]]s. It became a major [[nation]]al concern in the early part of the [[20th century]]; the introduction of the [[internal combustion engine]] provided a demand that has largely sustained the industry to this day. Early "local" finds like those in [[Pennsylvania]] and [[Ontario]] were quickly exhausted, leading to "oil booms" in [[Texas]], [[Oklahoma]], and [[California]].
+
===Other derivatives===
 +
Certain types of resultant hydrocarbons may be mixed with other non-hydrocarbons, to create other end products:
  
By [[1910]], significant oil fields had been discovered in [[Canada]] (specifically, in the province of [[Alberta]]), the [[Dutch East Indies]] ([[1885]], in [[Sumatra]]), [[Persian Empire|Persia]] ([[1901]], in [[Masjed Soleiman]]), [[Peru]], [[Venezuela]], and [[Mexico]], and were being developed at an industrial level.
+
*[[Alkenes]] (olefins) which can be manufactured into [[plastics]] or other compounds
 +
*[[Lubricant]]s (produces light machine oils, [[motor oil]]s, and [[grease]]s, adding [[viscosity]] stabilizers as required).
 +
*[[Wax]], used in the packaging of [[frozen food]]s, among others.
 +
*[[Sulfur]] or [[Sulfuric acid]]. These are a useful industrial materials.  Sulfuric acid is usually prepared as the acid precursor [[oleum]], a byproduct of [[Hydrodesulfurization|sulfur removal]] from fuels. 
 +
*Bulk [[tar]].
 +
*[[Asphalt]]
 +
*[[Petroleum coke]], used in speciality carbon products or as solid fuel.
 +
*[[Paraffin wax]]
 +
*[[Aromatic]] [[petrochemical]]s to be used as precursors in other [[chemical]] production.
  
Even until the mid-([[1950s]]), [[coal]] was still the world's foremost fuel, but oil quickly took over. Following the [[1973 energy crisis]] and the [[1979 energy crisis]] there was significant [[media]] coverage of oil supply levels. This brought to light the concern that oil is a limited resource that will eventually run out, at least as an economically viable energy source. At the time, the most common and popular predictions were always quite dire, and when they did not come true, many dismissed all such discussionThe future of petroleum as a fuel remains somewhat controversial. ''[[USA Today]]'' news ([[2004]]) reports that there are 40 years of petroleum left in the ground. Some would argue that because the total amount of petroleum is finite, the dire predictions of the [[1970s]] have merely been postponed. Others argue that technology will continue to allow for the production of cheap hydrocarbons and that the earth has vast sources of unconventional petroleum reserves in the form of [[tar sands]], bitumen fields and [[oil shale]] that will allow for petroleum use to continue for an extremely long period in the future.
+
===Consumption statistics===
 +
[[Image:Global Carbon Emission by Type.png|thumb|250px|Global fossil carbon emissions, an indicator of consumption, for 1800-2000Total is black. Oil is in blue.]]
  
Today, about 90% of vehicular fuel needs are met by oil. Petroleum also makes up 40% of total energy consumption in the United States, but is responsible for only 2% of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important [[commodity|commodities]]. Access to it was a major factor in several military conflicts, including World War II and the [[Persian Gulf War]]. About 80% of the world's readily accessible reserves are located in the [[Middle East]], with 62.5% coming from the Arab 5: [[Saudi Arabia]] (12.5%), [[UAE]], [[Iraq]], [[Qatar]] and [[Kuwait]]. The USA has less than 3%.
+
<gallery>
 +
Image:Hubbert world 2004.png|2004 U.S. government predictions for oil production other than in [[OPEC]] and the [[former Soviet Union]]
 +
Image:EIA_IEO2006.jpg|World energy consumption, 1980-2030. ''Source: International Energy Outlook 2006.''
 +
</gallery>
  
 
==Environmental effects==
 
==Environmental effects==
 +
[[Image:Dieselrainbow.jpg|thumb|right|Diesel fuel spill on a road]]
 +
 +
The presence of oil has significant [[society|social]] and [[Natural environment|environment]]al impacts, from accidents and routine activities such as [[seismology|seismic]] exploration, [[drilling]], and generation of [[pollution|polluting]] wastes not produced by other alternative energies.
 +
 +
=== Extraction ===
 +
Oil extraction is costly and sometimes environmentally damaging, although Dr. [[John Hunt (oceanographer)|John Hunt]] of the [[Woods Hole Oceanographic Institution]] pointed out in a 1981 paper that over 70 percent of the reserves in the world are associated with visible [[macroseepage]]s, and many oil fields are found due to natural [[leak]]s. Offshore exploration and extraction of oil disturbs the surrounding marine environment.<ref>Stanislave Patin. [http://www.offshore-environment.com/discharges.html Waste discharges during the offshore oil and gas activity]. Offshore-environment.com. Retrieved August 25, 2007.</ref>  But at the same time, [[offshore]] [[oil platform]]s also form micro-habitats for marine creatures. Extraction may involve [[dredging]], which [[wikt:stirs up|stirs up]] the [[seabed]], [[kill]]ing the sea plants that marine creatures need to survive.
  
The presence of oil has significant [[society|social]] and [[environment]]al impacts, from accidents and routine activities such as [[seismology|seismic]] exploration, drilling, and generation of [[pollution|polluting]] wastes. Oil extraction is costly and sometimes environmentally damaging, although [[John Hunt|Dr. John Hunt]] from [[Woods Hole]] pointed out in a [[1981]] paper that over 70% of the reserves in the world are associated with visible macroseepages, and many oil fields are found due to natural leaks. Offshore exploration and extraction of oil disturbs the surrounding marine environment. Extraction may involve [[dredging]], which stirs up the [[seabed]], [[kill]]ing the sea plants that marine creatures need to survive.  Crude oil and refined fuel spills from [[tanker|tanker ship]] accidents have damaged fragile [[ecosystem]]s in [[Alaska]], the [[Galapagos Islands]], [[Spain]], and many other places. 
+
=== Oil spills ===
 +
[[Image:PrestigeVolunteersInGaliciaCoast.jpg|thumb|200px|right|Volunteers cleaning up the aftermath of the [[Prestige oil spill]]]]
  
Burning oil releases carbon dioxide into the atmosphere, which is thought to contribute to [[global warming]]. Per energy unit, oil produces less CO2 than coal, but more than natural gas.  However, oil's unique role as a [[transportation]] fuel makes reducing its CO2 emissions a particularly thorny problem; amelioration strategies such as [[carbon sequestering]] are generally geared for large [[power plant]]s, not individual tailpipes.  
+
Crude oil and refined fuel spills from [[tanker (ship)|tanker ship]] accidents have damaged natural [[ecosystem]]s in [[Alaska]], the [[Galapagos Islands]] and many other places and times in [[Spain]] (i.e. [[Ibiza]]).
  
[[Renewable energy source]] alternatives do exist, although the degree to which they can replace petroleum and the possible environmental damage they may cause are uncertain and controversial.  [[Sun]], [[wind]], [[geothermal]], and other renewable electricity sources cannot directly replace high energy density liquid petroleum for transportation use; instead automobiles and other equipment must be altered to allow using electricity (in [[battery (electricity)|batteries]]) or hydrogen (via [[fuel cell]]s or internal combustion) which can be produced from renewable sources.  Other options include using [[biomass]]-origin liquid fuels ([[ethanol]], [[biodiesel]]).  Any combination of solutions to replace petroleum as a liquid transportation fuel will be a very large undertaking.
+
=== Global warming ===
 +
{{Main|Global warming}}
 +
Burning oil releases carbon dioxide into the atmosphere, which contributes to [[global warming]]. Per energy unit, oil produces less [[carbon dioxide|CO<sub>2</sub>]] than coal, but more than natural gas. However, oil's unique role as a [[transportation]] fuel makes reducing its CO<sub>2</sub> emissions a particularly thorny problem; amelioration strategies such as [[carbon sequestering]] are generally geared for large [[power plant]]s, not individual vehicles.
  
== Future of oil ==
+
==Alternatives to petroleum==
 +
{{Main|Renewable energy}}
  
''Main article: [[Hubbert Peak]]''
+
===Alternatives to petroleum-based vehicle fuels===
 +
{{main|Alternative propulsion|Biofuel|Fuel economy|Hydrogen economy}}
  
The Hubbert peak theory, also known as '''''[[peak oil]]''''', is a controversial theory concerning the long-term rate of conventional oil and other fossil fuel production and depletion. It assumes that oil reserves are not replenishable, and predicts that future world oil production must inevitably reach a peak and then decline as these reserves are exhausted. Much of the controversy is over whether past production or discovery data can be used to predict a future peak.
+
The term alternative propulsion or "alternative methods of propulsion" includes both:
 +
* [[alternative fuel]]s used in standard or modified [[internal combustion engine]]s (i.e. combustion [[hydrogen]] or [[biofuel]]s).
 +
* propulsion systems not based on internal combustion, such as those based on [[electricity]] (for example, [[electric vehicle|all-electric]] or [[hybrid vehicle]]s), [[air vehicle|compressed air]], or [[fuel cell]]s (i.e. hydrogen fuel cells).
  
The issue can be considered from the point of view of individual regions or the world as a whole. Originally [[M. King Hubbert]] noticed that the discoveries in the United States had peaked in the early [[1930s]], and concluded that production would then peak in the early [[1970s]]. His prediction turned out to be correct, and after the US peaked in [[1971]] - and thus lost its excess production capacity - [[OPEC]] was finally able to manipulate oil prices, which led to the oil crisis in 1973. Since then, various regions have peaked, for example, the [[North Sea]] in late [[1990s]]. China has confirmed that two of its largest producing regions are in decline, and Mexico's national oil company, [[Pemex]], has announced that [[Cantarell Field]], one of the world's largest offshore fields, is expected to peak in [[2006]], and then decline 14% per annum.
+
Nowadays, cars can be classified between the next main groups:
  
For various reasons (perhaps most importantly the lack of transparency in [[accounting]] of global oil reserves), it is difficult to predict the oil peak in any given region. Based on available production data, proponents have previously (and incorrectly) predicted the peak for the world to be in years [[1989]], [[1995]], or 1995-[[2000]]. However these predictions date from before the recession of the early [[1980s]], and the consequent reduction in global consumption, the effect of which was to delay the date of any peak by several years. A new prediction by [[Goldman Sachs]] picks [[2007]] for oil and some time later for natural gas. Just as the 1971 U.S. peak in oil production was only clearly recognized after the fact, a peak in world production may be difficult to discern until production clearly drops off.
+
* Petro-cars, this is, only use petroleum and biofuels ([[biodiesel]] and [[biobutanol]]).
 +
* [[Hybrid vehicle]] and [[plug-in hybrid]]s, that use petroleum and other source, generally, electricity.
 +
* Petrofree car, that can not use petroleum, like [[electric car]]s, [[hydrogen vehicle]]s…
  
One signal is that 2005 saw a dramatic fall in announced new oil projects coming to production from [[2008]] onwards. Since it takes on average four to six years for a new project to start producing oil, in order to avoid the peak, these new projects would have to not only make up for the depletion of current fields, but increase total production annually to meet increasing demand.
+
==The future of petroleum production==
 +
===Hubbert peak theory===
 +
{{main|Hubbert peak theory}}
 +
The [[Hubbert peak theory]] (also known as [[peak oil]]) is a proposition which predicts that future world petroleum production must inevitably reach a peak and then decline at a similar rate to the rate of increase before the peak as these reserves are exhausted. It also suggests a method to calculate mathematically the timing of this peak, based on past production rates, past discovery rates, and proven oil reserves.
  
However, [http://www.wnd.com/news/article.asp?ARTICLE_ID=38645 new information] suggests that the world's oil supply may not be as near it's death toll as we thought. It seems that oil may actually be the result of a chemical reacion between the Earth's crust and mantle instead of liquified lifeforms. Several oil wells that had significantly reduced their production levels are actually being refilled with oil from below. If this trend holds true for more oil deposits, the future of oil may not be as discouraging as we thought.
+
Controversy surrounds the theory for numerous reasons. Past predictions regarding the timing of the global peak have failed, causing a number of observers to disregard the theory. Further, predictions regarding the timing of the peak are highly dependent on the past production and discovery data used in the calculation.
  
== Classification ==
+
Proponents of [[peak oil]] theory also refer as an example of their theory, that when any given oil well produces oil in similar volumes to the amount of water used to obtain the oil, it tends to produce less oil afterwards, leading to the relatively quick exhaustion and/or commercial inviability of the well in question.
  
The [[oil industry]] classifies "crude" by the location of its origin (e.g., "West Texas Intermediate, WTI" or "Brent") and often by its relative weight ([[API gravity]]) or [[viscosity]] ("light", "intermediate" or "heavy"); refiners may also refer to it as "sweet", which means it contains relatively little [[sulfur]], or as "sour", which means it contains substantial amounts of [[sulfur]] and requires more refining in order to meet current product specifications.
+
The issue can be considered from the point of view of individual regions or of the world as a whole. [[M. King Hubbert|Hubbert]]'s prediction for when US oil production would peak turned out to be correct, and after this occurred in 1971 - causing the US to lose its excess production capacity - [[OPEC]] was finally able to manipulate oil prices, which led to the [[1973 oil crisis]]. Since then, most other countries have also peaked: the United Kingdom's [[North Sea oil|North Sea]], for example in the late 1990s. China has confirmed that two of its largest producing regions are in decline, and Mexico's national oil company, [[Pemex]], has announced that [[Cantarell Field]], one of the world's largest offshore fields, was expected to peak in 2006, and then decline 14 percent per annum.
  
The world reference [[barrel (unit)|barrel]]s are:
+
It is difficult to predict the [[peak oil|oil peak]] in any given region (due to the lack of transparency in [[accounting]] of global oil reserves<ref>[http://www.iags.org/n0331043.htm New study raises doubts about Saudi oil reserves].(March 31, 2004) Institute for the Analysis of Global Security (IAGS). Retrieved August 25, 2007.</ref>) Based on available production data, proponents have previously (and incorrectly) predicted the peak for the world to be in years 1989, 1995, or 1995-2000. Some of these predictions date from before the recession of the early 1980s, and the consequent reduction in global consumption, the effect of which was to delay the date of any peak by several years. A new prediction by [[Goldman Sachs]] picks 2007 for oil and some time later for natural gas. Just as the 1971 U.S. peak in oil production was only clearly recognized after the fact, a peak in world production will be difficult to discern until production clearly drops off.
* '''Brent Blend''', comprising 15 oils from fields in the [[Brent oilfield|Brent]] and [[Ninian]] systems in the [[East Shetland Basin]] of the [[North Sea]]. The oil is landed at [[Sullom Voe]] terminal in the [[Shetlands]]. Oil production from Europe, Africa and Middle Eastern oil flowing West tends to be priced off the price of this oil, which forms a [[benchmark]]. See also [[Brent crude]].
 
* [[West Texas Intermediate]] (WTI) for North American oil.
 
* Dubai used as benchmark for the [[Asia]]-[[Pacific]] region for Middle East Oil
 
* Tapis (from [[Malaysia]], used as a reference for light Far East oil)
 
* Minas (from [[Indonesia]], used as a reference for heavy Far East oil)
 
* The [[OPEC]] Basket consisting of
 
** Arab Light [[Saudi Arabia]]
 
** Bonny Light [[Nigeria]]
 
** Fateh [[Dubai]]
 
** Isthmus  [[Mexico]] (non-OPEC)
 
** Minas [[Indonesia]]
 
** Saharan Blend [[Algeria]]
 
** Tia Juana Light [[Venezuela]]
 
  
OPEC attempts to keep the price of the Opec Basket between upper and lower limits, by increasing and decreasing production.  This makes the measure important for market analysts. The OPEC Basket, including a mix of light and heavy crudes, is heavier than both Brent and WTI.
+
Many proponents of the [[Hubbert peak theory]] expound the belief that the production peak is imminent, for various reasons. The year 2005 saw a dramatic fall in announced new oil projects coming to production from 2008 onwards - in order to avoid the peak, these new projects would have to not only make up for the depletion of current fields, but increase total production annually to meet increasing demand.
  
See also [http://tonto.eia.doe.gov/ask/crude_types1.html]
+
The year 2005 also saw substantial increases in oil prices stemming from a number of circumstances, including war and political instability. Oil prices rose to new highs. Analysts such as Kenneth Deffeyes <ref>Kenneth Deffeyes. ''Beyond Oil: The View from Hubbert's Peak.'' New York, NY: Hill and Wang, 2005. ISBN 080902957X. </ref> argue that these price increases indicate a general lack of spare capacity, and the price fluctuations can be interpreted as a sign that [[peak oil]] is imminent.
  
==Pricing==
+
==International market==
[[Image:Gas-hike.jpg|thumb|350px|Overnight gas price hike shown at a Chicago area BP-Amoco station (background). The Shell station (foreground) has not yet posted the 12 cent price hike.]]
+
[[Image:OilConsumptionpercapita.png|thumb|center|550px|Oil consumption per capita (darker colors represent more consumption).]]
References to the oil price are usually either references to the [[spot]] price of either WTI/Light Crude as traded on [[New York Mercantile Exchange]] (NYMEX) for delivery in [[Cushing, Oklahoma]]; or the price of Brent as traded on the [[International Petroleum Exchange]] (IPE)  for delivery at [[Sullom Voe]]. The price of a barrel of oil is highly dependent on both its grade (which is determined by factors such as its specific gravity or [[API]] and its sulphur content) and location. The vast majority of oil will not be traded on an exchange but on a [[over-the-counter (finance)|over-the-counter]] basis, typically with reference to a marker crude oil grade that is typically quoted via the pricing agency [[Platts]]. For example in Europe a particular grade of oil, say Fulmar, might be sold at a price of "Brent plus US$0.25/barrel".or as an [[intra-company transaction]]. IPE claim that 65% of traded oil is priced off their Brent benchmarks. Other important benchmarks include Dubai, Tapis, and the OPEC basket. The [[Energy Information Administration]] (EIA) uses the Imported Refiner Acquisition Cost, the weighted average cost of all oil imported into the US as their "world oil price".
 
  
It is often claimed that OPEC sets the oil price and the true cost of a barrel of oil is around $2, which is equivalent to the cost of extraction of a barrel in the Middle East. These estimates of costs ignore the cost of finding and developing oil reserves. Furthermore the important cost as far as price is concerned, is not the price of the cheapest barrel but the cost of producing the marginal barrel. By limiting production OPEC has caused more expensive areas of production such as the North Sea to be developed before the Middle East has been exhausted. OPEC's power is also often overstated. Investing in spare capacity is expensive and the low oil price environment in the late 90s led to cutbacks in investment. This has meant during the oil price rally seen between 2003-2005, OPEC's spare capacity has not been sufficient to stabilise prices.
+
===Petroleum efficiency among countries===
  
[[Image:Oil Prices Medium Term.png|thumb|300px|Oil prices, 1994-2005 (not adjusted for inflation).]]
+
There are two main ways to measure the petroleum efficiency of countries:  by population or by [[GDP]] ([[gross domestic product]]). This metric is important in the global debate over oil consumption/energy consumption/climate change because it takes social and economic considerations into account when scoring countries on their oil consumption/energy consumption/climate change goals. Nations such as China and India with large populations tend to promote the use of population based metrics, while nations with large economies such as the United States would tend to promote the GDP based metric.
 +
{{col-begin}}
 +
{{col-break}}
 +
{|  style="text-align: right;" border="1" cellspacing="0" class="wikitable"
 +
! Selected Nations
 +
! Oil Efficiency (US dollar/barrel/day)
 +
|-
 +
|{{rh}}|[[Switzerland]]
 +
|3.75
 +
|-
 +
|{{rh}}|[[United Kingdom]]
 +
|3.34
 +
|-
 +
|{{rh}}|[[Norway]]
 +
|3.31
 +
|-
 +
|{{rh}}|[[Austria]]
 +
|2.96
 +
|-
 +
|{{rh}}|[[France]]
 +
|2.65
 +
|-
 +
|{{rh}}|[[Germany]]
 +
|2.89
 +
|-
 +
|{{rh}}|[[Sweden]]
 +
|2.71
 +
|-
 +
|{{rh}}|[[Italy]]
 +
|2.57
 +
|-
 +
|{{rh}}|[[European Union]]
 +
|2.52
 +
|-
 +
|{{rh}}|[[DRC]]
 +
|2.4
 +
|-
 +
|{{rh}}|[[Japan]]
 +
|2.34
 +
|-
 +
|{{rh}}|[[Australia]]
 +
|2.21
 +
|-
 +
|{{rh}}|[[Spain]]
 +
|1.96
 +
|-
 +
|{{rh}}|[[Bangladesh]]
 +
|1.93
 +
|-
 +
|{{rh}}|[[Poland]]
 +
|1.87
 +
|-
 +
|{{rh}}|[[United States]]
 +
|1.65
 +
|-
 +
|{{rh}}|[[Belgium]]
 +
|1.59
 +
|-
 +
|{{rh}}|[[World]]
 +
|'''1.47'''
 +
|-
 +
|{{rh}}|[[Turkey]]
 +
|1.39
 +
|-
 +
|{{rh}}|[[Canada]]
 +
|1.35
 +
|-
 +
|{{rh}}|[[Mexico]]
 +
|1.07
 +
|-
 +
|{{rh}}|[[Ethiopia]]
 +
|1.04
 +
|-
 +
|{{rh}}|[[South Korea]]
 +
|1.00
 +
|-
 +
|{{rh}}|[[Philippines]]
 +
|1.00
 +
|-
 +
|{{rh}}|[[Brazil]]
 +
|0.99
 +
|-
 +
|{{rh}}|[[Taiwan]]
 +
|0.98
 +
|-
 +
|{{rh}}|[[China]]
 +
|0.94
 +
|-
 +
|{{rh}}|[[Nigeria]]
 +
|0.94
 +
|-
 +
|{{rh}}|[[Pakistan]]
 +
|0.93
 +
|-
 +
|{{rh}}|[[Myanmar]]
 +
|0.89
 +
|-
 +
|{{rh}}|[[India]]
 +
|0.86
 +
|-
 +
|{{rh}}|[[Russia]]
 +
|0.84
 +
|-
 +
|{{rh}}|[[Indonesia]]
 +
|0.71
 +
|-
 +
|{{rh}}|[[Vietnam]]
 +
|0.61
 +
|-
 +
|{{rh}}|[[Thailand]]
 +
|0.53
 +
|-
 +
|{{rh}}|[[Saudi Arabia]]
 +
|0.46
 +
|-
 +
|{{rh}}|[[Egypt]]
 +
|0.41
 +
|-
 +
|{{rh}}|[[Singapore]]
 +
|0.40
 +
|-
 +
|{{rh}}|[[Iran]]
 +
|0.35
 +
|-
 +
|}
 +
{{col-break}}
 +
{| style="text-align: right;" border="1" cellspacing="0" class="wikitable"
 +
! Selected Nations
 +
! Oil Efficiency (barrel/person/year)
 +
|-
 +
|{{rh}}|[[DRC]]
 +
|0.13
 +
|-
 +
|{{rh}}|[[Ethiopia]]
 +
|0.37
 +
|-
 +
|{{rh}}|[[Bangladesh]]
 +
|0.57
 +
|-
 +
|{{rh}}|[[Myanmar]]
 +
|0.73
 +
|-
 +
|{{rh}}|[[Pakistan]]
 +
|1.95
 +
|-
 +
|{{rh}}|[[Nigeria]]
 +
|2.17
 +
|-
 +
|{{rh}}|[[India]]
 +
|2.18
 +
|-
 +
|{{rh}}|[[Vietnam]]
 +
|2.70
 +
|-
 +
|{{rh}}|[[Philippines]]
 +
|3.77
 +
|-
 +
|{{rh}}|[[Indonesia]]
 +
|4.63
 +
|-
 +
|{{rh}}|[[China]]
 +
|4.96
 +
|-
 +
|{{rh}}|[[Egypt]]
 +
|7.48
 +
|-
 +
|{{rh}}|[[Turkey]]
 +
|9.85
 +
|-
 +
|{{rh}}|[[Brazil]]
 +
|11.67
 +
|-
 +
|{{rh}}|[[Poland]]
 +
|11.67
 +
|-
 +
|{{rh}}|[[World]]
 +
|'''12.55'''
 +
|-
 +
|{{rh}}|[[Thailand]]
 +
|13.86
 +
|-
 +
|{{rh}}|[[Russia]]
 +
|17.66
 +
|-
 +
|{{rh}}|[[Mexico]]
 +
|18.07
 +
|-
 +
|{{rh}}|[[Iran]]
 +
|21.56
 +
|-
 +
|{{rh}}|[[European Union]]
 +
|29.70
 +
|-
 +
|{{rh}}|[[United Kingdom]]  
 +
|30.18
 +
|-
 +
|{{rh}}|[[Germany]]
 +
|32.31
 +
|-
 +
|{{rh}}|[[France]]
 +
|32.43
 +
|-
 +
|{{rh}}|[[Italy]]
 +
|32.43
 +
|-
 +
|{{rh}}|[[Austria]]
 +
|34.01
 +
|-
 +
|{{rh}}|[[Spain]]
 +
|35.18
 +
|-
 +
|{{rh}}|[[Switzerland]]
 +
|34.64
 +
|-
 +
|{{rh}}|[[Sweden]]
 +
|34.68
 +
|-
 +
|{{rh}}|[[Taiwan]]
 +
|41.68
 +
|-
 +
|{{rh}}|[[Japan]]
 +
|42.01
 +
|-
 +
|{{rh}}|[[Australia]]
 +
|42.22
 +
|-
 +
|{{rh}}|[[South Korea]]
 +
|43.84
 +
|-
 +
|{{rh}}|[[Norway]]
 +
|52.06
 +
|-
 +
|{{rh}}|[[Belgium]]
 +
|61.52
 +
|-
 +
|{{rh}}|[[United States]]
 +
|68.81
 +
|-
 +
|{{rh}}|[[Canada]]
 +
|69.85
 +
|-
 +
|{{rh}}|[[Saudi Arabia]]
 +
|75.08
 +
|-
 +
|{{rh}}|[[Singapore]]
 +
|178.45
 +
|-
 +
|}
  
Oil demand is highly dependent on global macroeconomic conditions, so this is also an important determinant of price. Some economists claim that high oil prices have a large negative impact on the global growth. This means that the relationship between the oil price and global growth is not particularly stable although a high oil price is often thought of as being a late cycle phenomenon.
+
(Note: The figure for Singapore is skewed because of its small<br/>population compared with its large oil refining capacity.<br/>Most of this oil is sent to other countries.)
 +
{{col-end}}
  
A recent low point was reached in January [[1999]], after increased oil production from Iraq coincided with the Asian financial crisis, which reduced demand. The prices then rapidly increased, more than doubling by September [[2000]], then fell until the end of [[2001]] before steadily increasing, reaching US $40 to US $50 per barrel by September [[2004]]. [http://futures.tradingcharts.com/chart/CO/M]
+
===Top petroleum-producing countries===
In October 2004, light crude [[futures contract]]s on the NYMEX for November delivery exceeded US $53 per barrel and for December delivery exceeded US $55 per barrel. Crude oil prices surged to a record high above $60 a barrel in June 2005, sustaining a rally built on strong demand for gasoline and diesel and on concerns about refiners' ability to keep up. This trend continued into early [[August]] [[2005]], as NYMEX crude oil futures contracts surged past the $65 mark as consumers kept up the demand for gasoline despite its high price. (see [[Oil price increases of 2004 and 2005]]).)
+
Source: [http://www.eia.doe.gov/emeu/cabs/topworldtables1_2.html Energy Statistics from the U.S. Government].
  
The [[New York Mercantile Exchange]] (NYMEX) trades crude oil (including futures contracts) and provides the basis of US crude oil pricing via WTI (West Texas Intermediate). Other exchanges also trade crude oil futures, eg the [[International Petroleum Exchange]] (IPE) in London trades contracts in Brent crude.  
+
For oil reserves by country, see [[Oil reserves#Oil reserves by country|Oil reserves by country]].
  
[[Image:Oil Prices Short Term.png|thumb|300px|Recent oil prices, 2003-2005]]
+
[[Image:Oil producing countries map.png|thumb|300px|Oil producing [[List of oil-producing states|countries]]]]
  
See also [http://www.wtrg.com/prices.htm History and Analysis of Crude Oil Prices]
+
In order of amount produced in 2004 in MM[[Barrel (unit)|bbl]]/[[Day|d]] & [[Mega|M]][[Litre|L]]/d:
 +
{|  style="text-align: right;" border="1" cellspacing="0" class="wikitable"
 +
!#
 +
!Producing Nation for 2004
 +
!(×10<sup>6</sup>bbl/d)
 +
!(×10<sup>3</sup>[[Cubic metre|m³]]/d)
 +
|-
 +
|1
 +
|{{rh}}|[[Saudi Arabia]] ([[OPEC]])
 +
|10.37
 +
|1,649
 +
|-
 +
|2
 +
|{{rh}}|[[Russia]]
 +
|9.27
 +
|1,474
 +
|-
 +
|3
 +
|{{rh}}|[[United States]] <sup>1</sup>
 +
|8.69
 +
|1,382
 +
|-
 +
|4
 +
|{{rh}}|[[Iran]] (OPEC)
 +
|4.09
 +
|650
 +
|-
 +
|5
 +
|{{rh}}|[[Mexico]] <sup>1</sup>
 +
|3.83
 +
|609
 +
|-
 +
|6
 +
|{{rh}}|[[China]] <sup>1</sup>
 +
|3.62
 +
|576
 +
|-
 +
|7
 +
|{{rh}}|[[Norway]] <sup>1</sup>
 +
|3.18
 +
|506
 +
|-
 +
|8
 +
|{{rh}}|[[Canada]] <sup>1,3</sup>
 +
|3.14
 +
|499
 +
|-
 +
|9
 +
|{{rh}}|[[Venezuela]] (OPEC) <sup>1</sup>
 +
|2.86
 +
|455
 +
|-
 +
|10
 +
|{{rh}}|[[United Arab Emirates]] (OPEC)
 +
|2.76
 +
|439
 +
|-
 +
|11
 +
|{{rh}}|[[Kuwait]] (OPEC)
 +
|2.51
 +
|399
 +
|-
 +
|12
 +
|{{rh}}|[[Nigeria]] (OPEC)
 +
|2.51
 +
|399
 +
|-
 +
|13
 +
|{{rh}}|[[United Kingdom]] <sup>1</sup>
 +
|2.08
 +
|331
 +
|-
 +
|14
 +
|{{rh}}|[[Iraq]] (OPEC) <sup>2</sup>
 +
|2.03
 +
|323
 +
|}
 +
<small><sup>1</sup> [[Oil reserves#Countries that have already passed their production peak|peak production of conventional oil already passed in this state]]</small>
  
==Top petroleum-producing countries==
+
<small><sup>2</sup> Though still a member, Iraq has not been included in production figures since 1998</small>
Source: [http://www.eia.doe.gov/emeu/cabs/topworldtables1_2.html Energy Statistics from the U.S. Government]
 
  
(Ordered by amount (''barrels per day'') produced in 2004):
+
<small><sup>3</sup> Canada has the world's second largest oil reserves when tar sands are included, and is the leading source of U.S. imports, averaging 1.7 MMbbl/d in April 2006 [http://tonto.eia.doe.gov/dnav/pet/pet_move_impcus_a2_nus_epc0_im0_mbblpd_m.htm].</small>
*[[Saudi Arabia]] ([[OPEC]])
 
*[[Russia]]
 
*[[United States]]
 
*[[Iran]] (OPEC)
 
*[[Mexico]]
 
*[[China]]
 
*[[Norway]]
 
*[[Canada]]
 
*[[Venezuela]] (OPEC)
 
*[[United Arab Emirates]] (OPEC)
 
*[[Kuwait]] (OPEC)
 
*[[Nigeria]] (OPEC)
 
*[[United Kingdom]]
 
*[[Iraq]]
 
  
[[Image:World petroleum systems.png|thumb|300px|Non-USA petroleum areas (blue regions).]]
+
===Top petroleum-exporting countries===
(Ordered by amount ''exported'' in 2003):
+
[[Image:Oil exports.PNG|thumb|300px|Oil exports by country]]
*Saudi Arabia (OPEC)
+
In order of amount ''exported'' in 2003:
*Russia
+
#Saudi Arabia (OPEC)
*Norway
+
#Russia
*Iran (OPEC)
+
#Norway <sup>1</sup>
*United Arab Emirates (OPEC)
+
#Iran (OPEC)
*Venezuela (OPEC)
+
#United Arab Emirates (OPEC)
*Kuwait (OPEC)
+
#Venezuela (OPEC) <sup>1</sup>
*Nigeria (OPEC)
+
#Kuwait (OPEC)
*Mexico
+
#Nigeria (OPEC)
*Algeria (OPEC)
+
#Mexico <sup>1</sup>
*Libya (OPEC)
+
#Algeria (OPEC)
 +
#Libya (OPEC) <sup>1</sup>
 +
<small><sup>1</sup> [[Oil reserves#Countries that have already passed their production peak|peak production already passed in this state]]</small>
  
Note that the USA consumes almost all of its own production.
+
Note that the USA consumes almost all of its own production, while the UK has recently become a net-importer rather than net-exporter.  
  
Total world production/consumption (as of [[2005]]) is approximately 84 million barrels per day.
+
Total world production/consumption (as of 2005) is approximately 84 million barrels per day.
  
 
See also: [[Organization of Petroleum Exporting Countries]].
 
See also: [[Organization of Petroleum Exporting Countries]].
  
==Related topics==
+
===Top petroleum-consuming countries===
* [[Abiogenic petroleum origin]]
+
{| style="text-align: right;" border="1" cellspacing="0" class="wikitable"
* [[List of oil fields]]
+
!#
* [[List of oil-producing states]]
+
!Consuming Nation
* [[List of oil-consuming states]]
+
!(bbl/day)
* [[List of petroleum companies]]
+
!(m³/day)
* [[Energy crisis]]: [[1973 energy crisis]], [[1979 energy crisis]]
+
|-
* [[Fossil fuel]]
+
|1
* [[Greenhouse gas]]es
+
|{{rh}}|United States
* [[History of the Petroleum Industry]]
+
|20,030,000
* [[Hubbert peak]] (aka peak oil)
+
|3,184,516
* [[Future energy development]]
+
|-
* [[1990 spike in the price of oil]]
+
|2
* [[Non-conventional oil]]
+
|{{rh}}|China
* [[Oil imperialism]]
+
|6,391,000
* [[Oil price increases of 2004 and 2005]]
+
|1,016,088
* [[Oil refinery]]
+
|-
* [[Oil supplies]]
+
|3
* [[Oil well]]
+
|{{rh}}|Japan
* [[Olduvai theory]] (not strictly about oil, but it basically assumes that oil and gas are the only significant energy sources)
+
|5,578,000
* [[Petroleum disaster]]s
+
|886,831
* [[Petroleum geology]]
+
|-
* [[Petroleum politics]]
+
|4
* [[Renewable energy]]
+
|{{rh}}|Russia
* [[Thermal depolymerization]]
+
|2,800,000
* [[Thomas Gold]]
+
|445,164
* [[Irish Sea]]
+
|-
 +
|5
 +
|{{rh}}|Germany
 +
|2,677,000
 +
|425,609
 +
|-
 +
|6
 +
|{{rh}}|India
 +
|2,320,000
 +
|368,851
 +
|-
 +
|7
 +
|{{rh}}|Canada
 +
|2,300,000
 +
|365,671
 +
|-
 +
|8
 +
|{{rh}}|South Korea
 +
|2,061,000
 +
|327,673
 +
|-
 +
|9
 +
|{{rh}}|France
 +
|2,060,000
 +
|327,514
 +
|-
 +
|10
 +
|{{rh}}|Italy
 +
|1,874,000
 +
|297,942
 +
|-
 +
|11
 +
|{{rh}}|Saudi Arabia
 +
|1,775,000
 +
|282,202
 +
|-
 +
|12
 +
|{{rh}}|Mexico
 +
|1,752,000
 +
|278,546
 +
|-
 +
|13
 +
|{{rh}}|United Kingdom
 +
|1,722,000
 +
|273,776
 +
|-
 +
|14
 +
|{{rh}}|Brazil
 +
|1,610,000
 +
|255,970
 +
|}
 +
Source: [https://www.cia.gov/library/publications/the-world-factbook/rankorder/2174rank.html CIA World Factbook]
  
==External links==
+
===Top petroleum-importing countries===
 +
[[Image:Oil imports.PNG|thumb|300px|Oil imports by country]]
 +
{| style="text-align: right;" border="1" cellspacing="0" class="wikitable"
 +
!#
 +
!Importing Nation
 +
!(bbl/day)
 +
!(m³/day)
 +
|-
 +
|1
 +
|{{rh}}|United States
 +
|13,150,000
 +
|2,790,683
 +
|-
 +
|2
 +
|{{rh}}|Japan
 +
|5,449,000
 +
|866,322
 +
|-
 +
|3
 +
|{{rh}}|China
 +
|3,226,000
 +
|512,893
 +
|-
 +
|4
 +
|{{rh}}|Netherlands
 +
|2,284,000
 +
|363,127
 +
|-
 +
|5
 +
|{{rh}}|France
 +
|2,281,000
 +
|362,650
 +
|-
 +
|6
 +
|{{rh}}|South Korea
 +
|2,263,000
 +
|359,788
 +
|-
 +
|7
 +
|{{rh}}|Italy
 +
|2,158,000
 +
|343,095
 +
|-
 +
|8
 +
|{{rh}}|Germany
 +
|2,135,000
 +
|339,438
 +
|-
 +
|9
 +
|{{rh}}|India
 +
|2,090,000
 +
|332,283
 +
|-
 +
|10
 +
|{{rh}}|Spain
 +
|1,582,000
 +
|251,518
 +
|-
 +
|11
 +
|{{rh}}|United Kingdom
 +
|1,084,000
 +
|172,342
 +
|-
 +
|12
 +
|{{rh}}|Belgium
 +
|1,042,000
 +
|165,665
 +
|-
 +
|13
 +
|{{rh}}|Canada
 +
|963,000
 +
|153,105
 +
|-
 +
|14
 +
|{{rh}}|Turkey
 +
|616,500
 +
|98,016
 +
|}
 +
Source: [https://www.cia.gov/library/publications/the-world-factbook/rankorder/2175rank.html CIA World Factbook]
  
* [http://www.api.org/ American Petroleum Institute] - A site run by the American Petroleum Institute, the trade association of the US oil industry.
+
===Top petroleum non-producing and consuming countries===
* [http://www.eia.doe.gov/oil_gas/petroleum/info_glance/petroleum.html US Energy Information Administration] - Part of the informative website of the US Government's Energy Information Administration.
+
{| style="text-align: right;" border="1" cellspacing="0" class="wikitable"
* [http://www.geo.uw.edu.pl/BOBRKA/DATY/daty.htm Major dates of the Polish petroleum industry]
+
!#
*[http://www.gasresources.net/DisposalBioClaims.htm Dismissal of the Claims of a Biological Connection for Natural Petroleum.]
+
!Consuming Nation
*[http://www.aapg.org/explorer/2002/11nov/abiogenic.cfm Abiogenic Gas Debate 11:2002 (EXPLORER)]
+
!(bbl/day)
*[http://www.gasresources.net/Introduction.htm An introduction to the modern petroleum science, and to the Russian-Ukrainian theory of deep, abiotic petroleum origins.]
+
!(m³/day)
*[http://www.spe.org/elibinfo/eLibrary_Papers/spe/1982/82UGR/00010836/00010836.htm Unconventional Ideas About Unconventional Gas (Society of Petroleum Engineers)]
+
|-
*[http://www.bp.com/genericsection.do?categoryId=92&contentId=7005893 BP Statistical Revue of World Energy ]
+
|1
* [http://www.nymex.com Nymex] - oil trading center of the US
+
|{{rh}}|Japan
* [http://www.bloomberg.com/energy/ Bloomberg Energy Prices] - current prices on world mercantile exchanges
+
|5,578,000
* [http://www.oilmarketer.co.uk/ Oil Marketer] - oil news and market information
+
|886,831
* [http://www.economist.com/surveys/displaystory.cfm?story_id=3884623 Oil in troubled waters] - Economist article on investor approaches to oil markets, supply, and future
+
|-
 +
|2
 +
|{{rh}}|Germany
 +
|2,677,000
 +
|425,609
 +
|-
 +
|3
 +
|{{rh}}|India
 +
|2,320,000
 +
|368,851
 +
|-
 +
|4
 +
|{{rh}}|South Korea
 +
|2,061,000
 +
|327,673
 +
|-
 +
|5
 +
|{{rh}}|France
 +
|2,060,000
 +
|327,514
 +
|-
 +
|6
 +
|{{rh}}|Italy
 +
|1,874,000
 +
|297,942
 +
|-
 +
|7
 +
|{{rh}}|Spain
 +
|1,537,000
 +
|244,363
 +
|-
 +
|8
 +
|{{rh}}|Netherlands
 +
|946,700
 +
|150,513
 +
|}
 +
Source :  [https://www.cia.gov/library/publications/the-world-factbook/rankorder/2175rank.html CIA World Factbook]
  
===Articles===
+
==See also==
* [http://pr.caltech.edu/periodicals/CaltechNews/articles/v38/oil.html The End of the Age of Oil] - article adapted from a talk by Caltech vice provost and professor of physics [[David Goodstein]]
 
* [http://www.publicintegrity.org/oil/ The Politics of Oil] - A report on the oil industry's influence of lawmakers and public policy by the ''[[Center for Public Integrity]]''.
 
* [http://news.bbc.co.uk/2/hi/business/3953907.stm BBC: Stability fears rise as oil reliance grows]
 
* [http://www.washingtonpost.com/wp-dyn/content/article/2005/06/09/AR2005060900148_pf.html Top Saudi Says Kingdom Has Plenty of Oil] "261 billion barrels in reserve..."
 
* [http://business.timesonline.co.uk/article/0,,16849-1733893,00.html Lee Raymond of Exxon Mobile believes oil supplies will rise]
 
* [http://www.arabnews.com/?page=6&section=0&article=44011&d=29&m=4&y=2004  Known Saudi Arabian Oil Reserves Tripled]
 
* [http://www2.eluniversal.com.mx/pls/impreso/noticia.html?id_nota=6110&tabla=miami Pemex's oil estimates double:] Mexican Oil company's estimate of reserves doubled.
 
*''[http://www.gasresources.net/DisposalBioClaims.htm Dismissal of the Claims of a Biological Connection for Natural Petroleum] {{ref|Kenney2001}}''
 
*''[http://www.aapg.org/explorer/2002/11nov/abiogenic.cfm Abiogenic Gas Debate 11:2002 (EXPLORER)]''
 
  
===Data===
+
* [[Fossil fuel]]
*[http://www.eia.doe.gov/emeu/international/petroleu.html Department of Energy EIA - World supply and consumption]
+
* [[Global warming]]
* [http://www.eia.doe.gov/oil_gas/petroleum/info_glance/prices.html US petroleum prices]
+
* [[Greenhouse gas]]es
 +
* [[Mineral oil]]
 +
* [[Natural gas]]
  
 +
== Notes ==
 +
<references />
  
===References===
+
==References==
# {{note|Kenney2002}} {{Journal reference | Author=Kenney, J., Kutcherov, V., Bendeliani, N. and Alekseev, V. | Title= The evolution of multicomponent systems at high pressures: VI. The thermodynamic stability of the hydrogen–carbon system: The genesis of hydrocarbons and the origin of petroleum | Journal=Proceedings of the National Academy of Sciences of the U.S.A. | Volume=99 | Year=2002 | Pages=10976-10981}} [http://www.pnas.org/cgi/content/full/99/17/10976 Article link]
 
# {{note|Kenney2001}} {{Journal reference | Author=Kenney, J., Shnyukov, A., Krayushkin, V., Karpov, I., Kutcherov, V. and Plotnikova, I. | Title= Dismissal of the claims of a biological connection for natural petroleum | Journal=Energia | Volume=22 | Issue=3 | Year=2001 | Pages=26-34}}
 
  
==Books about the petroleum industry==
+
* Conaway, Charles F. 1999. ''The Petroleum Industry: A Nontechnical Guide.'' Tulsa, OK: PennWell. ISBN 0878147772
* {{Book reference | Author=James Howard Kunstler | Title=The Long Emergency: Surviving the Converging Catastrophes of the Twenty-first Century | Publisher=Atlantic Monthly Press | Year=2005 | ID=0871138883}}
+
* Hyne, Norman J. 2001. ''Nontechnical Guide to Petroleum Geology, Exploration, Drilling, and Production,'' 2nd ed. Tulsa, OK: PennWell. ISBN 087814823X
* {{Book reference | Author= C.J. Campbell| Title=The Coming Oil Crisis | Publisher= | Year=2004 | ID=}}
+
* McCain, William D. 1989. ''The Properties of Petroleum Fluids.'' Tulsa, OK: PennWell. ISBN 0878143351
* {{Book reference | Author= | Title=Out of Gas: The End of the Age of Oil | Publisher= | Year=2004 | ID=}}
+
* Meyers, Robert A. 2004. ''Handbook of Petroleum Refining Processes,'' 3rd ed. McGraw-Hill Handbooks. New York: McGraw-Hill. ISBN 0071391096
* {{Book reference | Author=Amory B. Lovins | Title=Winning the Oil Endgame | Publisher=Rocky Mountain Institute | Year=2004 | ID=1881071103}}
 
* {{Book reference | Author= | Title=Hubbert's Peak : The Impending World Oil Shortage | Publisher= | Year=2003 | ID=}}
 
* {{Book reference | Author=Vaclav Smil | Title=Energy at the Crossroads : Global Perspectives and Uncertainties | Publisher=The MIT Press | Year=2003 | ID=0262194929}}
 
* {{Book reference | Author=Daniel Yergin | Title=The Prize: The Epic Quest for Oil, Money, and Power | Publisher=Simon & Schuster | Year=1991 | ID=0671502484}}
 
* {{Book reference | Author=Harold F. Williamson and Arnold R. Daum | Title=The American Petroleum Industry: Volume I, The Age of Illumination | Publisher=Northwestern University Press | Year=1959 | ID=}}
 
* {{Book reference | Author=Harold F. Williamson, Ralph L. Andreano, Arnold R. Daum, and Gilbert C. Klose | Title=The American Petroleum Industry: Volume II, The Age of Energy | Publisher=Northwestern University Press | Year=1963 | ID=}}
 
  
==Films about petroleum==
+
==External links==
 
+
All links retrieved April 17, 2015.
* {{imdb title|id=0299612|title=Burning of the Standard Oil Co.'s Tanks, Bayonne, N.J.}}
+
* [http://www.lloydminsterheavyoil.com OTS Heavy Oil Science Centre] (includes overview of all phases of the oil industry).
* {{imdb title|id=0363498|title=California Oil Wells in Operation }}
+
* [http://www.eia.doe.gov/oil_gas/petroleum/info_glance/petroleum.html US Energy Information Administration] - Part of the informative website of the US Government's Energy Information Administration.
* {{imdb title|id=0222879|title=Canada Strikes Oil: Leduc, Alberta 1947 }}
+
* [http://www.offshore-environment.com/discharges.html Waste discharges during the offshore oil and gas activity] - Environmental effects of oil extraction.
* {{imdb title|id=0446320|title=The End of Suburbia: Oil Depletion and the Collapse of the American Dream}}
+
* [http://www.api.org/ American Petroleum Institute] - the trade association of the US oil industry.
** http://www.endofsuburbia.com
+
*[http://www.atimes.com/atimes/Global_Economy/GE26Dj02.html The real problems with $50 oil], An analysis by Henry C.K. Liu in Asia Times Online, details the economic impact of high oil prices.
* {{imdb title|id=0063060|title=Hellfighters}}
+
* ONTA, Inc.[http://www.oilrocks.com Oil Rocks].
* {{imdb title|id=0386530|title=Incendio del pozo petrolero de Dos Bocas, Veracruz}}
+
* [http://www.bloomberg.com/energy/ Bloomberg Energy Prices] - current prices on world mercantile exchanges.  
* {{imdb title|id=0391235|title=La Industria del Petróleo}}
+
* [http://www.oilmarketer.co.uk/ Oil Marketer] - oil news and market information.
* {{imdb title|id=0172594|title=Industria petrolului }}
+
* [http://www.economist.com/surveys/displaystory.cfm?story_id=3884623 Oil in troubled waters] - ''The Economist'' article on investor approaches to oil markets, supply, and future.
* {{imdb title|id=0334042|title=Oil - From Fossil to Flame }}
+
* [http://www.globaloilwatch.com Global Oil Watch] - Real-time oil and gas news and resources.
* {{imdb title|id=0184795|title=Oil Fires, Their Prevention and Extinguishment}}
+
*[http://www.globalpetroleumclub.com Petroleum Club] Online Community for the Petroleum Industry.
* {{imdb title|id=0461695|title=Oil Storm }}
+
* [http://www.our-energy.com/oil_en.html Oil, petroleum: Development, production, consumption and reserves].
* {{imdb title|id=0224029|title=Roughnecks: The Story of Oil Drillers }}
+
* [http://www.miriresortcity.com/?q=earthoil Discovery of oil in South East Asia] - History of an oil town.
* {{imdb title|id=0348412|title=Wildcatter: The Story of Texas Oil }}
+
* Jorn Madslien [http://news.bbc.co.uk/2/hi/business/3953907.stm BBC News online: "Stability fears rise as oil reliance grows"].(October 26, 2004)
* {{imdb title|id=0104706|title=Lektionen in Finsternis }}
+
*[http://geology.about.com/od/petroleum/a/aa_petroleum.htm Petroleum in a Nutshell] - About.com:Geology.
 +
*J. F. Kenney [http://www.gasresources.net/Introduction.htm "An introduction to the modern petroleum science, and to the Russian-Ukrainian theory of deep, abiotic petroleum origins."] GasResources.net.
 +
*[http://www.eia.doe.gov/emeu/international/contents.html Department of Energy EIA - World supply and consumption].
 +
*[http://www.eia.doe.gov/pub/oil_gas/petroleum/data_publications/company_level_imports/current/import.html Department of Energy EIA - Crude Oil and Total Petroleum Imports to USA].
 +
*[http://tonto.eia.doe.gov/dnav/pet/hist/rbrted.htm European Brent prices] since 1987.
  
==Writers covering the petroleum industry==
 
*[[Colin Campbell (geologist)|Colin J. Campbell]]
 
*[[Jay Hanson]]
 
*[[Kenneth S. Deffeyes]]
 
*[[David Goodstein]]
 
*[[Daniel Yergin]]
 
*[[Thomas Gold]]
 
  
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Revision as of 19:01, 17 April 2015

"Crude oil" redirects here.
Pumpjack pumping an oil well near Lubbock, Texas

Petroleum (Latin Petroleum derived from Greek πέτρα (Latin petra) - rock + έλαιον (Latin oleum) - oil) or crude oil is a naturally occurring liquid found in formations in the Earth consisting of a complex mixture of hydrocarbons (mostly alkanes) of various lengths. The approximate length range is C5H12 to C18H38. Any shorter hydrocarbons are considered natural gas or natural gas liquids, while long-chain hydrocarbons are more viscous, and the longest chains are paraffin wax. In its naturally occurring form, it may contain other nonmetallic elements such as sulfur, oxygen, and nitrogen.[1] It is usually black or dark brown (although it may be yellowish or even greenish) but varies greatly in appearance, depending on its composition. Crude oil may also be found in semi-solid form mixed with sand, as in the Athabasca oil sands in Canada, where it may be referred to as crude bitumen.

Petroleum is used mostly, by volume, for producing fuel oil and gasoline (petrol), both important "primary energy" sources. In a typical barrel 84 percent (37 of 42 gallons) of the hydrocarbons present in petroleum is converted into energy-rich fuels (petroleum-based fuels), including gasoline, diesel, jet, heating, and other fuel oils, and liquefied petroleum gas.[2]

Due to its high energy density, easy transportability and relative abundance, it has become the world's most important source of energy since the mid-1950s. Petroleum is also the raw material for many chemical products, including solvents, fertilizers, pesticides, and plastics; the 16 percent not used for energy production is converted into these other materials.

Petroleum is found in porous rock formations in the upper strata of some areas of the Earth's crust. There is also petroleum in oil sands. Known reserves of petroleum are typically estimated at around 1.2 trillion barrels without oil sands [3], or 3.74 trillion barrels with oil sands[4] However, oil production from oil sands is currently severely limited. Consumption is currently around 84 million barrels per day, or 4.9 trillion liters per year. Because of reservoir engineering difficulties, recoverable oil reserves are significantly less than total oil-in-place. At current consumption levels, and assuming that oil will be consumed only from reservoirs, known reserves would be gone in about 32 years, around 2039, potentially leading to a global energy crisis. However, this ignores any new discoveries, changes in consumption, using oil sands, using synthetic petroleum, and other factors.

Ignacy Łukasiewicz - inventor of the refining of kerosene from crude oil.

Formation

Chemistry

Octane, a hydrocarbon found in petroleum, lines are single bonds, black spheres are carbon, white spheres are hydrogen

The chemical structure of petroleum is composed of hydrocarbon chains of different lengths. These different hydrocarbon chemicals are separated by distillation at an oil refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbons. The general formula for these alkanes is CnH2n+2. For example 2,2,4-trimethylpentane (isooctane), widely used in gasoline, has a chemical formula of C8H18 and it reacts with oxygen exothermically:[5]

Incomplete combustion of petroleum or gasoline results in emission of poisonous gases such as carbon monoxide and/or nitric oxide. For example:

Formation of petroleum occurs in a variety of mostly endothermic reactions in high temperature and/or pressure. For example, a kerogen may break down into hydrocarbons of different lengths.[6]

Biogenic theory

Most geologists view crude oil and natural gas as the product of compression and heating of ancient organic materials over geological time. According to this theory, oil is formed from the preserved remains of prehistoric zooplankton and algae which have been settled to the sea (or lake) bottom in large quantities under anoxic conditions. Terrestrial plants, on the other hand, tend to form coal. Over geological time this organic matter, mixed with mud, is buried under heavy layers of sediment. The resulting high levels of heat and pressure cause the organic matter to chemically change during diagenesis, first into a waxy material known as kerogen which is found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons in a process known as catagenesis. Because most hydrocarbons are lighter than rock or water, these sometimes migrate upward through adjacent rock layers until they become trapped beneath impermeable rocks, within porous rocks called reservoirs. Concentration of hydrocarbons in a trap forms an oil field, from which the liquid can be extracted by drilling and pumping. Geologists often refer to an "oil window" which is the temperature range that oil forms in—below the minimum temperature oil remains trapped in the form of kerogen, and above the maximum temperature the oil is converted to natural gas through the process of thermal cracking. Though this happens at different depths in different locations around the world, a 'typical' depth for the oil window might be 4–6 km. Note that even if oil is formed at extreme depths, it may be trapped at much shallower depths, even if it is not formed there (the Athabasca Oil Sands is one example). Three conditions must be present for oil reservoirs to form: first, a source rock rich in organic material buried deep enough for subterranean heat to cook it into oil; second, a porous and permeable reservoir rock for it to accumulate in; and last a cap rock (seal) that prevents it from escaping to the surface.

The vast majority of oil that has been produced by the earth has long ago escaped to the surface and been biodegraded by oil-eating bacteria. Oil companies are looking for the small fraction that has been trapped by this rare combination of circumstances. Oil sands are reservoirs of partially biodegraded oil still in the process of escaping, but contain so much migrating oil that, although most of it has escaped, vast amounts are still present - more than can be found in conventional oil reservoirs. On the other hand, oil shales are source rocks that have never been buried deep enough to convert their trapped kerogen into oil.

The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where kerogen is broken down to oil and natural gas by a set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions. The first set was originally patented in 1694 under British Crown Patent No. 330 covering,

"a way to extract and make great quantityes of pitch, tarr, and oyle out of a sort of stone."

The latter set is regularly used in petrochemical plants and oil refineries.

Abiogenic theory

The idea of abiogenic petroleum origin was championed in the Western world by astronomer Thomas Gold based on thoughts from Russia, mainly on studies of Nikolai Kudryavtsev. The idea proposes that hydrocarbons of purely geological origin exist in the planet. Hydrocarbons are less dense than aqueous pore fluids, and are proposed to migrate upward through deep fracture networks. Thermophilic, rock-dwelling microbial life-forms are proposed to be in part responsible for the biomarkers found in petroleum.

This theory is a minority opinion, especially amongst geologists; no oil companies are currently known to explore for oil based on this theory.

Classification

The oil industry classifies "crude" by the location of its origin (e.g., "West Texas Intermediate, WTI" or "Brent") and often by its relative weight or viscosity ("light," "intermediate" or "heavy"); refiners may also refer to it as "sweet," which means it contains relatively little sulfur, or as "sour," which means it contains substantial amounts of sulfur and requires more refining in order to meet current product specifications. Each crude oil has unique molecular characteristics which are understood by the use of crude oil assay analysis in petroleum laboratories.

Barrels from an area in which the crude oil's molecular characteristics have been determined and the oil has been classified are used as pricing references throughout the world. These references are known as Crude oil benchmarks:

  • Brent Crude, comprising 15 oils from fields in the Brent and Ninian systems in the East Shetland Basin of the North Sea. The oil is landed at Sullom Voe terminal in the Shetlands. Oil production from Europe, Africa and Middle Eastern oil flowing West tends to be priced off the price of this oil, which forms a benchmark.
  • West Texas Intermediate (WTI) for North American oil.
  • Dubai, used as benchmark for Middle East oil flowing to the Asia-Pacific region.
  • Tapis (from Malaysia, used as a reference for light Far East oil)
  • Minas (from Indonesia, used as a reference for heavy Far East oil)
  • The OPEC Reference Basket, a weighted average of oil blends from various OPEC (The Organization of the Petroleum Exporting Countries) countries.

Means of production

Extraction

The most common method of obtaining petroleum is extracting it from oil wells found in oil fields. After the well has been located, various methods are used to recover the petroleum. Primary recovery methods are used to extract oil that is brought to the surface by underground pressure, and can generally recover about 20 percent of the oil present. After the oil pressure has depleted to the point that the oil is no longer brought to the surface, secondary recovery methods draw another 5 to 10 percent of the oil in the well to the surface. Finally, when secondary oil recovery methods are no longer viable, tertiary recovery methods reduce the viscosity of the oil in order to bring more to the surface.

Alternative methods

During the last oil price peak, other alternatives to producing oil gained importance. The best known such methods involve extracting oil from sources such as oil shale or tar sands. These resources are known to exist in large quantities; however, extracting the oil at low cost without negatively impacting the environment remains a challenge.

It is also possible to transform natural gas or coal into oil (or, more precisely, the various hydrocarbons found in oil). The best-known such method is the Fischer-Tropsch process. It was a concept pioneered in Nazi Germany when imports of petroleum were restricted due to war and Germany found a method to extract oil from coal. It was known as Ersatz ("substitute" in German), and accounted for nearly half the total oil used in WWII by Germany. However, the process was used only as a last resort as naturally occurring oil was much cheaper. As crude oil prices increase, the cost of coal to oil conversion becomes comparatively cheaper. The method involves converting high ash coal into synthetic oil in a multi-stage process. Ideally, a ton of coal produces nearly 200 liters (1.25 bbl, 52 US gallons) of crude, with by-products ranging from tar to rare chemicals.

Currently, two companies have commercialized their Fischer-Tropsch technology. Shell in Bintulu, Malaysia, uses natural gas as a feedstock, and produces primarily low-sulfur diesel fuels.[7] Sasol[8] in South Africa uses coal as a feedstock, and produces a variety of synthetic petroleum products.

The process is today used in South Africa to produce most of the country's diesel fuel from coal by the company Sasol. The process was used in South Africa to meet its energy needs during its isolation under Apartheid. This process has received renewed attention in the quest to produce low sulfur diesel fuel in order to minimize the environmental impact from the use of diesel engines.

An alternative method of converting coal into petroleum is the Karrick process, which was pioneered in the 1930s in the United States. It uses high temperatures in the absence of ambient air, to distill the short-chain hydrocarbons of petroleum out of coal.

More recently explored is thermal depolymerization (TDP), a process for the reduction of complex organic materials into light crude oil. Using pressure and heat, long chain polymers of hydrogen, oxygen, and carbon decompose into short-chain petroleum hydrocarbons. This mimics the natural geological processes thought to be involved in the production of fossil fuels. In theory, TDP can convert any organic waste into petroleum.

History

Petroleum, in some form or other, is not a substance new in the world's history. More than four thousand years ago, according to Herodotus and confirmed by Diodorus Siculus, asphalt was employed in the construction of the walls and towers of Babylon; there were oil pits near Ardericca (near Babylon), and a pitch spring on Zacynthus.[9] Great quantities of it were found on the banks of the river Issus, one of the tributaries of the Euphrates. Ancient Persian tablets indicate the medicinal and lighting uses of petroleum in the upper levels of their society.

The first oil wells were drilled in China in the fourth century or earlier. They had depths of up to 243 meters (about 800 feet) and were drilled using bits attached to bamboo poles. The oil was burned to evaporate brine and produce salt. By the tenth century, extensive bamboo pipelines connected oil wells with salt springs. The ancient records of China and Japan are said to contain many allusions to the use of natural gas for lighting and heating. Petroleum was known as burning water in Japan in the seventh century.[10]

In the eighth century, the streets of the newly constructed Baghdad were paved with tar, derived from easily accessible petroleum from natural fields in the region. In the 9th century, oil fields were exploited in the area around modern Baku, Azerbaijan, to produce naphtha. These fields were described by the geographer Masudi in the tenth century, and by Marco Polo in the thirteenth century, who described the output of those wells as hundreds of shiploads. Petroleum was first distilled by Muslim chemists in the ninth century, producing chemicals such as kerosene.[11] (See also: Islamic science and Timeline of science and technology in the Islamic world.)

The earliest mention of American petroleum occurs in Sir Walter Raleigh's account of the Trinidad Pitch Lake in 1595; whilst 37 years later, the account of a visit of a Franciscan, Joseph de la Roche d'Allion, to the oil springs of New York was published in Sagard's Histoire du Canada. A Russian traveller, Peter Kalm, in his work on America published in 1748 showed on a map the oil springs of Pennsylvania.[12]

The modern history of petroleum began in 1846 with the discovery of the process of refining kerosene from coal by Atlantic Canada's Abraham Pineo Gesner.

The first modern oil well was drilled in 1745 in Pechelbronn, Alsace (France) under the direction of Louis de La Sablonniere, by special appointment of King Louis XV.[13] The Pechelbronn oil field was alive until 1970, and was the birthplace of companies like Schlumberger. The first modern refinery was built there in 1857.[14]

Poland's Ignacy Łukasiewicz discovered a means of refining kerosene from the more readily available "rock oil" ("petr-oleum") in 1852 and the first rock oil mine was built in Bóbrka, near Krosno in southern Poland in the following year. These discoveries rapidly spread around the world, and Meerzoeff built the first Russian refinery in the mature oil fields at Baku in 1861. At that time Baku produced about 90 percent of the world's oil.

Oil field in California, 1938.

The first commercial oil well drilled in North America was in Oil Springs, Ontario, Canada in 1858, dug by James Miller Williams. The American petroleum industry began with Edwin Drake's drilling of a 69-foot-deep oil well in 1859, on Oil Creek near Titusville, Pennsylvania, for the Seneca Oil Company (originally yielding 25 barrels a day, by the end of the year output was at the rate of 15 barrels).[15] The industry grew slowly in the 1800s, driven by the demand for kerosene and oil lamps. It became a major national concern in the early part of the twentieth century; the introduction of the internal combustion engine provided a demand that has largely sustained the industry to this day. Early "local" finds like those in Pennsylvania and Ontario were quickly exhausted, leading to "oil booms" in Texas, Oklahoma, and California.

Early production of crude petroleum in the United States:[16]

  • 1859: 2,000 barrels
  • 1869: 4,215,000 barrels
  • 1879: 19,914,146 barrels
  • 1889: 35,163,513 barrels
  • 1899: 57,084,428 barrels
  • 1906: 126,493,936 barrels

By 1910, significant oil fields had been discovered in Canada (specifically, in the province of Ontario), the Dutch East Indies (1885, in Sumatra), Iran (1908, in Masjed Soleiman), Peru, Venezuela, and Mexico, and were being developed at an industrial level.

Even until the mid-1950s, coal was still the world's foremost fuel, but oil quickly took over. Following the 1973 energy crisis and the 1979 energy crisis, there was significant media coverage of oil supply levels. This brought to light the concern that oil is a limited resource that will eventually run out, at least as an economically viable energy source. At the time, the most common and popular predictions were always quite dire, and when they did not come true, many dismissed all such discussion. The future of petroleum as a fuel remains somewhat controversial. USA Today newspaper (2004) reports that there are 40 years of petroleum left in the ground. Some would argue that because the total amount of petroleum is finite, the dire predictions of the 1970s have merely been postponed. Others argue that technology will continue to allow for the production of cheap hydrocarbons and that the earth has vast sources of unconventional petroleum reserves in the form of tar sands, bitumen fields and oil shale that will allow for petroleum use to continue in the future, with both the Canadian tar sands and United States shale oil deposits representing potential reserves matching existing liquid petroleum deposits worldwide.

Today, about 90 percent of vehicular fuel needs are met by oil. Petroleum also makes up 40 percenr of total energy consumption in the United States, but is responsible for only 2 percent of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important commodities. Access to it was a major factor in several military conflicts including World War II and the Persian Gulf Wars of the late twentieth and early twenty-first centuries. The top three oil producing countries are Saudi Arabia, Russia, and the United States. About 80 percent of the world's readily accessible reserves are located in the Middle East, with 62.5 pervent coming from the Arab Five: Saudi Arabia (12.5 percent), UAE, Iraq, Qatar and Kuwait. However, with today's oil prices, Venezuela has larger reserves than Saudi Arabia due to crude reserves derived from bitumen.

Uses

The chemical structure of petroleum is composed of hydrocarbon chains of different lengths. Because of this, petroleum may be taken to oil refineries and the hydrocarbon chemicals separated by distillation and treated by other chemical processes, to be used for a variety of purposes. See Petroleum products.

Fuels

  • Ethane and other short-chain alkanes which are used as fuel
  • Diesel fuel
  • Fuel oils
  • Gasoline
  • Jet fuel
  • Kerosene
  • Liquid petroleum gas (LPG)

Other derivatives

Certain types of resultant hydrocarbons may be mixed with other non-hydrocarbons, to create other end products:

  • Alkenes (olefins) which can be manufactured into plastics or other compounds
  • Lubricants (produces light machine oils, motor oils, and greases, adding viscosity stabilizers as required).
  • Wax, used in the packaging of frozen foods, among others.
  • Sulfur or Sulfuric acid. These are a useful industrial materials. Sulfuric acid is usually prepared as the acid precursor oleum, a byproduct of sulfur removal from fuels.
  • Bulk tar.
  • Asphalt
  • Petroleum coke, used in speciality carbon products or as solid fuel.
  • Paraffin wax
  • Aromatic petrochemicals to be used as precursors in other chemical production.

Consumption statistics

Global fossil carbon emissions, an indicator of consumption, for 1800-2000. Total is black. Oil is in blue.

Environmental effects

Diesel fuel spill on a road

The presence of oil has significant social and environmental impacts, from accidents and routine activities such as seismic exploration, drilling, and generation of polluting wastes not produced by other alternative energies.

Extraction

Oil extraction is costly and sometimes environmentally damaging, although Dr. John Hunt of the Woods Hole Oceanographic Institution pointed out in a 1981 paper that over 70 percent of the reserves in the world are associated with visible macroseepages, and many oil fields are found due to natural leaks. Offshore exploration and extraction of oil disturbs the surrounding marine environment.[17] But at the same time, offshore oil platforms also form micro-habitats for marine creatures. Extraction may involve dredging, which stirs up the seabed, killing the sea plants that marine creatures need to survive.

Oil spills

Volunteers cleaning up the aftermath of the Prestige oil spill

Crude oil and refined fuel spills from tanker ship accidents have damaged natural ecosystems in Alaska, the Galapagos Islands and many other places and times in Spain (i.e. Ibiza).

Global warming

Main article: Global warming

Burning oil releases carbon dioxide into the atmosphere, which contributes to global warming. Per energy unit, oil produces less CO2 than coal, but more than natural gas. However, oil's unique role as a transportation fuel makes reducing its CO2 emissions a particularly thorny problem; amelioration strategies such as carbon sequestering are generally geared for large power plants, not individual vehicles.

Alternatives to petroleum

Main article: Renewable energy

Alternatives to petroleum-based vehicle fuels

The term alternative propulsion or "alternative methods of propulsion" includes both:

Nowadays, cars can be classified between the next main groups:

  • Petro-cars, this is, only use petroleum and biofuels (biodiesel and biobutanol).
  • Hybrid vehicle and plug-in hybrids, that use petroleum and other source, generally, electricity.
  • Petrofree car, that can not use petroleum, like electric cars, hydrogen vehicles…

The future of petroleum production

Hubbert peak theory

The Hubbert peak theory (also known as peak oil) is a proposition which predicts that future world petroleum production must inevitably reach a peak and then decline at a similar rate to the rate of increase before the peak as these reserves are exhausted. It also suggests a method to calculate mathematically the timing of this peak, based on past production rates, past discovery rates, and proven oil reserves.

Controversy surrounds the theory for numerous reasons. Past predictions regarding the timing of the global peak have failed, causing a number of observers to disregard the theory. Further, predictions regarding the timing of the peak are highly dependent on the past production and discovery data used in the calculation.

Proponents of peak oil theory also refer as an example of their theory, that when any given oil well produces oil in similar volumes to the amount of water used to obtain the oil, it tends to produce less oil afterwards, leading to the relatively quick exhaustion and/or commercial inviability of the well in question.

The issue can be considered from the point of view of individual regions or of the world as a whole. Hubbert's prediction for when US oil production would peak turned out to be correct, and after this occurred in 1971 - causing the US to lose its excess production capacity - OPEC was finally able to manipulate oil prices, which led to the 1973 oil crisis. Since then, most other countries have also peaked: the United Kingdom's North Sea, for example in the late 1990s. China has confirmed that two of its largest producing regions are in decline, and Mexico's national oil company, Pemex, has announced that Cantarell Field, one of the world's largest offshore fields, was expected to peak in 2006, and then decline 14 percent per annum.

It is difficult to predict the oil peak in any given region (due to the lack of transparency in accounting of global oil reserves[18]) Based on available production data, proponents have previously (and incorrectly) predicted the peak for the world to be in years 1989, 1995, or 1995-2000. Some of these predictions date from before the recession of the early 1980s, and the consequent reduction in global consumption, the effect of which was to delay the date of any peak by several years. A new prediction by Goldman Sachs picks 2007 for oil and some time later for natural gas. Just as the 1971 U.S. peak in oil production was only clearly recognized after the fact, a peak in world production will be difficult to discern until production clearly drops off.

Many proponents of the Hubbert peak theory expound the belief that the production peak is imminent, for various reasons. The year 2005 saw a dramatic fall in announced new oil projects coming to production from 2008 onwards - in order to avoid the peak, these new projects would have to not only make up for the depletion of current fields, but increase total production annually to meet increasing demand.

The year 2005 also saw substantial increases in oil prices stemming from a number of circumstances, including war and political instability. Oil prices rose to new highs. Analysts such as Kenneth Deffeyes [19] argue that these price increases indicate a general lack of spare capacity, and the price fluctuations can be interpreted as a sign that peak oil is imminent.

International market

Oil consumption per capita (darker colors represent more consumption).

Petroleum efficiency among countries

There are two main ways to measure the petroleum efficiency of countries: by population or by GDP (gross domestic product). This metric is important in the global debate over oil consumption/energy consumption/climate change because it takes social and economic considerations into account when scoring countries on their oil consumption/energy consumption/climate change goals. Nations such as China and India with large populations tend to promote the use of population based metrics, while nations with large economies such as the United States would tend to promote the GDP based metric.

Selected Nations Oil Efficiency (US dollar/barrel/day)
Switzerland 3.75
United Kingdom 3.34
Norway 3.31
Austria 2.96
France 2.65
Germany 2.89
Sweden 2.71
Italy 2.57
European Union 2.52
DRC 2.4
Japan 2.34
Australia 2.21
Spain 1.96
Bangladesh 1.93
Poland 1.87
United States 1.65
Belgium 1.59
World 1.47
Turkey 1.39
Canada 1.35
Mexico 1.07
Ethiopia 1.04
South Korea 1.00
Philippines 1.00
Brazil 0.99
Taiwan 0.98
China 0.94
Nigeria 0.94
Pakistan 0.93
Myanmar 0.89
India 0.86
Russia 0.84
Indonesia 0.71
Vietnam 0.61
Thailand 0.53
Saudi Arabia 0.46
Egypt 0.41
Singapore 0.40
Iran 0.35

Selected Nations Oil Efficiency (barrel/person/year)
DRC 0.13
Ethiopia 0.37
Bangladesh 0.57
Myanmar 0.73
Pakistan 1.95
Nigeria 2.17
India 2.18
Vietnam 2.70
Philippines 3.77
Indonesia 4.63
China 4.96
Egypt 7.48
Turkey 9.85
Brazil 11.67
Poland 11.67
World 12.55
Thailand 13.86
Russia 17.66
Mexico 18.07
Iran 21.56
European Union 29.70
United Kingdom 30.18
Germany 32.31
France 32.43
Italy 32.43
Austria 34.01
Spain 35.18
Switzerland 34.64
Sweden 34.68
Taiwan 41.68
Japan 42.01
Australia 42.22
South Korea 43.84
Norway 52.06
Belgium 61.52
United States 68.81
Canada 69.85
Saudi Arabia 75.08
Singapore 178.45

(Note: The figure for Singapore is skewed because of its small
population compared with its large oil refining capacity.
Most of this oil is sent to other countries.)

Top petroleum-producing countries

Source: Energy Statistics from the U.S. Government.

For oil reserves by country, see Oil reserves by country.

Oil producing countries

In order of amount produced in 2004 in MMbbl/d & ML/d:

# Producing Nation for 2004 (×106bbl/d) (×103m³/d)
1 Saudi Arabia (OPEC) 10.37 1,649
2 Russia 9.27 1,474
3 United States 1 8.69 1,382
4 Iran (OPEC) 4.09 650
5 Mexico 1 3.83 609
6 China 1 3.62 576
7 Norway 1 3.18 506
8 Canada 1,3 3.14 499
9 Venezuela (OPEC) 1 2.86 455
10 United Arab Emirates (OPEC) 2.76 439
11 Kuwait (OPEC) 2.51 399
12 Nigeria (OPEC) 2.51 399
13 United Kingdom 1 2.08 331
14 Iraq (OPEC) 2 2.03 323

1 peak production of conventional oil already passed in this state

2 Though still a member, Iraq has not been included in production figures since 1998

3 Canada has the world's second largest oil reserves when tar sands are included, and is the leading source of U.S. imports, averaging 1.7 MMbbl/d in April 2006 [1].

Top petroleum-exporting countries

Oil exports by country

In order of amount exported in 2003:

  1. Saudi Arabia (OPEC)
  2. Russia
  3. Norway 1
  4. Iran (OPEC)
  5. United Arab Emirates (OPEC)
  6. Venezuela (OPEC) 1
  7. Kuwait (OPEC)
  8. Nigeria (OPEC)
  9. Mexico 1
  10. Algeria (OPEC)
  11. Libya (OPEC) 1

1 peak production already passed in this state

Note that the USA consumes almost all of its own production, while the UK has recently become a net-importer rather than net-exporter.

Total world production/consumption (as of 2005) is approximately 84 million barrels per day.

See also: Organization of Petroleum Exporting Countries.

Top petroleum-consuming countries

# Consuming Nation (bbl/day) (m³/day)
1 United States 20,030,000 3,184,516
2 China 6,391,000 1,016,088
3 Japan 5,578,000 886,831
4 Russia 2,800,000 445,164
5 Germany 2,677,000 425,609
6 India 2,320,000 368,851
7 Canada 2,300,000 365,671
8 South Korea 2,061,000 327,673
9 France 2,060,000 327,514
10 Italy 1,874,000 297,942
11 Saudi Arabia 1,775,000 282,202
12 Mexico 1,752,000 278,546
13 United Kingdom 1,722,000 273,776
14 Brazil 1,610,000 255,970

Source: CIA World Factbook

Top petroleum-importing countries

Oil imports by country
# Importing Nation (bbl/day) (m³/day)
1 United States 13,150,000 2,790,683
2 Japan 5,449,000 866,322
3 China 3,226,000 512,893
4 Netherlands 2,284,000 363,127
5 France 2,281,000 362,650
6 South Korea 2,263,000 359,788
7 Italy 2,158,000 343,095
8 Germany 2,135,000 339,438
9 India 2,090,000 332,283
10 Spain 1,582,000 251,518
11 United Kingdom 1,084,000 172,342
12 Belgium 1,042,000 165,665
13 Canada 963,000 153,105
14 Turkey 616,500 98,016

Source: CIA World Factbook

Top petroleum non-producing and consuming countries

# Consuming Nation (bbl/day) (m³/day)
1 Japan 5,578,000 886,831
2 Germany 2,677,000 425,609
3 India 2,320,000 368,851
4 South Korea 2,061,000 327,673
5 France 2,060,000 327,514
6 Italy 1,874,000 297,942
7 Spain 1,537,000 244,363
8 Netherlands 946,700 150,513

Source : CIA World Factbook

See also

Notes

  1. Manual of Petroleum Measurement Standards (MPMS), by the American Petroleum Institute
  2. "Crude oil is made into different fuels". Energy Kids Page. Retrieved August 25, 2007.
  3. EIA reserves estimates. Energy Information Administration. Retrieved August 25, 2007.
  4. CERA report on total world oil. CERA. Retrieved August 25, 2007.
  5. WebMOHeat of Combustion of Fuels.Classroom-tested WebMO Exercises. Retrieved August 25, 2007.
  6. Petroleum Study. DOE "Technical and Scientific Information" Bridge. Retrieved August 25, 2007.
  7. Shell Middle Distillate Synthesis Malaysia. Shell Oil. Retrieved August 25, 2007.
  8. Sasol corporate website. Retrieved August 25, 2007.
  9. Encyclopedia Britannica, (1911 ed.) "Petroleum."
  10. Ibid.
  11. Kasem Ajram. The Miracle of Islam Science. (Lincolnshire, IL: Knowledge House Publishers, 1992. ISBN 0911119434).
  12. Encyclopedia Britannica (1911)
  13. Pechelbronn History of Pechelbronn oil. The Oil Museum. Retrieved August 25, 2007.
  14. Ibid.
  15. Encyclopedia Britannica. (1911)
  16. Ibid.
  17. Stanislave Patin. Waste discharges during the offshore oil and gas activity. Offshore-environment.com. Retrieved August 25, 2007.
  18. New study raises doubts about Saudi oil reserves.(March 31, 2004) Institute for the Analysis of Global Security (IAGS). Retrieved August 25, 2007.
  19. Kenneth Deffeyes. Beyond Oil: The View from Hubbert's Peak. New York, NY: Hill and Wang, 2005. ISBN 080902957X.

References
ISBN links support NWE through referral fees

  • Conaway, Charles F. 1999. The Petroleum Industry: A Nontechnical Guide. Tulsa, OK: PennWell. ISBN 0878147772
  • Hyne, Norman J. 2001. Nontechnical Guide to Petroleum Geology, Exploration, Drilling, and Production, 2nd ed. Tulsa, OK: PennWell. ISBN 087814823X
  • McCain, William D. 1989. The Properties of Petroleum Fluids. Tulsa, OK: PennWell. ISBN 0878143351
  • Meyers, Robert A. 2004. Handbook of Petroleum Refining Processes, 3rd ed. McGraw-Hill Handbooks. New York: McGraw-Hill. ISBN 0071391096

External links

All links retrieved April 17, 2015.

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